Rigid renewable polyester compositions having a high impact strength and tensile elongation

Patent metadata

Field	Value
Publication number	US-10144825-B2
Application number	US-201514618267-A
Country	US
Kind code	B2
Filing date	Feb 10, 2015
Priority date	Feb 10, 2012
Publication date	Dec 4, 2018
Grant date	Dec 4, 2018

Abstract

A thermoplastic composition that contains a rigid renewable polyester and a polymeric toughening additive is provided. The toughening additive can be dispersed as discrete physical domains within a continuous matrix of the renewable polyester. An increase in the deformation force and elongational strain causes debonding to occur in the renewable polyester matrix at those areas located adjacent to the discrete domains. This can result in the formation of a plurality of voids adjacent to the discrete domains that can help to dissipate energy under load and increase impact strength. To even further increase the ability of the composition to dissipate energy in this manner, an interphase modifier may be employed that reduces the degree of friction between the toughening additive and renewable polyester and thus enhances the degree and uniformity of debonding.

First claim

What is claimed is:

1. A melt blended, thermoplastic composition comprising:
a rigid polyester having a glass transition temperature of from 30° C. to 100° C., wherein the polyester constitutes about 70 wt. % or more of the thermoplastic composition;
from about 1 wt. % to about 30 wt. % of at least one polymeric toughening additive based on the weight of the polyester;
from about 0.1 wt. % to about 20 wt. % of at least one interphase modifier based on the weight of the polyester, wherein the interphase modifier comprises a silicone, a silicone-polyether copolymer, an alkylene glycol, an alkane diol, an amine oxide, a fatty acid ester, or a combination thereof; and
wherein the thermoplastic composition has a morphology in which a plurality of discrete primary domains are dispersed within a continuous phase, the domains containing the polymeric toughening additive and the continuous phase containing the polyester,
wherein the ratio of the glass transition temperature of the thermoplastic composition to the glass transition temperature of the polyester is from about 0.7 to about 1.3, and
wherein the thermoplastic composition has a tensile modulus of from about 500 to about 3800 MPa.

2. The thermoplastic composition of claim 1 , wherein polyester and the thermoplastic composition have a glass transition temperature of from about 50° C. to about 75° C.

3. The thermoplastic composition of claim 1 , wherein the ratio of the solubility parameter for the polyester to the solubility parameter of the polymeric toughening additive is from about 0.5 to about 1.5.

4. The thermoplastic composition of claim 3 , wherein the polymeric toughening additive has a solubility parameter of from about 15 to about 30 MJoules 1/2 /m 3/2 .

5. The thermoplastic composition of claim 1 , wherein the ratio of the melt flow rate for the polyester to the melt flow rate of the polymeric toughening additive is from about 0.2 to about 8.

6. The thermoplastic composition of claim 1 , wherein the ratio of the Young's modulus elasticity of the polyester to the Young's modulus of elasticity of the polymeric toughening additive is from about 2 to about 500.

7. The thermoplastic composition of claim 1 , wherein the polyolefin is a propylene homopolymer, propylene/α-olefin copolymer, ethylene/α-olefin copolymer, or a combination thereof.

8. The thermoplastic composition of claim 1 , wherein the interphase modifier has a kinematic viscosity of from about 0.7 to about 200 centistokes, determined at a temperature of 40° C.

9. The thermoplastic composition of claim 1 , wherein the interphase modifier is hydrophobic.

10. The thermoplastic composition of claim 1 , wherein the interphase modifier is an alkylene glycol, an alkane diol, a fatty acid ester, or a combination thereof.

11. The thermoplastic composition of claim 1 , wherein the discrete domains have a length of from about 0.05 micrometers to about 30 micrometers.

12. The thermoplastic composition of claim 1 , wherein the compatibilizer comprises a polyepoxide modifier.

13. The thermoplastic composition of claim 12 , wherein the polyepoxide modifier includes an epoxy-functional (meth)acrylic monomeric component.

14. The thermoplastic composition of claim 13 , wherein the polyepoxide modifier is poly(ethylene-co-methacrylate-co-glycidyl methacrylate).

15. The thermoplastic composition of claim 1 , wherein the composition exhibits an Izod impact strength of about 0.3 Joules per centimeter or more, measured at 23° C. according to ASTM D256-10 (Method A), and a tensile elongation at break of about 10% or more, measured at 23° C. according to ASTM D638-10.

16. The thermoplastic composition of claim 1 , wherein the composition exhibits an Izod notched impact strength of from about 0.8 Joules per centimeter to about 2.5 Joules per centimeter, measured at 23° C. according to ASTM D256-10 (Method A).

17. The thermoplastic composition of claim 1 , wherein the composition exhibits a tensile elongation at break of from about 100% to about 300%, measured at 23° C. according to ASTM D638-10.

18. The thermoplastic composition of claim 1 , wherein the rigid polyester comprises polylactic acid.

19. The thermoplastic composition of claim 1 , wherein the rigid polyester comprises polyethylene terephthalate.

20. The thermoplastic composition of claim 1 , wherein the rigid polyester constitutes from about 80 wt. % to about 99 wt. % of the thermoplastic composition.

21. The thermoplastic composition of claim 1 , wherein the polymeric toughening additive includes a polyolefin.

22. The thermoplastic composition of claim 1 , wherein the composition further includes a compatibilizer.

23. The thermoplastic composition of claim 22 , wherein the compatibilizer is present in an amount of from about 0.5 wt. % to about 20 wt. %, based on the weight of the composition.

Assignees

• Kimberly Clark Co

Inventors

• Topolkaraev Vasily A
• Scholl Neil T
• Mceneany Ryan J
• Eby Thomas A

Classifications

• C08L23/10

  Homopolymers or copolymers of propene · CPC title

• C08L67/04 Primary

  Polyesters derived from hydroxycarboxylic acids, e.g. lactones (C08L67/06 takes precedence) · CPC title

• C08J2363/00

  Characterised by the use of epoxy resins; Derivatives of epoxy resins · CPC title

• C08L23/0807

  with unsaturated hydrocarbons only containing four or more carbon atoms · CPC title

• C08J9/0061

  characterized by the use of several polymeric components · CPC title