Small scale modular gas to liquids plant for stranded remote gas

Patent metadata

Field	Value
Publication number	US-10144877-B2
Application number	US-201615011717-A
Country	US
Kind code	B2
Filing date	Feb 1, 2016
Priority date	Feb 1, 2016
Publication date	Dec 4, 2018
Grant date	Dec 4, 2018

Abstract

A method of processing stranded remote gas comprising (a) introducing stranded remote gas and steam to a reforming unit to produce synthesis gas (syngas), wherein the stranded remote gas comprises methane, carbon dioxide, and sulfur-containing compounds, and wherein the syngas is characterized by a molar ratio of hydrogen to carbon monoxide of from about 1.7:1 to about 2.5:1; (b) introducing at least a portion of the syngas to a Fischer-Tropsch (FT) unit to produce an FT syncrude product, FT water, and FT tail gas, wherein the FT syncrude product comprises FT hydrocarbon liquids, wherein the FT syncrude product comprises FT wax in an amount of less than about 5 wt. %, and wherein the FT unit is characterized by an FT reaction temperature of from about 300° C. to about 350° C.; and (c) blending the FT syncrude product with crude oil for storage and/or transport.

First claim

What is claimed is:

1. A method of processing stranded remote gas comprising:
(a) introducing stranded remote gas and steam to a reforming unit to produce synthesis gas (syngas), wherein the stranded remote gas comprises methane, carbon dioxide, and sulfur-containing compounds, and wherein the syngas is characterized by a molar ratio of hydrogen to carbon monoxide of from about 1.7:1 to about 2.5:1;
(b) introducing at least a portion of the syngas to a Fischer-Tropsch (FT) unit to produce an FT syncrude product, FT water, and FT tail gas, wherein the FT syncrude product comprises FT hydrocarbon liquids, wherein the FT syncrude product comprises FT wax in an amount of less than 5 wt. %, and wherein the FT unit is characterized by an FT reaction temperature of from about 300° C. to about 350° C.; and
(c) without separating the FT syncrude product into fractions, blending the FT syncrude product with crude oil from a wellbore for storage and/or transport.

2. The method of claim 1 , wherein at least a portion of the FT water is introduced to a wellbore for oil recovery.

3. The method of claim 2 , wherein the oil recovery comprises hydraulic fracturing, water flooding, enhanced oil recovery, steam injection, or combinations thereof.

4. The method of claim 1 , wherein the FT water comprises water and hydrocarbons, and wherein the method excludes treating the FT water for hydrocarbon removal.

5. The method of claim 4 , wherein a portion of the FT water is used for producing the steam that is introduced to the reforming unit, and wherein at least a portion of the hydrocarbons of the FT water is converted to syngas in the reforming unit.

6. The method of claim 1 , wherein a molar ratio of carbon dioxide to carbon in hydrocarbons of total feed streams to the reforming unit is from about 0.4:1 to about 0.8:1.

7. The method of claim 1 excluding separating at least a portion of the carbon dioxide from the stranded remote gas prior to introducing the stranded remote gas to the reforming unit.

8. The method of claim 1 , wherein the sulfur-containing compounds comprise hydrogen sulfide.

9. The method of claim 1 , wherein a molar ratio of steam to carbon in hydrocarbons of total feed streams to the reforming unit is from about 0.65:1 to about 2.0:1.

10. The method of claim 1 , wherein the reforming unit comprises a nickel-based catalyst and/or a sulfur passivated nickel-based catalyst.

11. The method of claim 1 , wherein the FT syncrude product is miscible with the crude oil.

12. The method of claim 1 , wherein the FT syncrude product is a value added product for crude oil.

13. The method of claim 1 , wherein the FT syncrude product comprises sulfur in an amount of less than about 2 ppb.

14. The method of claim 11 excluding storing the FT syncrude product on-site for a time period greater than about 8 hours, prior to blending the FT syncrude product with the crude oil.

15. The method of claim 1 excluding separating the FT syncrude product into fractions prior to blending the FT syncrude product with crude oil.

16. The method of claim 1 , wherein a portion of the FT tail gas is used as fuel for heating the reforming unit, a pre-reforming unit, or combinations thereof.

