Spherical alumina powder and resin composition using same

Patent metadata

Field	Value
Publication number	US-10144816-B2
Application number	US-201515328785-A
Country	US
Kind code	B2
Filing date	Jul 28, 2015
Priority date	Jul 28, 2014
Publication date	Dec 4, 2018
Grant date	Dec 4, 2018

Abstract

Provided is a spherical alumina powder which, when incorporated into resins in a high concentration, enables a resin composition to have low viscosity and which has reduced viscosity increase in the resin composition over time after surface treatment of the spherical alumina powder. The spherical alumina powder has an alkyl group(s) derived from a silane compound(s) on its surface, and is characterized in that an intensity ratio {I (CH3)/I (CH2)} of a peak (2960±5 cm−1) associated with asymmetric vibration of CH3 to a peak (2925±5 cm−1) associated with asymmetric vibration of CH2 in the alkyl group(s) of the silane compound(s) in the same spectral data obtained by infrared spectroscopic analysis measurement is 0.2 or more and less than 2.0.

First claim

The invention claimed is:

1. A surface-treated spherical alumina powder surface treated by at least one silane compound, the surface-treated spherical alumina powder comprising at least one alkyl group derived from the at least one silane compound on a surface of the spherical alumina powder, wherein a peak intensity ratio {I (CH 3 )/I (CH 2 )} of a peak (2960±5 cm −1 ) associated with asymmetric vibration of CH 3 to a peak (2925±5 cm −1 ) associated with asymmetric vibration of CH 2 in the at least one alkyl group in the same spectral data obtained by infrared spectroscopic analysis measurement is 0.2 or more and less than 2.0, wherein a total carbon content in the spherical alumina powder is from 0.05 to 0.9% by mass, and wherein the surface-treated spherical alumina powder has been treated by at least one silane compound of chemical formula (1) and at least one silane compound of chemical formula (2), and the at least one alkyl group is a plurality of alkyl groups comprising at least one alkyl group derived from chemical formula (1) and at least one alkyl group derived from chemical formula (2):
CH 3 (CH 2 ) n SiX 3   Chemical Formula (1)

with X=a methoxy group or an ethoxy group, and n=an integer from 5 to 15; and
(CH 3 ) 3 SiX  Chemical Formula (2)

with X=a methoxy group or an ethoxy group.

2. The surface-treated spherical alumina powder according to claim 1 , wherein an average particle size is 0.1 to 100 μm and average sphericity is 0.85 or more.

3. The surface-treated spherical alumina powder according to claim 1 , wherein the total carbon content is from 0.1 to 0.6% by mass.

4. A resin composition comprising the surface-treated spherical alumina powder according to claim 1 .

5. A method for producing the surface-treated spherical alumina powder according to claim 1 , comprising a plurality of alkyl groups, said method comprising performing a surface treatment of a spherical alumina powder with both of the following silane compounds of the chemical formulae (1) and (2):
CH 3 (CH 2 ) n SiX 3   Chemical Formula (1)

with X=a methoxy group or an ethoxy group, and n=an integer from 5 to 15; and
(CH 3 ) 3 SiX  Chemical Formula (2)

with X=a methoxy group or an ethoxy group,

to adjust the peak intensity ratio {I (CH 3 )/I (CH 2 )} of the peak (2960±5 cm −1 ) associated with asymmetric vibration of CH 3 to the peak (2925±5 cm −1 ) associated with asymmetric vibration of CH 2 in the plurality of alkyl groups in the same spectral data obtained by infrared spectroscopic analysis measurement to 0.2 or more and less than 2.0.

6. The method for producing a surface-treated spherical alumina powder having a plurality of alkyl groups according to claim 5 , wherein the silane compound of the chemical formula (1) is used in an amount of 0.2 to 2% by mass based on an outer percentage relative to the spherical alumina powder, and the silane compound of the chemical formula (2) is used in an amount of 0.1 to 6% by mass based on the outer percentage relative to the spherical alumina powder.

7. The method for producing a surface-treated spherical alumina powder having a plurality of alkyl groups according to claim 5 , further comprising performing a drying treatment of the surface-treated spherical alumina such that a total carbon content of the surface-treated spherical alumina after the drying treatment is 0.05 to 0.9% by mass.

8. The method for producing a surface-treated spherical alumina powder having a plurality of alkyl groups according to claim 5 , wherein the surface treatment of the spherical alumina powder is performed to adjust the peak intensity ratio {I (CH 3 )/I (CH 2 )} to 0.5 or more and 1.0 or less.

9. The method for producing surface-treated spherical alumina powder having a plurality of alkyl groups according to claim 5 , wherein an average particle size of the spherical alumina powder is 0.1 to 100 μm and an average sphericity is 0.85 or more.

10. The method for producing a surface-treated spherical alumina powder having a plurality of alkyl groups according to claim 5 , further comprising performing a drying treatment of the surface-treated spherical alumina such that a total carbon content of the surface-treated spherical alumina after the drying treatment is 0.1 to 0.6% by mass.

Assignees

• Denka Company Ltd

Inventors

• Ikeda Kazuyoshi
• Fukazawa Motoharu
• Komaki Takafumi

Classifications

• C01F7/021

  After-treatment of oxides or hydroxides · CPC title

• C08K2201/005

  Additives being defined by their particle size in general · CPC title

• C01F7/02

  Aluminium oxide; Aluminium hydroxide; Aluminates · CPC title

• C08K2201/016

  Additives defined by their aspect ratio · CPC title

• C08K9/06 Primary

  with silicon-containing compounds · CPC title