Activation energy reducers for catalytic oxidation of gaseous mixtures

Patent metadata

Field	Value
Publication number	US-10143998-B2
Application number	US-201715407278-A
Country	US
Kind code	B2
Filing date	Jan 17, 2017
Priority date	Feb 5, 2016
Publication date	Dec 4, 2018
Grant date	Dec 4, 2018

Abstract

The present invention provides materials for improving the ignition of gaseous reactants in metal catalyzed oxidation reactions comprising a metal catalyst gauze, preferably, a platinum/rhodium catalyst gauze, having in contact therewith, from 0.25 to 1.5 wt. %, based on the weight of the metal catalyst gauze, of one or more pieces of previously used metal catalyst gauze. Further, methods of making the metal catalyst materials comprise shaping the pieces of previously used metal catalyst gauze and placing them equidistant from each other in contact with or on the surface of the metal catalyst gauze. And methods of using the materials comprise feeding into the reactor a gas mixture of oxygen or air and one or more reactant gases, and igniting the gas mixture at the surface of one or more or all of the pieces of previously used metal catalyst.

First claim

We claim:

1. A metal catalyst material comprising a metal catalyst gauze having in contact therewith, from 0.5 to 1.5 wt. %, based on the weight of the metal catalyst gauze, of one or more pieces of previously used and untreated metal catalyst gauze, that have not been contaminated with iron and that have not been contaminated with foreign debris, hydrocarbons, or oil as tested by visual inspection, the one or more pieces placed equidistant from each other on the surface of the metal catalyst gauze, or, if one piece, placed in contact with or concentrically with the center of the metal catalyst gauze, wherein the previously used and untreated metal catalyst gauze does not contain a metal coating treatment.

2. The metal catalyst material as claimed in claim 1 , wherein the one or more pieces of previously used metal catalyst gauze comprise used platinum/rhodium catalyst gauze.

3. The metal catalyst material as claimed in claim 1 , wherein the amount of the one or more pieces of previously used metal catalyst gauze ranges from 0.5 to 1.0 wt. %, based on the weight of the metal catalyst gauze.

4. The metal catalyst material as claimed in claim 1 , wherein the one or more pieces of previously used metal catalyst gauze numbers from 2 to 20 pieces.

5. The metal catalyst material as claimed in claim 1 , wherein each of the one or more pieces of previously used metal catalyst gauze comprises a gauze of one or more metals selected from the group consisting of nickel, platinum, palladium, cobalt, rhodium, silver, gold, copper, iridium, rhenium, cerium, alloys thereof, binary alloys thereof, ternary alloys thereof, intermetallics thereof, and combinations thereof.

6. The metal catalyst material as claimed in claim 1 , wherein the metal catalyst gauze is chosen from new catalysts, used catalysts, recycled catalysts, reconditioned catalysts, damaged catalysts, contaminated catalysts and combinations thereof.

7. The metal catalyst material as claimed in claim 1 , wherein the metal catalyst gauze and the pieces of previously used metal catalyst gauze are each made from the same metal, metal alloy or combination of metals.

Assignees

• Rohm & Haas

Inventors

• Busick Jon
• Maillot Philippe P
• Mendoza Joy L

Classifications

• C01C3/0216

  characterised by the catalyst used · CPC title

• B01J35/06

  Operations & Transport · mapped topic

• B01J23/464 Primary

  Rhodium · CPC title

• Y02P20/129

  Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines · CPC title

• B01J35/58

  Fabrics or filaments · CPC title