Ion mirror, an ion mirror assembly and an ion trap

Patent metadata

Field	Value
Publication number	US-10147591-B2
Application number	US-201615547408-A
Country	US
Kind code	B2
Filing date	Jan 29, 2016
Priority date	Feb 3, 2015
Publication date	Dec 4, 2018
Grant date	Dec 4, 2018

Abstract

An ion mirror ( 10 ) for use in a time of flight mass spectrometer ( 100 ) comprises a first conductor ( 20 ) for producing a quadratic field along a first axis ( 80 ), and a second conductor ( 30 ) for producing a quadratic field along a second axis ( 90 ), the axes ( 80, 90 ) being orthogonal.

First claim

The invention claimed is:

1. An ion mirror comprising:
a first means for producing a quadratic field along a first axis;
a second means for producing a quadratic field along a second axis, the axes being orthogonal; and
a front plate defining an entry aperture for admission of ions, wherein the first means and the second means are arranged to generate a quadratic field along a first axis and a quadratic field along a second axis by application of a first potential at the first means and a second potential at the second means, wherein the first potential and the second potential are concurrently alternately and oppositely biased, thereby to define a plane of zero field in between the first means and the second means, the entry aperture lying in the plane of zero field.

2. The ion mirror as claimed in claim 1 , wherein at least one of the first and second means is arranged to produce a hyberbolic electric field.

3. The ion mirror as claimed in claim 1 , wherein the front plate includes an exit aperture in the plane of zero field between the first and second means and displaced from the entry aperture.

4. The ion mirror as claimed in claim 1 , wherein the first means comprises a series of discrete electrodes.

5. The ion mirror as claimed in claim 4 , wherein the series of discrete electrodes comprises a capacitive divider that is configurable to apportion different potentials to different ones of the discrete electrodes in the series of discrete electrodes.

6. The ion mirror as claimed in claim 5 , wherein the capacitive divider is arranged such that the capacitance of each of the discrete electrodes increases linearly across the series of discrete electrodes from one discrete electrode to the next.

7. The ion mirror as claimed in claim 4 , wherein the series of discrete electrodes is a system of substantially parallel plane electrodes.

8. The ion mirror as claimed in claim 4 , wherein the series of discrete electrodes is formed on a first dielectric material.

9. The ion mirror as claimed in claim 8 , wherein the first dielectric material comprises a further electrode on an opposite side of the first dielectric material from the series of discrete electrodes, thereby to form a series of capacitors.

10. The ion mirror as claimed in claim 9 , wherein the first dielectric material is a different thickness at a point between a first discrete electrode of the series of discrete electrodes and the further electrode and at a point between a second discrete electrode of the series of discrete electrodes and the further electrode, thereby to create at least two capacitors of different capacitances.

11. The ion mirror as claimed in claim 8 , wherein the series of discrete electrodes is also formed on a second dielectric material which comprises a further electrode on an opposite side of the second dielectric material from the series of discrete electrodes, thereby to form a series of capacitors.

12. The ion mirror as claimed in claim 11 , wherein the second dielectric material is a different thickness at a point between a first discrete electrode of the series of discrete electrodes and the further electrode and at a point between a second discrete electrode of the series of discrete electrodes and the further electrode of the second dielectric thereby to create at least two capacitors of different capacitances.

13. The ion mirror as claimed in claim 12 , wherein the further electrode of the first dielectric and the further electrode of the second dielectric are configured to provide a capacitive divider.

14. The ion mirror as claimed in claim 1 , wherein the first means comprises a first elongate conductor, and the second means comprises a second elongate conductor, the first elongate conductor being parallel to the second elongate conductor and spaced therefrom.

15. A mass spectrometer including an ion mirror according to claim 1 .

16. An ion mirror assembly comprising:
an ion mirror comprising:
a first means for producing a quadratic field along a first axis;
a second means for producing a quadratic field along a second axis, the axes being orthogonal;
wherein the first means and the second means are arranged to generate a quadratic field along a first axis and a quadratic field along a second axis by application of a first potential at the first means and a second potential at the second means, wherein the first potential and the second potential are concurrently alternately and oppositely biased, thereby to define a plane of zero field in between the first means and the second means;

and the assembly further comprising:
means defining a direction of entry of ions into the ion mirror, the defined direction of entry lying substantially in the plane of zero field.

17. The ion mirror assembly as claimed in claim 16 , wherein the ion mirror further comprises a front plate defining an entry aperture for admission of ions, the entry aperture lying in the plane of zero field.

18. A mass spectrometer including an ion mirror assembly according to claim 16 .

19. An ion trap comprising:
a first means for producing a quadratic field along a first axis, a second means for producing a quadratic field along a second axis, a third means for producing a quadratic field along a third axis, a fourth means for producing a quadratic field along a fourth axis, the first axis, second axis, third axis and fourth axis being mutually orthogonal about a notional central axis;
means to produce a magnetic field substantially perpendicular to each of the first axis, second axis, third axis and fourth axis at each end of the ion trap;
wherein the first means, the second means, the third means and the fourth means are arranged such that an ion introduced between the first means, second means, third means and fourth means and the magnetic means is trappable upon application of the quadratic fields along the first, second, third and fourth axes.

20. The ion trap as claimed in claim 19 , wherein the ion trap includes means to image ions trapped in the trap by monitoring image currents.

21. The ion trap as claimed in claim 20 , wherein each magnetic means includes an end plate and the imaging means is arranged to monitor the image currents in the end plates.

22. The ion trap as claimed in claim 19 , wherein the first and third means are arranged to produce quadratic fields along the first and third axes in phase with one another and out of phase with the quadratic fields along the second and fourth axes, arranged to be produced by the second and fourth means, wherein the quadratic fields produced by the first and third axes are provided by application of a first potential at the first and third means and the quadratic fields produced by the second and fourth axis are provided by application of a second potential at the second and fourth means, wherein the first potential and the second potential are concurrently alternately and oppositely biased.

23. The ion trap as claimed in claim 19 , wherein each of the first, second, third and fourth means is arranged to produce a hyberbolic electric field.

24. The ion trap as claimed in claim 19 , wherein each of the first, second, third and fourth means comprises a series of discrete electrodes.

25. The ion trap as claimed in claim 24 , wherein the series of discrete electrodes comprises a capacitive divider that is configurable to apportion different potentials to different ones of the discrete electrodes in the seri

Assignees

• Aukland Uniservices Ltd
• Auckland Uniservices Ltd

Inventors

• Derrick Peter
• Filippov Igor

Classifications

• H01J49/405

  characterised by the reflectron, e.g. curved field, electrode shapes · CPC title

• H01J49/406

  with multiple reflections · CPC title

• H01J49/408

  with multiple changes of direction, e.g. by using electric or magnetic sectors, closed-loop time-of-flight · CPC title

• H01J49/061 Primary

  Ion deflecting means, e.g. ion gates · CPC title

• H01J49/422

  Two-dimensional RF ion traps (ion guides without mass selection H01J49/062) · CPC title