Zirconium based bulk metallic glasses with hafnium
US-9353428-B2 · May 31, 2016 · US
US10144992B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10144992-B2 |
| Application number | US-201314655578-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 24, 2013 |
| Priority date | Dec 31, 2012 |
| Publication date | Dec 4, 2018 |
| Grant date | Dec 4, 2018 |
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An amorphous alloy and a method for preparing the amorphous alloy are provided. The amorphous alloy is represented by a formula of (Zr,Hf)aMbNcBed. M contains at least one element selected from transition group elements. N contains at least one selected from Al and Ti. And 40≤a≤70, 10≤b≤40, 5≤c≤20, 5≤d≤25, and a+b+c+d=100. The ratio of an atomic percentage of Hf to an atomic percentage of Zr is in a range of about 0.01 to about 5.
Opening claim text (preview).
What is claimed is: 1. An amorphous alloy represented by formula [I]: (Zr,Hf) a M b N c Be d [I] wherein M comprises at least one element selected from transition group elements; N is Al; 40≤a≤70, 10≤b≤40, 5≤c≤20, 5≤d≤25, a+b+c+d=100; and a ratio of an atomic percentage of Hf to an atomic percentage of Zr is in a range of about 0.01 to about 0.032. 2. The amorphous alloy according to claim 1 , wherein M comprises at least one selected from the group consisting of Cu, Ni, Co, Fe, Mn, Y, Nb, Ag and Ti. 3. The amorphous alloy according to claim 1 , wherein the amorphous alloy comprises an impurity, and the impurity has an atomic percentage of lower than 2%. 4. The amorphous alloy according to claim 1 , wherein 49.3≤a≤70. 5. The amorphous alloy according to claim 4 , wherein 5≤d≤15. 6. The amorphous alloy according to claim 4 , wherein either an atomic percentage of Hf equals or less than about 1.8, or an atomic percentage of Zr equals or more than about 48.45. 7. The amorphous alloy according to claim 4 , which is (Zr 57 Hf 1 Nb 5 Cu 14.4 Ni 12.6 Al 10 ) 94 Be 6 . 8. The amorphous alloy according to claim 4 , which is (Zr 57 Hf 1 Nb 5 Cu 14.4 Ni 12.6 Al 10 ) 85 Be 15 . 9. The amorphous alloy according to claim 4 , which is (Zr 63 Hf 2 Cu 12 Ti 2 Co 1 Al 10 Ni 10 ) 90 Be 10 . 10. An amorphous alloy having the formula (Zr 65 Hf 0.6 Cu 14.4 Al 10 Ni 10 ) 90 Be 10 .
Treatment of fused masses in the ladle or the supply runners before casting {(for continuous casting B22D11/10; metallurgical processing, e.g. refining of iron or other metal C21, C22, C25C)} · CPC title
using master alloys · CPC title
with molybdenum, tungsten, niobium, tantalum, titanium, or zirconium {or Hf} as the major constituent · CPC title
Making amorphous alloys · CPC title
by melting {(C22C1/1036 takes precedence)} · CPC title
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