17. The method of claim 1 , wherein the FT tail gas comprises olefins, unreacted syngas, and carbon dioxide, wherein the unreacted syngas comprises carbon monoxide and hydrogen, wherein at least a portion of the FT tail gas and steam are introduced to a pre-reforming unit to produce hydrogenated hydrocarbons, wherein at least a portion of the olefins react with at least a portion of the hydrogen to produce the hydrogenated hydrocarbons.

18. The method of claim 17 , wherein at least a portion of the hydrogenated hydrocarbons are introduced to the reforming unit, and wherein at least a portion of the hydrogenated hydrocarbons is converted to syngas in the reforming unit.

19. The method of claim 17 , wherein at least a portion of the stranded remote gas is introduced to the pre-reforming unit, and wherein at least a portion of the stranded remote gas and at least a portion of the hydrogenated hydrocarbons are communicated from the pre-reforming unit to the reforming unit.

20. The method of claim 1 , further comprising setting up at least one modular system for processing the stranded remote gas at a wellbore site, wherein each modular system comprises a pre-reforming unit, a reforming unit, and an FT unit.

21. A method of processing stranded remote gas comprising:
(a) introducing stranded remote gas and steam to a reforming unit to produce synthesis gas (syngas), wherein the stranded remote gas comprises methane, carbon dioxide, and sulfur-containing compounds, and wherein the syngas is characterized by a molar ratio of hydrogen to carbon monoxide of from about 1.7:1 to about 2.5:1;
(b) introducing at least a portion of the syngas to a Fischer-Tropsch (FT) unit to produce an FT syncrude product, FT water, and FT tail gas, wherein the FT syncrude product comprises FT hydrocarbon liquids, wherein, without separating the FT syncrude product into fractions, the FT syncrude product comprises FT wax in an amount of less than 5 wt. %, and wherein the FT unit is characterized by an FT reaction temperature of from about 300° C. to about 350° C.; and
(c) introducing at least a portion of the FT water to a wellbore for enhanced oil recovery.

22. The method of claim 21 , further comprising setting up at least one modular system for processing the stranded remote gas at a wellbore site, wherein each modular system comprises a pre-reforming unit, a reforming unit, and an FT unit.

23. A method of processing stranded remote gas comprising:
(a) setting up at least one modular system for processing stranded remote gas at a wellbore site, wherein each modular system comprises a pre-reforming unit, a reforming unit, and a Fischer-Tropsch (FT) unit;
(b) introducing stranded remote gas and steam to the reforming unit to produce synthesis gas (syngas), wherein the stranded remote gas is recovered at the wellbore site, wherein the stranded remote gas comprises methane, carbon dioxide, and sulfur-containing compounds, and wherein the syngas is characterized by a molar ratio of hydrogen to carbon monoxide of from about 1.7:1 to about 2.5:1;
(c) introducing at least a portion of the syngas to the FT unit to produce an FT syncrude product, FT water, and FT tail gas, wherein the FT syncrude product comprises FT hydrocarbon liquids, wherein the FT syncrude product comprises FT wax in an amount of less than 5 wt. %, and wherein the FT unit is characterized by an FT reaction temperature of from about 300° C. to about 350° C.;
(d) introducing at least a portion of the FT water to a wellbore for oil recovery;
(e) recovering a crude oil from the wellbore;
(f) without separating the FT syncrude product into fractions, blending the FT syncrude product with the crude oil from the wellbore, wherein the FT syncrude product is miscible with the crude oil;
(g) introducing at least a portion of the FT tail gas and steam to the pre-reforming unit to produce hydrogenated hydrocarbons, wherein the FT tail gas comprises olefins, unreacted syngas, and carbon dioxide, wherein the unreacted syngas comprises carbon monoxide and hydrogen, and wherein at least a portion of the olefins react with at least a portion of the hydrogen to produce the hydrogenated hydrocarbons; and
(h) introducing at least a portion of the hydrogenated hydrocarbons to the reforming un

Assignees

• Fluor Tech Corp

Inventors

• Ravikumar Ravi
• Koppel Paul
• Dabee Sanjiv

Classifications

• C09K8/66

  Compositions based on water or polar solvents (C09K8/64 takes precedence) · CPC title

• C09K8/592

  Compositions used in combination with generated heat, e.g. by steam injection · CPC title

• E21B43/24

  using heat, e.g. steam injection · CPC title

• C09K8/58

  Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids · CPC title

• C01B2203/062

  Hydrocarbon production, e.g. Fischer-Tropsch process · CPC title