Polyethylene homo- or copolymer having improved wear properties

Patent metadata

Field	Value
Publication number	US-10144788-B2
Application number	US-201515526783-A
Country	US
Kind code	B2
Filing date	Oct 27, 2015
Priority date	Nov 18, 2014
Publication date	Dec 4, 2018
Grant date	Dec 4, 2018

Abstract

The present invention relates to a polyethylene homo- or copolymer having improved wear properties. In particular, the invention relates to an ultra-high molecular weight polyethylene having improved wear properties prepared using a heterogeneous Ziegler catalyst system. Said polyethylene homo- or copolymer is characterized in that the abrasion index of said polyethylene is related to the elongational stress according to the formula (I): in which ES=elongational stress as measured according to ISO 11542-2:1998 AI=abrasion index, as measured according to ISO 15527:2010 where the reference material according to ISO 15527:2010 is set to 100; β<1.8; and −0.015<a<−0.017.

AI
<

ES
-
β

α

(
I
)

First claim

The invention claimed is:

1. Polyethylene homo- or copolymer characterized in that the abrasion index of said polyethylene is related to the elongational stress according to the formula:

AI
<

ES
-
β

α

in which
ES=elongational stress as measured according to ISO 11542-2:1998
AI=abrasion index, as measured according to ISO 15527:2010 where the reference material according to ISO 15527:2010 is set to 100;
β<1.7; and
−0.015>α>−0.017.

2. Polyethylene according to claim 1 in which the polyethylene is produced by reacting ethylene with optionally one of more other α-olefin monomer in the presence of a Ziegler catalyst.

3. Polyethylene according to claim 1 in which the polyethylene has a molecular weight of more than 500,000 g/mol.

4. Polyethylene according to claim 1 in which the elongational stress is less than 0.5 MPa.

5. Polyethylene according to claim 1 in which the abrasion index is less than 80, said abrasion index measured according to ISO 15527:2010 where the reference material according to ISO 15527:2010 is set to 100.

6. Process for the production of polyethylene according to claim 1 in which the process comprises the polymerization of ethylene in the presence of a catalyst composition comprising
I) the product obtained by combining:
a) a hydrocarbon solution comprising:
i) a magnesium-containing compound selected from an organic oxygen-containing magnesium compound and a halogen-containing magnesium compound; and
ii) an organic oxygen-containing titanium compound;

b) a solution comprising:
i) a metal-containing compound having the formula (I):
MeR n X 3-n   (I)

in which X is a halogen, Me is a metal of group III of Mendelejev's Periodic Table of Elements, R is a hydrocarbon moiety comprising 1-10 carbon atoms, and n is 1≤n<3, or a dimer of a compound of formula (I); and
ii) a silicon-containing compound of formula R′ m SiCl 4-m in which 0≤m≤2 and R′ is a hydrocarbon moiety comprising at least one carbon atom;
in which the combination of solutions a) and b) results in a suspension of solid particles;

II) an organo aluminium compound having the formula AlR′ 3 in which R′ is a hydrocarbon moiety containing 1-10 carbon atoms, and
III) one or more of an external electron donor selected from the group of 1,2-dialkoxy hydrocarbon compounds to obtain a polyethylene powder.

7. Process according to claim 6 in which the molar ratio of the external electron donor III) to the titanium present in I) is between 0.5 and 5.5, and the span of the polyethylene powder obtained from the process as measured according to ISO-13320:2009 is between 0.9 and 1.3.

8. Process according to any claim 6 in which:
the metal-containing compound is one or more selected from n-butyl aluminium dichloride, isobutyl aluminium dichloride, diisobutyl aluminium chloride, di-n-butyl aluminium chloride, sesquiisobutyl aluminium chloride, ethyl aluminium dibromide, ethyl aluminium dichloride, propyl aluminium dichloride, diethyl aluminium chloride, and diisobutyl aluminium chloride;
the silicon-containing compound is SiCl 4 ; and
the external electron donor is one or more selected from 1,2-dimethoxybenzene, 1,2,4-trimethoxybenzene, 1,2-diethoxybenzene, 2,3-dimethoxytoluene, 1-allyl-3,4-dimethoxybenzene, 1,2-dimethoxyethane, 1,2-dimethoxy cyclohexane, 1,2-dimethoxypropane, 1,2-dimethoxybutane, and 2,3-dimethoxybutane.

9. Process according to claim 6 , wherein the process is a continuous process.

10. Polyethylene according to claim 1 , wherein β<1.5.

11. Polyethylene according to claim 10 , wherein β<1.3.

12. Polyethylene according to claim 1 , wherein −0.016>α>−0.017.

13. Polyethylene according to claim 12 , wherein −0.0165≥α>−0.017.

14. Polyethylene homo- or copolymer characterized in that the abrasion index of said polyethylene is related to the elongational stress according to the formula:

AI
<

ES
-
β

α

in which
ES=elongational stress as measured according to ISO 11542-2:1998
AI=abrasion index, as measured according to ISO 15527:2010 where the reference material according to ISO 15527:2010 is set to 100;
β<1.8; and
−0.0165≥α>−0.017.

15. Polyethylene according to claim 3 , wherein −0.016>α>−0.017.

16. Polyethylene according to claim 15 , wherein −0.0165≥α>−0.017.

Assignees

• Sabic Global Technologies Bv

Inventors

• Gerrits Niclasina Siberta Johanna Alberdina
• Friederichs Nicolaas Hendrika
• Van Kessel Matthijs

Classifications

• C08F10/02 Primary

  Ethene · CPC title

• C08F110/02 Primary

  Ethene · CPC title

• C08F2500/01

  High molecular weight, e.g. >800,000 Da. · CPC title

• C08F2500/18

  Bulk density · CPC title

• C08F4/6567

  and aluminium or compounds thereof · CPC title