Process for generation of synthesis gas by flue gas recycle

Patent metadata

Field	Value
Publication number	US-10150670-B2
Application number	US-201515527202-A
Country	US
Kind code	B2
Filing date	Nov 25, 2015
Priority date	Nov 25, 2014
Publication date	Dec 11, 2018
Grant date	Dec 11, 2018

Abstract

A novel process for synthesis gas generation comprises treating a hydrocarbon feed in a primary reformer (PR), compressing at least part of the flue gas from the primary reformer in a compressor (C1), and feeding the compressed flue gas to a secondary reformer (SR) together with the primary reformer effluent. In the process, enriched air (EA) is added either to the primary reformer, to the secondary reformer or both. The process is especially suited for co-production of ammonia and methanol or for production of either ammonia or methanol. The total CO2 emission is lowered considerably by using the process of the invention.

First claim

The invention claimed is:

1. A process for synthesis gas generation, said process comprising the following steps:
treating a hydrocarbon feed in a primary reformer (PR) to obtain a stream of flue gas and a stream of effluent,
compressing at least part of the flue gas from the primary reformer in a compressor (C 1 ), and
feeding the compressed flue gas and the effluent to a secondary reformer (SR),
wherein enriched air (EA) is added either to the primary reformer, the secondary reformer or both.

2. The process according to claim 1 , further including the following steps:
passing the secondary reformer effluent through a shift conversion section,
removing CO 2 from the shift conversion effluent in a CO 2 removal section,
performing a synthesis gas clean-up of the CO 2 removal section effluent, and
compressing the resulting stream in a compressor (C 3 ) and transferring the compressed stream to an ammonium loop (AL) for ammonia synthesis,
wherein the amount of CO 2 removed in the CO 2 removal step is sufficient to convert all the ammonia produced in the ammonium synthesis to urea.

3. The process according to claim 1 , further including the following steps:
passing the secondary reformer effluent or part thereof through a shift conversion section,
removing all the CO 2 or part thereof from the shift converter effluent in a CO 2 removal section,
compressing the CO 2 removal section effluent in a compressor (C 2 ) and passing part or all of the compressed effluent through a methanol synthesis section (M),
performing a synthesis gas clean-up of the methanol synthesis section effluent,
compressing the resulting stream further in the compressor (C 3 ), and
transferring the resulting stream to an ammonium loop (AL) for ammonia synthesis,
wherein the amount of CO 2 removed in the CO 2 removal step is sufficient to convert all the ammonia produced in the ammonium synthesis or part thereof to urea.

4. The process according to claim 3 , further including the following steps:
feeding the secondary reformer effluent directly to the compressor (C 2 ), and
passing the effluent from the compressor (C 2 ) through a methanol synthesis section.

5. The process according to claim 1 , wherein the enriched air is obtained by using an air separation unit (ASU).

6. The process according to claim 5 , wherein the air separation unit (ASU) is based on membrane separation technology.

7. The process according to claim 1 , wherein the hydrocarbon feed is a mixture of steam and optionally pre-reformed hydrocarbons, said hydrocarbons originating from any hydrocarbon source that can be used for reformer feeding.

Assignees

• Haldor Topsoe As
• Haldor Topsoe As

Inventors

• Andersen Niels Ulrik

Classifications

• C01B2203/0475

  the impurity being carbon dioxide · CPC title

• C01B3/34 Primary

  by reaction of hydrocarbons with gasifying agents · CPC title

• C01B2203/0233

  the reforming step being a steam reforming step · CPC title

• C01B2203/061

  Methanol production · CPC title

• C01B2203/142

  At least two reforming, decomposition or partial oxidation steps in series · CPC title