Stabilized rhenium-based heterogeneous catalyst and use thereof

Patent metadata

Field	Value
Publication number	US-10143997-B2
Application number	US-201515524026-A
Country	US
Kind code	B2
Filing date	Aug 4, 2015
Priority date	Aug 5, 2014
Publication date	Dec 4, 2018
Grant date	Dec 4, 2018

Abstract

The present invention relates to a stabilized rhenium-based heterogeneous catalyst, obtainable by a process comprising contacting a rhenium-based heterogeneous catalyst with a stabilizing agent at a temperature in a range from 0-100° C., the stabilizing agent comprising an aliphatic hydrocarbon compound and use thereof.

First claim

The invention claimed is:

1. A process for preparing an olefin hydrocarbon compound, the process comprising:
contacting, in the absence of an olefin feed stream, a rhenium-based heterogeneous catalyst with a stabilizing agent comprising an aliphatic hydrocarbon selected from the group consisting of ethane, ethylene, propane, and propylene, to provide a stabilized rhenium-based heterogeneous catalyst, followed by
reacting the olefin feed stream in the presence of the stabilized rhenium-based heterogeneous catalyst to obtain the olefin hydrocarbon compound,
wherein the olefin feed stream comprises a C4 olefin, a C5 olefin, or a mixture thereof, and wherein the reacting is carried out at a temperature in a range from 0 to 300° C.

2. The process according to claim 1 , wherein the contacting is carried out at a temperature from 0° C. to 100° C. to provide the stabilized rhenium-based heterogeneous catalyst.

3. The process according to claim 1 , wherein the contacting is carried out at a temperature from 10° C. to 60° C. to provide the stabilized rhenium-based heterogeneous catalyst.

4. The process according to claim 1 , wherein the reacting of the olefin feed stream in the presence of the stabilized rhenium-based heterogeneous catalyst is carried out in a fixed bed reactor.

5. The process of claim 1 , wherein the olefin feed stream comprises (i) ethylene and a C4 linear olefin, (ii) ethylene and a C5 linear olefin, or (iii) ethylene and both C4 and C5 linear olefins.

6. The process according to claim 3 , wherein the contacting is carried out at a temperature from 20 to 40° C.

7. The process of claim 1 , wherein the rhenium-based heterogeneous catalyst comprises elemental rhenium or a rhenium compound, wherein rhenium is present in an amount from 0.01% to 20% by weight of the catalyst.

8. The process of claim 1 , wherein the rhenium-based heterogeneous catalyst comprises elemental rhenium or a rhenium compound, disposed on a solid support comprising Al 2 O 3 , Ga 2 O 3 , SiO 2 , GeO 2 , TiO 2 , ZrO 2 , SnO 2 , aluminosilicate, activated carbon, hydrotalcite, an anionic clay, or a mixture thereof.

9. The process of claim 8 , wherein the solid support comprises Al 2 O 3 or SiO 2 .

10. The process of claim 8 , wherein the rhenium-based heterogeneous catalyst comprises elemental rhenium, rhenium oxide, rhenium hydride, rhenium sulfide, or rhenium carbide.

11. The process of claim 1 , wherein the contacting provides the stabilized rhenium-based heterogeneous catalyst with increased conversion stability and/or increased selectivity to the olefin hydrocarbon compound, relative to performing the reacting alone.

12. The process of claim 11 , wherein the olefin feed stream comprises oxygenated compounds.

13. The process of claim 1 , wherein the olefin hydrocarbon compound is propylene that is obtained from an olefin metathesis reaction, with ethylene, of the C4 olefin and/or the C5 olefin of the olefin feed stream.

14. The process of claim 1 , wherein the rhenium-based heterogeneous catalyst has been subjected to regeneration, prior to the contacting.

15. A process for preparing an olefin hydrocarbon compound, the process comprising:
contacting, in the absence of an olefin feed stream, a rhenium-based heterogeneous catalyst with a flow of a stabilizing gas comprising an aliphatic hydrocarbon compound selected from the group consisting of ethane, ethylene, propane, and propylene, to provide a stabilized rhenium-based heterogeneous catalyst, followed by
reacting the olefin feed stream in the presence of the stabilized rhenium-based heterogeneous catalyst to obtain the olefin hydrocarbon compound,
wherein the olefin feed stream comprises at least one olefin selected from the group consisting of C4 to C12 olefins, and wherein the reacting is carried out at a temperature in a range from 0 to 300° C.

16. The process of claim 15 , wherein the olefin feed stream comprises (i) a C2 olefin and a C4 olefin or (ii) a C2 olefin and a C5 olefin.

17. The process of claim 15 , wherein the olefin feed stream comprises oxygenated compounds.

18. A process for preparing an olefin hydrocarbon compound, the process comprising:
contacting a rhenium-based heterogeneous catalyst with a stabilizing agent comprising ethane or propane, to provide a stabilized rhenium-based heterogeneous catalyst, followed by
reacting an olefin feed stream in the presence of the stabilized rhenium-based heterogeneous catalyst to obtain the olefin hydrocarbon compound,
wherein the olefin feed stream comprises at least one olefin selected from the group consisting of C2 to C12 olefins, and wherein the reacting is carried out at a temperature in a range from 0 to 300° C.

19. The process of claim 18 , wherein the contacting provides the stabilized rhenium-based heterogeneous catalyst with increased conversion stability and/or increased selectivity to the olefin hydrocarbon compound, relative to performing the reacting alone.

20. The process of claim 18 , wherein the rhenium-based heterogeneous catalyst has been subjected to regeneration, prior to the contacting.

Assignees

• Scg Chemicals Co Ltd

Inventors

• Suriye Kongkiat
• Jantharasuk Amnart
• Phongsawat Weena

Classifications

• Y02P20/52

  using catalysts, e.g. selective catalysts · CPC title

• C07C2523/08

  of gallium, indium or thallium · CPC title

• C07C2521/06

  Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof · CPC title

• C07C2523/36

  Rhenium · CPC title

• B01J2231/54

  Metathesis reactions, e.g. olefin metathesis · CPC title