Heat generating catalyst for hydrocarbons cracking

Patent metadata

Field	Value
Publication number	US-10144003-B2
Application number	US-201715720185-A
Country	US
Kind code	B2
Filing date	Sep 29, 2017
Priority date	May 12, 2016
Publication date	Dec 4, 2018
Grant date	Dec 4, 2018

Abstract

A method of using a heat generating catalyst in a hydrocarbon cracking process. The method includes providing a catalyst bed reactor which includes a catalyst bed of the heat generating catalyst disposed in the catalyst bed reactor. The heat generating catalyst includes at least one mordenite framework-inverted (MFI) zeolite catalyst having a Si/Al molar ratio of 15 or greater, and at least one metal oxide dispersed within a microstructure of the MFI zeolite catalyst. The method additionally includes introducing a hydrocarbon feed to the catalyst bed reactor and cracking the hydrocarbon feed to produce a cracking product. Additionally, an associated method of making the heat generating catalyst for hydrocarbon cracking is provided.

First claim

What is claimed is:

1. A method of using a heat generating catalyst in a hydrocarbon cracking process, the method comprising:
providing a catalyst bed reactor,
where the catalyst bed reactor includes a catalyst bed of the heat generating catalyst disposed in the catalyst bed reactor,
the heat generating catalyst comprising:
at least one mordenite framework-inverted (MFI) zeolite catalyst having a Si/Al molar ratio of 15 or greater, and
at least one metal oxide dispersed within a microstructure of the MFI zeolite catalyst,
where the ratio of the MFI zeolite catalyst to the metal oxide is in the range of 70:30 to 85:15 on a weight basis;

introducing a hydrocarbon feed to the catalyst bed reactor; and
cracking the hydrocarbon feed to produce a cracking product.

2. The method of claim 1 where the catalyst bed reactor comprises a fluidized bed reactor or a fixed-bed reactor.

3. The method of claim 2 where the catalyst bed reactor is a fixed-bed reactor and the catalyst bed of the heat generating catalyst comprises a layer of the heat generating catalyst disposed before a layer of MFI zeolite catalyst based on flow direction through the catalyst bed, a layer of heat generating catalyst disposed after a layer of MFI zeolite catalyst based on flow direction through the catalyst bed, or at least one layer of heat generating catalyst disposed between at least two layers of MFI zeolite catalyst based on flow direction through the catalyst bed.

4. The method of claim 1 where the at least one metal oxide is chemically bonded to the microstructure of the MFI zeolite catalyst.

5. The method of claim 1 where the heat generating catalyst further comprises a promoter, where the promoter is at least one of an alkali metal, an alkaline earth metal, a rare earth metal, a transition metal, phosphorous, and their combinations.

6. The method of claim 1 where the MFI zeolite catalyst is a ZSM-5 catalyst.

7. The method of claim 6 where the ZSM-5 catalyst is an H-ZSM-5 catalyst.

8. The method of claim 1 where the at least one metal oxide is at least one of an oxide of iron, copper, zinc, chromium, molybdenum, vanadium, cerium, manganese, bismuth, silver, cobalt, vanadium, zirconium, tungsten, magnesium, and their combinations.

9. The method of claim 1 where the at least one metal oxide comprises copper oxide.

10. The method of claim 1 where the MFI zeolite catalyst is crushed ZSM-5 catalyst having an average particle size of 5 to 850 nanometers.

Assignees

• Saudi Arabian Oil Co

Inventors

• Ali Ola S
• Al Yami Hussain
• Kaminsky Mark P
• Shaikh Sohel
• Xu Wei

Classifications

• C10G11/18

  according to the "fluidised-bed" technique · CPC title

• B01J29/90

  Regeneration or reactivation · CPC title

• B01J29/24

  Iron group metals or copper · CPC title

• B01J2229/186

  not in framework positions · CPC title

• B01J37/0209

  involving a reaction between the support and a fluid · CPC title