Nanoparticle material and light-emitting device
US-2016225947-A1 · Aug 4, 2016 · US
US10147844B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10147844-B2 |
| Application number | US-201615380157-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 15, 2016 |
| Priority date | Dec 29, 2015 |
| Publication date | Dec 4, 2018 |
| Grant date | Dec 4, 2018 |
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A quantum dot includes: a core including at least one first positive ion precursor and at least one negative ion precursor; a shell including at least one second positive ion precursor and at least one negative ion precursor and wrapping the core; and a ligand formed on a surface of the shell, wherein the first positive ion precursor is an n-period element and the second positive ion precursor is an (n-1)-period element, where n is an integer of 3 to 6.
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What is claimed is: 1. A light-emitting device comprising: a first electrode; a second electrode facing the first electrode; an emission layer provided between the first electrode and the second electrode, wherein the emission layer includes a core including at least one first positive ion precursor and at least one negative ion precursor, a shell including at least one second positive ion precursor and at least one negative ion precursor and wrapping the core, and a ligand formed on a surface of the shell, and wherein the first positive ion precursor is an n-period element and the second positive ion precursor is an (n-1)-period element, where n is an integer of 3 to 6; a hole transport layer disposed between the first electrode and the emission layer; and an electron transport layer disposed between the emission layer and the second electrode, wherein the hole transport layer, the electron transport layer and the core of the emission layer include a same inorganic material, wherein the hole transport layer includes a p-doped compound of the compound included in the core, the p-doped compound being doped with a metal, a non-metal, or a halogen element, and the electron transport layer includes an n-doped compound of the compound included in the core, the n-doped compound being doped with a metal, a non-metal, or a halogen element. 2. The light-emitting device of claim 1 , wherein the light-emitting device includes a quantum dot in which a HOMO energy level and a LUMO energy level of the shell are different from a HOMO energy level and a LUMO energy level of the core by equal to or less than 2.0 eV, respectively. 3. The light-emitting device of claim 2 , wherein the first positive ion precursor includes at least one of Al, Fe, Co, Cu, Zn, Ga, In, Ag, Pb, Bi, and Tl. 4. The light-emitting device of claim 3 , wherein the at least one negative ion precursor includes at least one of Te, I, O, S, Se, N, P, As, and Sb. 5. The light-emitting device of claim 4 , wherein the core includes at least one of PbI2, BiI3, Fe2O3, CoO, CuO, Cu2O, AgO, Ag2O, CuS, Cu2S, Ag2S, In2S3, Bi2S3, CuSe, Cu2Se, AgSe, Ga2Se3, In2Se3, TlSe, Cu2Te, ZnTe, Cu3N, Zn3P2, GaP, InP, AlAs, GaAs, and AlSb. 6. The light-emitting device of claim 5 , wherein the light-emitting device further includes a blocking layer, and the blocking layer is provided between the hole transport layer and the emission layer and/or between the emission layer and the electron transport layer. 7. The light-emitting device of claim 6 , wherein the blocking layer includes a first-group metal based halide compound or a second-group metal based halide compound. 8. The light-emitting device of claim 7 , wherein the blocking layer is 0.5 nm to 5 nm thick.
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