Oxygen-absorbing resin composition

Patent metadata

Field	Value
Publication number	US-10150107-B2
Application number	US-201414770934-A
Country	US
Kind code	B2
Filing date	Mar 5, 2014
Priority date	Mar 5, 2013
Publication date	Dec 11, 2018
Grant date	Dec 11, 2018

Abstract

Oxygen-absorbing resin composition comprising a polyester containing a constitutional unit (a) comprising tetralin ring structure, for example, an alkyl tetralin dicarboxylate, wherein the alkyl component has, for example, from 2 to 6 carbon atoms, and a constitutional unit (b) derived from a polyfunctional compound, selected from glycerin, trimethylol propane, pentaerythritol, trimellitic acid, trimellitic acid anhydride, pyromellitic acid, and pyromellitic acid anhydride, and a transition metal catalyst.

First claim

The invention claimed is:

1. An oxygen-absorbing resin composition at least comprising a polyester compound containing a constitutional unit (a) and a constitutional unit (b), and a transition metal catalyst;
the constitutional unit (a): a constitutional unit having at least one tetralin ring selected from the group consisting of constitutional units represented by the following general formulas (5) to (7):

and
constitutional unit (b): a constitutional unit derived from a polyfunctional compound selected from at least one of glycerin, trimethylol propane, pentaerythritol, trimellitic acid, trimellitic acid anhydride, pyromellitic acid, and pyromellitic acid anhydride,
wherein the oxygen-absorbing resin composition further comprises a catalyst for producing the polyester compound, and
wherein the transition metal catalyst is different from the catalyst for producing the polyester compound, and
wherein the content of component (b) is from 0.2 mol % to 1 mol % and the polyester compound optionally contains up to 0.1 mol % of constitutional units other than constitutional units (a) and (b), and the sum of all constitutional units is 100 mol %, and
wherein the content of the polyester compound is at least 90% by mass based on a total amount of the oxygen-absorbing resin composition.

2. The oxygen-absorbing resin composition according to claim 1 , wherein the polyester compound has a melt viscosity value (shear rate: 1216 sec-1, temperature: 260° C.) of 80 Pa·sec or more.

3. The oxygen-absorbing resin composition according to claim 1 , wherein the transition metal catalyst is a catalyst comprising at least one transition metal selected from the group consisting of manganese, iron, cobalt, nickel and copper.

4. The oxygen-absorbing resin composition according to claim 1 , wherein the transition metal catalyst is contained in an amount of 0.001 to 10 parts by mass in terms of a transition metal based on 100 parts by mass of the polyester compound.

5. A molded article comprising the oxygen-absorbing resin composition according to claim 1 .

Assignees

• Mitsubishi Gas Chemical Co

Inventors

• Iwamoto Shinpei
• Okada Satoshi
• Ikeda Shinichi
• Ito Fumihiro

Classifications

• B01D2259/4525

  for storage and dispensing systems · CPC title

• C08G63/60

  derived from the reaction of a mixture of hydroxy carboxylic acids, polycarboxylic acids and polyhydroxy compounds · CPC title

• B01D53/81

  Solid phase processes · CPC title

• B01D2255/20761

  Copper · CPC title

• B01D2255/20746

  Cobalt · CPC title