Microstructure reactor for carrying out exothermic heterogenously-catalysed reactions with efficient evaporative cooling

Patent metadata

Field	Value
Publication number	US-10150093-B2
Application number	US-201615743765-A
Country	US
Kind code	B2
Filing date	Jul 15, 2016
Priority date	Jul 17, 2015
Publication date	Dec 11, 2018
Grant date	Dec 11, 2018

Abstract

The invention relates to a micro-reactor for carrying out at least one catalytic reaction between two or more reactants in each case, comprising a stacking sequence of reaction surfaces ( 1 ) for carrying out at least one exothermic reaction, and a cooling region ( 6 ) divided at least into individual fields ( 6 ) with feed and discharge devices for the coolant.

First claim

What is claimed is:

1. A microstructure reactor for carrying out an exothermic reaction between two or more reactants, which are passed in the form of fluids over one or more catalysts, wherein the reactor comprises at least one stacking sequence of
(a) at least one layer comprising one or more catalysts for carrying out at least one exothermic reaction,
(b) at least one layer divided into two or more cooling fields,
(c) at least one layer having distributor structures comprising
lines for distribution of a coolant,
connections for feeding the coolant to the lines of the distributor structure and for connection to the cooling fields,
connections for discharging heated coolant from the cooling fields, and
lines and connections for discharging heated coolant from the stacking sequence.

2. The microstructure reactor of claim 1 , wherein the reactor comprises a plurality of stacking sequences.

3. The microstructure reactor of claim 2 , wherein the stacking sequences are arranged as mirror images of each other.

4. The microstructure reactor of claim 1 , wherein individual layers (a) to (c) are configured in the form of plates or in the form of films.

5. The microstructure reactor of claim 4 , wherein layers (a) to (c) have the following thicknesses:
layer (a): from 0.5 mm to 10 mm,
layer (b): from 0.1 mm to 5 mm,
layer (c): from 1 mm to 10 mm.

6. The microstructure reactor of claim 1 , wherein one or more layers (a) to (c) comprise structures on their surface.

7. The microstructure reactor of claim 6 , wherein the one or more catalysts are filled into the structures.

8. The microstructure reactor of claim 7 , wherein the structures are reaction channels or reaction slots, which are filled with particles.

9. The microstructure reactor of claim 8 , wherein the reaction channels or reaction slots have a height of from 0.4 mm to 8 mm.

10. The microstructure reactor of claim 1 , wherein within the distribution structures lines of coolant-carrying feed are arranged with maximum gap to lines for discharging the coolant from the cooling fields.

11. The microstructure reactor of claim 10 , wherein the feed lines for the coolant are descending in hydraulic diameter in a direction of flow of the coolant.

12. The microstructure reactor of claim 11 , wherein discharge lines for steam are ascending in hydraulic diameter in a direction of flow of the coolant.

13. The microstructure reactor of claim 1 , wherein each cooling field comprises a single feed and discharge of the coolant in the distributor structure.

14. The microstructure reactor of claim 1 , wherein the one or more catalysts are cobalt, iron, nickel, rhodium or ruthenium catalysts or contain such elements.

15. The microstructure reactor of claim 1 , wherein feed and discharge of coolant in the distributor structure are arranged in cross-flow in relation to a flow of the reactants.

Assignees

• Karlsruher Inst Technologie
• Ineratec Gmbh

Inventors

• Pfeifer Peter
• Piermartini Paolo
• Wenka Achim

Classifications

• B01J2219/246

  Perforated plates · CPC title

• B01J2219/2453

  Plates arranged in parallel · CPC title

• B01J2219/00783

  Laminate assemblies, i.e. the reactor comprising a stack of plates · CPC title

• B01J2219/00835

  Comprising catalytically active material · CPC title

• B01J2219/2462

  the reactants being in indirect heat exchange with a non reacting heat exchange medium · CPC title