Method for operating hydrogen generator, hydrogen generator, and fuel cell system

Patent metadata

Field	Value
Publication number	US-10144639-B2
Application number	US-201615063307-A
Country	US
Kind code	B2
Filing date	Mar 7, 2016
Priority date	Mar 13, 2015
Publication date	Dec 4, 2018
Grant date	Dec 4, 2018

Abstract

A method for operating a hydrogen generator includes producing a hydrogen-containing gas from a source gas fed from a hydrodesulfurizer and reforming water with a reformer; feeding part of the hydrogen-containing gas to the hydrodesulfurizer as a recycle gas, and removing a sulfur compound contained in the source gas with the hydrodesulfurizer; condensing water vapor contained in the recycle gas in a recycle-gas channel through which the recycle gas flows, and separating the resulting condensed water from the recycle-gas channel; and regulating the amount of reforming water fed to the reformer on the basis of the temperature of the reformer.

First claim

What is claimed is:

1. A method for operating a hydrogen generator, the method comprising:
producing a hydrogen-containing gas from a source gas fed from a hydrodesulfurizer and reforming water with a reformer;
feeding part of the hydrogen-containing gas to the hydrodesulfurizer as a recycle gas, and removing a sulfur compound contained in the source gas with the hydrodesulfurizer;
condensing water vapor contained in the recycle gas with a condenser disposed on a recycle-gas channel through which the recycle gas flows, and separating the resulting condensed water from the recycle-gas channel;
obtaining an amount of the condensed water at a condenser disposed on the recycle-gas channel; and
regulating an amount of reforming water fed to the reformer on a basis of a temperature of the reformer, wherein:
the amount of reforming water fed to the reformer is regulated on a basis of the amount of the condensed water at the condenser, the temperature of the reformer and at least one selected from a flow rate of the recycle gas and a temperature of the condenser.

2. The method for operating a hydrogen generator according to claim 1 , further comprising increasing the amount of reforming water fed to the reformer when the amount of condensed water is increased.

3. A hydrogen generator comprising:
a hydrodesulfurizer that removes a sulfur compound contained in a source gas by hydrodesulfurization;
a reformer that produces a hydrogen-containing gas from the source gas fed from the hydrodesulfurizer and reforming water by a reforming reaction;
a reforming-water feeder that feeds the reforming water to the reformer;
a recycle-gas channel through which part of the hydrogen-containing gas produced by the reformer is fed to the hydrodesulfurizer as a recycle gas;
a condenser disposed on the recycle-gas channel, the condenser condensing water vapor contained in the recycle gas and separating the resulting condensed water from the recycle-gas channel;
a first temperature sensor that detects a temperature of the reformer;
at least one selected from a flow sensor that detects a flow rate of the recycle gas and a second temperature sensor that detects a temperature of the condenser; and
a controller that controls the reforming-water feeder such that an amount of the reforming water is regulated on a basis of the temperature of the reformer, wherein:
the controller obtains an amount of the condensed water at a condenser disposed on the recycle-gas channel, and
the controller regulates the amount of the reforming water on the basis of the amount of the condensed water at the condenser, the temperature of the reformer and at least one selected from the flow rate of the recycle gas and the temperature of the condenser.

4. The hydrogen generator according to claim 3 ,
wherein the condenser condenses the water vapor contained in the recycle gas by cooling the recycle gas with a coolant and separates the condensed water from the recycle-gas channel.

5. The hydrogen generator according to claim 3 , wherein the controller increases the amount of reforming water fed to the reformer when the amount of condensed water is increased.

6. The hydrogen generator according to claim 3 , further comprising a recycle gas flow regulator that regulates the flow rate of the recycle gas flowing in the recycle flow passage.

7. A fuel cell system comprising:
the hydrogen generator according to claim 3 ; and
a fuel cell that generates electric power from hydrogen-containing gas fed from the hydrogen generator.

8. The fuel cell system according to claim 7 ,
wherein the fuel cell is a solid oxide fuel cell.

Assignees

• Panasonic Ip Man Co Ltd

Inventors

• Abe Miki
• Yukimasa Akinori

Classifications

• H01M2300/0071

  Oxides · CPC title

• H01M8/04097

  with recycling of the reactants (H01M8/04119, H01M8/04104 take precedence) · CPC title

• C01B3/38 Primary

  using catalysts · CPC title

• C01B3/50

  Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification · CPC title

• H01M8/0675

  Removal of sulfur · CPC title