Method for preparing coal mixture for cokemaking, coal mixture, and method for producing coke

Patent metadata

Field	Value
Publication number	US-10144891-B2
Application number	US-201314388578-A
Country	US
Kind code	B2
Filing date	Mar 25, 2013
Priority date	Mar 27, 2012
Publication date	Dec 4, 2018
Grant date	Dec 4, 2018

Abstract

Provided is a method for preparing a coal mixture used for the purpose of producing coke with desired strength by taking into account the compatibility between coals for cokemaking. In the case of preparing a coal mixture, used as at least one portion of a coal blend for cokemaking, containing two or more types of coals with different surface tensions, the blending ratio of each of the coals is adjusted using the surface tension of a semicoke mixture obtained from the coal mixture as an indicator.

First claim

The invention claimed is:

1. A method for preparing a coal mixture for cokemaking, the coal mixture containing two or more types of coals with different surface tensions,
the method comprising:
adjusting a blending ratio of each of the coals using a surface tension of a semicoke mixture obtained from the coal mixture as an indicator; and
blending the two or more types of coals according to the adjusted blending ratio to create the coal mixture, the coal mixture being mixed with other coal to create a coal blend for cokemaking;
wherein the adjusting comprises adjusting the blending ratio such that the surface tension of the semicoke mixture is within the range of ±1.5 mN/m from a surface tension of semicoke obtained by thermally treating the other coal.

2. The method according to claim 1 , wherein the surface tension of the semicoke mixture is a value that is determined by weighted-averaging surface tensions of two or more types of semicokes using the blending ratios of the coals contained in the coal mixture as weights, the two or more types of semicokes being obtained by thermally treating the coals contained in the coal mixture.

3. The method according to claim 1 , wherein the surface tension of the semicoke obtained by thermally treating the rest of the coal blend is a value that is determined by weighted-averaging the surface tensions of semicokes obtained by thermally treating at least two types of coals contained in the rest of the coal blend using the blending ratios of the at least two types of coals contained in the rest of the coal blend as weights.

4. The method according to claim 1 , wherein the surface tension of the semicoke obtained by thermally treating the rest of the coal blend is a surface tension of semicoke obtained by thermally treating one type of coal of at least one type of coal contained in the rest of the coal blend, the content of the one type of coal being highest.

5. The method according to claim 1 , wherein the surface tension of the semicoke obtained by thermally treating the rest of the coal blend is a value that is determined by weighted-averaging the surface tensions of plural types of semicokes using the blending ratios of the plural types of coals as weights, the plural types of semicokes being obtained by thermally treating plural types of coals contained in the rest of the coal blend, the sum of the mass contents of the plural types of coals being 50% by mass or more.

6. A method for preparing a coal mixture for cokemaking, the coal mixture containing two or more types of coals with different surface tensions,
the method comprising:
adjusting a blending ratio of each of the coals using a surface tension of a semicoke mixture obtained from the coal mixture as an indicator; and
blending the two or more types of coals according to the adjusted blending ratio to create the coal mixture, the coal mixture being mixed with other coal to create a coal blend for cokemaking;
wherein the adjusting comprises adjusting the blending ratio such that the semicoke mixture has such a surface tension that the interfacial tension between the semicoke mixture and semicoke obtained by thermally treating one type of coal of at least one type of coal contained in the other coal, the mass content of the one type of coal being 50% by mass or more, is 0.03 mN/m or less.

7. The method according to claim 6 , wherein the interfacial tension is calculated by the following equation:
[Math. 2]
γ AB =γ A +γ B −2ϕ√{square root over (γ A γ B )}  (2)

where
γ A is a surface tension of the semicoke obtained by thermally treating the one type of coal,
γ B is a surface tension of the semicoke mixture,
γ AB is a interfacial tension, and
ϕ is an interaction coefficient.

8. The method according to claim 6 , wherein the Interfacial tension is calculated by the following equation:
[Math. 3]
γ AB =γ A +γ B −2exp[−β(γ A −γ B ) 2 ]√{square root over (γ A γ B )}  (3)

where
γ A is a surface tension of the semicoke obtained by thermally treating the one type of coal,
γ B is a surface tension of the semicoke mixture,
γ AB is a interfacial tension, and
β is a constant.

9. A method for preparing a coal mixture for cokemaking, the coal mixture containing two or more types of coals with different surface tensions,
the method comprising:
adjusting a blending ratio of each of the coals using a surface tension of a semicoke mixture obtained from the coal mixture as an indicator; and
blending the two or more types of coals according to the adjusted blending ratio to create the coal mixture, the coal mixture being mixed with other coal to create a coal blend for cokemaking,
wherein the adjusting comprises adjusting the blending ratio such that the semicoke mixture has such a surface tension that the interfacial tension between the semicoke mixture and plural types of semicokes obtained by thermally treating plural types of coals in the other coal, the sum of the mass contents of the plural types of coals being 50% by mass or more, is 0.03 mN/m or less.

10. The method according to claim 9 , wherein the interfacial tension is calculated by the following equation:
[Math. 2]
γ AB =γ A +γ B −2ϕ√{square root over (γ A γ B )}  (2)

where
γ A is a surface tension of the plural types of semicokes,
γ B is a surface tension of the semicoke mixture,
γ AB is a interfacial tension, and
ϕ is an interaction coefficient.

11. The method according to claim 9 , wherein the interfacial tension is calculated by the following equation:
[Math. 3]
γ AB =γ A +γ B −2exp[−β(γ A −γ B ) 2 ]√{square root over (γ A γ B )}  (3)

where
γ A is a surface tension of the plural types of semicokes,
γ B is a surface tension of the semicoke mixture,
γ AB is a interfacial tension, and
β is a constant.

12. A method for preparing a coal mixture for cokemaking, the coal mixture containing two or more types of coals,
the method comprising:
determining a blending ratio of the coal mixture in the coal blend in advance in the case of using the coal mixture being as a portion of the coal blend;
determining a type and a blending ratio of coal contained in the rest of the coal blend excluding the coal mixture; and
adjusting the blending ratio of each coal in the coal mixture such that the interfacial tension (γ blend ) of semicoke obtained by thermally treating the coal blend is 0.03 mN/m or less.

13. The method according to claim 1 , wherein the interfacial tension is determined by a film floatation method.

14. A coal mixture produced by the preparation method according to claim 1 .

15. A method for producing coke, comprising:
blending the coal mixture according to claim 1 with the other coal to create the coal blend; and
carbonizing the coal blend to form the coke.

Assignees

• Jfe Steel Corp

Inventors

• Shimoyama Izumi
• Anyashiki Takashi
• Fukada Kiyoshi
• Fujimoto Hidekazu
• Sumi Hiroyuki

Classifications

• G01N33/222

  Solid fuels, e.g. coal · CPC title

• G01N13/02

  Investigating surface tension of liquids · CPC title

• C10L2290/24

  Mixing, stirring of fuel components · CPC title

• C10L5/04 Primary

  Raw material {of mineral origin} to be used; Pretreatment thereof {(pretreatment of fuels of non-mineral origin C10L5/40)} · CPC title

• C10B57/04 Primary

  using charges of special composition · CPC title