Red phosphor and light emitting device including the same
US-2015349213-A1 · Dec 3, 2015 · US
US10141484B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10141484-B2 |
| Application number | US-201715605197-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 25, 2017 |
| Priority date | May 26, 2016 |
| Publication date | Nov 27, 2018 |
| Grant date | Nov 27, 2018 |
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A light emitting device includes a light emitting element having a peak emission wavelength of 410 nm to 440 nm and a phosphor member. The phosphor member includes a first phosphor having a peak emission wavelength of 430 nm to 500 nm and containing an alkaline-earth phosphate, a second phosphor having a peak emission wavelength of 440 nm to 550 nm and containing at least one of an alkaline-earth aluminate and a silicate containing Ca, Mg, and Cl, a third phosphor having a peak emission wavelength of 500 nm to 600 nm and containing a rare-earth aluminate, a fourth phosphor having a peak emission wavelength of 610 nm to 650 nm and containing a silicon nitride containing Al and at least one of Sr and Ca, and a fifth phosphor having a peak emission wavelength of 650 nm to 670 nm and containing a fluorogermanate.
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What is claimed is: 1. A light emitting device composing: a light emitting element having a peak emission wavelength in a range of 410 nm to 440 nm; and a phosphor member, the phosphor member containing a phosphor comprising: a first phosphor having a peak emission wavelength in a range of 430 nm to 500 nm and containing an alkaline-earth phosphate, which includes Cl and is activated with Eu; a second phosphor having a peak emission wavelength in a range of 440 nm to 550 nm and containing at least one of an alkaline-earth aluminate, which is activated with Eu, and a silicate, which includes Ca, Mg, and Cl and is activated with Eu; a third phosphor having a peak emission wavelength in a range of 500 nm to 600 nm and containing a rare-earth aluminate, which is activated with Ce; a fourth phosphor having a peak emission wavelength in a range of 610 nm to 650 nm and containing a silicon nitride, which includes Al and at least one of Sr and Ca and is activated with Eu; and a fifth phosphor having a peak emission wavelength in a range of 650 nm to 670 nm and containing a fluorogermanate, which is activated with Mn, wherein a percentage content of the first phosphor to a total content of the phosphor is in a range of 20 mass % to 80 mass %, wherein a content ratio of the first phosphor to the third phosphor is 0.3 to 7, wherein a half value width of the emission spectrum of the third phosphor is 95 nm to 115 nm; and wherein the light emitting device is configured to emit light of correlated color temperature in a range of 4,500 K to 5,500 K, and a ratio of peak optical intensity of the first phosphor to the light emitting element is in a range of 0.6 to 1.5, and a special color rendering Index R12 of the light emitting device is 90 or greater and a sum of special color rendering Indices R9 to R15 of the light emitting device is 660 or greater. 2. The light emitting device according to claim 1 , wherein the light emitting device is configured to emit light of correlated color temperature in a range of 4,500 K to less than 5,500 K, and a percentage content of the first phosphor with respect to a total content of the phosphor is in a range of 30 mass % to 80 mass %. 3. The light emitting device according to claim 2 , wherein a content ratio of the first phosphor with respect to the third phosphor is in a range of 0.8 to 5.5. 4. The light emitting device according to claim 1 , wherein the alkaline-earth phosphate has a composition represented by formula (1): (Ca,Sr,Ba) 5 (PO 4 ) 3 (Cl,Br):Eu (1). 5. The light emitting device according to claim 1 , wherein the alkaline-earth aluminate has a composition represented by formula (2a) and the silicate has a composition represented by formula (2b): (Sr,Ca,Ba) 4 Al 14 O 25 :Eu (2a) (Ca,Sr,Ba) 8 MgSi 4 O 16 (F,Cl,Br) 2 :Eu (2b). 6. The light emitting device according to claim 1 , wherein the rare-earth aluminate has a composition represented by formula (3): (Y,Lu,Gd) 3 (Al,Ga) 5 O 12 :Ce (3). 7. The light emitting device according to claim 1 , wherein the silicon nitride has a composition represented by formula (4): (Sr,Ca)AlSiN 3 :Eu (4). 8. The light emitting device according to claim 1 , wherein the fluorogermanate has a composition represented by formula (5a) or formula (5b): 3.5MgO.0.5MgF 2 GeO 2 :Mn (5a) ( x−s )MgO.( s/ 2)Sc 2 O 3 .y MgF 2 .c CaF 2 .(1− t )GeO 2 .( t/ 2)M t 2 O 3 :z Mn (5b) wherein, M t is at least one selected from the group consisting of Al, Ga, and In, and x, y, z, s, t, and u respectively satisfy 2≤x≤4, 0<y<1.5, 0<z<0.05, 0<s<0.5, 0<t<0.5, and 0≤u<1.5.
Arsenides; Nitrides; Phosphides · CPC title
Germanates · CPC title
with halogens · CPC title
Aluminates · CPC title
Electricity · mapped topic
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