Multi-metallic catalyst system and use of the same in preparing upgraded fuel from biomass

Patent metadata

Field	Value
Publication number	US-10144002-B2
Application number	US-201615135054-A
Country	US
Kind code	B2
Filing date	Apr 21, 2016
Priority date	Apr 23, 2015
Publication date	Dec 4, 2018
Grant date	Dec 4, 2018

Abstract

The present disclosure provides a multi-metallic catalyst system comprising at least one support, and at least one promoter component and an active component comprising at least two metals uniformly dispersed on the support. The present disclosure also provides a process for preparing the multi-metallic catalyst system. Further, the present disclosure provides a process for preparing upgraded fuel from biomass. The process is carried out in two steps. In the first step, a biomass slurry is prepared and is heated in the presence of hydrogen and a multi-metallic catalyst that comprises at least one support, at least one promoter component, and an active component comprising at least two metals to obtain crude biofuel as an intermediate product. The intermediate product obtained in the first step is then cooled and filtered to obtain a filtered intermediate product. In the second step, the filtered intermediate product is hydrogenated in the presence of the multi-metallic catalyst to obtain the upgraded fuel. The fuel obtained from the process of the present disclosure is devoid of heteroatoms such as oxygen, nitrogen and sulfur.

First claim

The invention claimed is:

1. A process for preparing a multi-metallic catalyst system; said process comprising the following steps:
i. calcining at least one alumina support to obtain a calcined alumina support;
ii. impregnating said calcined alumina support with,
a. at least one promoter component in the presence of a stabilizing agent, followed by filtering, drying and calcining to obtain a promoter component impregnated support, wherein the promoter component is phosphorous or niobium and the stabilizing agent is hexamethyleneimine; and
b. an active component comprising cobalt and molybdenum in the presence of said stabilizing agent, followed by filtering, drying, and calcining,
wherein the process steps (a) and (b) are carried out in any sequence, to obtain a calcined alumina support impregnated with the promoter component at a concentration of 0.1 to 1 wt. % and the active component at a concentration of 0.05 to 8 wt. %; and

iii. reducing said calcined alumina support impregnated with the promoter component and the active component to obtain the multi-metallic catalyst system.

2. The process as claimed in claim 1 , further comprising sulfiding the catalyst system using at least one sulfiding agent selected from the group consisting of dimethyl disulfide and dimethyl sulfoxide.

3. The process as claimed in claim 1 , wherein the calcining is carried out at a temperature in the range of 500 to 700° C.

Assignees

• Reliance Industries Ltd

Inventors

• Mandan Chidambaram
• Mantri Kshudiram
• Bhujade Ramesh
• Sharma Nagesh
• Jasra Raksh Vir

Classifications

• C11C3/126

  using catalysts based principally on other metals or derivates · CPC title

• C10G3/46

  in combination with chromium, molybdenum, tungsten metals or compounds thereof · CPC title

• C10G3/44

  characterised by the catalyst used · CPC title

• B01J2523/00

  Constitutive chemical elements of heterogeneous catalysts · CPC title

• B01J37/28

  Phosphorising · CPC title