Electrode, nonaqueous electrolyte battery, battery pack, and vehicle

Patent metadata

Field	Value
Publication number	US-10141575-B2
Application number	US-201715459242-A
Country	US
Kind code	B2
Filing date	Mar 15, 2017
Priority date	Sep 21, 2016
Publication date	Nov 27, 2018
Grant date	Nov 27, 2018

Abstract

According to one embodiment, an electrode is provided. The electrode includes a current collector and an electrode layer. The electrode layer is disposed on the current collector and includes lithium fluoride. A first content of lithium fluoride in a first region is 0.02% by weight or more and less than 2% by weight. The first region is adjacent to an interface between the electrode layer and the current collector, and has a first thickness equal to 20% with respect to a thickness of the electrode layer. A second content of lithium fluoride in a second region is from 2% by weight to 10% by weight. The second region is adjacent to a surface on a reverse side of the electrode layer, and has the first thickness.

First claim

What is claimed is:

1. An electrode comprising:
a current collector; and
an electrode layer disposed on the current collector and including lithium fluoride,
wherein a first content of lithium fluoride based on a weight of the electrode layer in a first region of the electrode layer is within a range of 0.02% by weight or more and less than 2% by weight, the first region being adjacent to an interface between the electrode layer and the current collector, and having a first thickness equal to 20% with respect to a thickness of the electrode layer,
and a second content of lithium fluoride based on a weight of the electrode layer in a second region of the electrode layer is within a range of from 2% by weight to 10% by weight, the second region being adjacent to a surface on a reverse side of the electrode layer with respect to the interface between the electrode layer and the current collector, and having the first thickness.

2. The electrode according to claim 1 , wherein a third content of lithium fluoride in a third region of the electrode layer between the first region and the second region is within a range of from the first content of lithium fluoride to the second content of lithium fluoride.

3. The electrode according to claim 1 , wherein the electrode layer includes a first layer and a second layer, the first layer including the first region, and the second layer including the second region.

4. A nonaqueous electrolyte battery comprising:
a positive electrode;
a negative electrode including an active material, the active material including a titanium-containing oxide; and
a nonaqueous electrolyte,
wherein at least one of the positive electrode and the negative electrode includes the electrode according to claim 1 .

5. The nonaqueous electrolyte battery according to claim 4 , wherein the titanium-containing oxide includes at least one selected from the group consisting of spinel type lithium titanate, monoclinic β type titanium oxide, Ti 1-x M1 x Nb 2-y M2 y O 7-δ , where 0≤x<1, 0≤y<1, −0.5≤δ≤0.5, M1 is at least one selected from the group consisting of Mg, Fe, Ni, Co, W, Ta, and Mo, and M2 is at least one selected from the group consisting of Mg, Fe, Ni, Co, W, Ta, and Mo, and orthorhombic type Na-containing niobium titanium composite oxide represented by Li 2+v Na 2-w M1 x Ti 6-y-z Nb y M2 z O 14+δ , where 0≤v≤4, 0<w<2, 0≤x<2, 0<y<6, 0≤z<3, y+z<6, −0.5≤δ≤0.5, M1 is at least one selected from the group consisting of Cs, K, Sr, Ba, and Ca, and M2 is at least one selected from the group consisting of Zr, Sn, V, Ta, Mo, W, Fe, Co, Mn, and Al.

6. The nonaqueous electrolyte battery according to claim 4 , wherein the positive electrode includes, as a positive electrode active material, at least one selected from the group consisting of LiMn 1-x-y Fe x A y PO 4 , where 0≤x≤1, 0≤y≤0.1, and A is at least one element selected from the group consisting of Mg, Ca, Al, Ti, Zn, and Zr, LiNi x Mn y Co 1-x-y O 2 , where 0.3≤x≤0.8 and 0.1≤y≤0.4, a spinel structure manganese oxide LiMn 2 O 4 , and LiMO 2 , where M is at least one element selected from the group consisting of Ni, Co, and Mn.

7. A battery pack comprising the nonaqueous electrolyte battery according to claim 4 .

8. The battery pack according to claim 7 further comprising:
an external power distribution terminal; and
a protective circuit.

9. The battery pack according to claim 7 , comprising a plural of the nonaqueous electrolyte batteries, the nonaqueous electrolyte batteries being electrically connected in series, in parallel, or in a combination of in a series and in parallel.

10. A vehicle comprising the battery pack according to claim 7 .

11. The vehicle according to claim 10 , wherein the battery pack is configured to recover a regenerative energy of a power of the vehicle.

Assignees

• Toshiba Kk

Inventors

• Yamashita Yasunobu
• Hoshina Keigo
• Sasakawa Tetsuya
• Isozaki Yoshiyuki
• Takami Norio

Classifications

• H01M4/485

  of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy (H01M4/505, H01M4/525 take precedence) · CPC title

• H01M4/5825

  Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines · CPC title

• H01M4/366

  as layered products · CPC title

• H01M10/05

  Accumulators with non-aqueous electrolyte (H01M10/39 takes precedence) · CPC title

• H01M2220/20

  Batteries in motive systems, e.g. vehicle, ship, plane · CPC title