Shear-stable oil compositions and processes for making the same

Patent metadata

Field	Value
Publication number	US-10144894-B2
Application number	US-201715425211-A
Country	US
Kind code	B2
Filing date	Feb 6, 2017
Priority date	Jul 20, 2016
Publication date	Dec 4, 2018
Grant date	Dec 4, 2018

Abstract

An oil composition comprising a first component having pendant groups and a second component but free of a third component and process for making such oil composition, where a single molecule of the third component can form large shearable stable complex structure with two molecules of the first component via van der Waals force between pendant groups and the terminal carbon chains, and a single molecule of the second component is capable of adjoining no more than one molecule of the first type. The oil composition has high shear stability making it suitable for use in lubricants subject to repeated high shear stress events.

First claim

The invention claimed is:

1. An oil composition comprising a first component and a second component differing from the first component and free of a third component, wherein:
the first component is a base stock comprising multiple molecules of a first type each having multiple pendant groups, where (i) the average pendant group length of the longest 5%, by mole, of the pendant groups of all of the molecules of the first type have an average pendant group length of Lpg(5%), where Lpg(5%)≥5.0; and (ii) a portion of the molecules of the first type have molecular weight greater than or equal to 20,000;
the second component comprises multiple molecules of a second type each of which individually is capable of adjoining no more than one molecule of the first type via van der Waals force between straight carbon chains to form a stable first complex structure; and
the third component comprises molecules of a third type each comprising two terminal carbon chains, where (i) the number average molecular weight of the third component is no greater than 2,000; and (ii) the two terminal carbon chains have chain lengths equal to or greater than 5.0 and do not share a common carbon atom.

2. The oil composition of claim 1 , wherein:
the molecules of the second type comprise one or zero terminal carbon chain that has a chain length equal to or greater than 5.0.

3. The oil composition of claim 2 , wherein:
the molecules of the second type comprise one or zero terminal carbon chain that has a chain length equal to or greater than Lpg(5%).

4. The oil composition of claim 1 , wherein:
the molecules of the second type comprise two carbon chains that extend in directions that form an angle theta in the range from 0° to 45° and that are substantially incapable of attaching to pendant groups of two differing molecules of the first type simultaneously substantially free of steric hindrance.

5. The oil composition of claim 1 , wherein:
the molecules of the second type comprise one or more terminal carbon chains having an average chain length of at least 5.0;
each of the molecules of the first type is capable of adjoining multiple molecules of the second type through the interaction between the multiple pendant groups and the terminal carbon chains of the molecules of the second type via van der Waals force to form a stable first complex structure, the first complex structures comprising a first heavy fraction thereof having an equivalent molecular weight of at least 45,000; and
the total maximum theoretical concentration of the first heavy fraction of the first complex structure, based on the total weight of the first component and the second component, is C11 wt %, and C11≤10.

6. The oil composition of claim 1 , wherein:
the second component is a PAO base stock having an isotacticity of at most 50 mol %.

7. The oil composition of claim 1 , wherein:
the second component is an alkylated aromatic hydrocarbon base stock.

8. The oil composition of claim 7 , wherein multiple molecules of the second type comprise two alkyl groups connected to aromatic ring(s) extending in directions that form an angle theta in the range from 0° to 45°, and are substantially incapable of attaching to pendant groups of two differing molecules of the first type simultaneously substantially free of steric hindrance.

9. The oil composition of claim 1 , wherein the second component is a lubricant additive.

10. The oil composition of claim 1 , wherein the first component is a PAO base stock having a KV100 of at least 50 cSt.

11. The oil composition of claim 1 , having shear stability performance as follows:
SS100≤5%;
SS192≤10%; and
SS192>SS100.

12. A process for forming a lubricant oil, comprising the following steps:
(I) providing a first component comprising multiple molecules of the first type each having multiple pendant groups, where (i) the average pendant group length of the longest 5%, by mole, of the pendant groups of all of the molecules of the first type have an average pendant group length of Lpg(5%), where Lpg(5%)≥5.0; and (ii) a portion of the molecules of the first type have molecular weight greater than or equal to 20,000;
(II) providing a second component comprising multiple molecules of the second type each of which individually is capable of adjoining no more than one molecule of the first type via van der Waals force between straight carbon chains to form a stable first complex structure;
(III) mixing the first component in a first quantity, the second component in a second quantity, and optionally other components to obtain an oil composition free of a third component, wherein:
the second component comprises multiple molecules of the second type each comprising two terminal carbon chains, where (i) the number average molecular weight of the second component is no greater than 2,000; and (ii) the two terminal carbon chains have chain lengths equal to or greater than 5.0 and do not share a common carbon atom.

13. The process of claim 12 , wherein:
the molecules of the second type comprise two carbon chains that extend in directions that form an angle theta in the range from 0° to 45° and that are substantially incapable of attaching to pendant groups of two differing molecules of the first type simultaneously substantially free of steric hindrance.

14. The process of claim 12 , wherein:
the molecules of the second type comprise one or more terminal carbon chains;
each of the molecules of the first type is capable of adjoining multiple molecules of the second type through the interaction between the multiple pendant groups and the terminal carbon chains of the molecules of the second type via van der Waals force to form a stable first complex structure, the first complex structures comprising a first heavy fraction thereof having an equivalent molecular weight of at least 45,000; and
the total maximum theoretical concentration of the first heavy fraction of the first complex structure, based on the total weight of the first component and the second component, is C11 wt %, and C11≤10.

15. The process of claim 12 , wherein:
the second component is an alkylated aromatic hydrocarbon base stock.

16. The process of claim 12 , wherein the second component is a lubricant additive.

17. The process of claim 12 , wherein the first component is a PAO base stock having a KV100 of at least 50 cSt.

18. The process of claim 12 , wherein the oil composition has shear stability performances as follows:
SS20≤10%; and
SS100≤15%.

19. The process of claim 12 , wherein the oil composition has shear stability performances as follows:
SS100≤5%;
SS192≤10%; and
SS192>SS100.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Han Wenning W
• Pafford Bernie J

Classifications

• C10N2030/68

  Shear stability · CPC title

• C10M105/36 Primary

  of polycarboxylic acids · CPC title

• C10M2205/0285

  used as base material · CPC title

• C10M105/04

  aliphatic · CPC title

• C10M2203/065

  used as base material · CPC title