Silicon thin film solar cell having improved haze and methods of making the same
US-9224892-B2 · Dec 29, 2015 · US
US10141460B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10141460-B2 |
| Application number | US-201414767385-A |
| Country | US |
| Kind code | B2 |
| Filing date | Feb 11, 2014 |
| Priority date | Feb 12, 2013 |
| Publication date | Nov 27, 2018 |
| Grant date | Nov 27, 2018 |
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A photovoltaic structure, or a photovoltaic structure for a roadway suitable for circulation of pedestrians and vehicles, including: at least one photovoltaic cell; and a non-opaque coating covering at least a front face of the photovoltaic cell and having an outer surface which is macrotextured and microtextured irregularly, with a mean texture depth MTD, measured according to the norm NF EN 13036-1, of between 0.2 mm and 3 mm, and a polishing resistance value PRV, according to the norm NF EN 13043, of at least PRV 44 , or PRV 50 , or PRV 53 .
Opening claim text (preview).
The invention claimed is: 1. A roadway comprising: (i) a road having a surface made of bituminous mixes or made of cement concrete, and (ii) a photovoltaic structure comprising: (a) at least one photovoltaic module adhesively bonded directly to the surface of the road, and (b) a non-opaque surfacing comprising: (1) a non-opaque matrix covering the at least one photovoltaic module, and (2) non-opaque texturing elements embedded in the non-opaque matrix, wherein the non-opaque texturing elements form reliefs of different shapes and different sizes on an outer surface of the non-opaque surfacing, the reliefs giving an irregular macrotexture and an irregular microtexture to the outer surface, with a mean texture depth measured according to the NF EN 13036-1 standard of between 0.2 mm and 3 mm and a polished stone value (PSV) of resistance to polishing according to the NF EN 13043 standard of at least PSV 44 . 2. The roadway as claimed in claim 1 , the mean texture depth being at least 0.30 mm. 3. The roadway as claimed in claim 1 , the non-opaque surfacing having a degree of transparency of greater than 50% in a range of 100 nm around a peak of efficiency of the photovoltaic module. 4. The roadway as claimed in claim 1 , a texture of the outer surface being defined at least partially by the non-opaque matrix. 5. The roadway as claimed in claim 1 , the non-opaque matrix being selected from materials of synthetic or plant origin, bituminous binders, clear road binders of synthetic or plant origin, and polymeric binders. 6. The roadway as claimed in claim 1 , a density of texturing elements at the outer surface of the non-opaque surfacing being between 0.1 kg/m 2 and 5 kg/m 2 . 7. The roadway as claimed in claim 1 , the texturing elements having a shape factor of less than 8. 8. The roadway as claimed in claim 1 , the texturing elements being arranged in a single layer. 9. The roadway as claimed in claim 1 , the texturing elements being selected from aggregates of organic or mineral, transparent or translucent, materials. 10. The roadway as claimed in claim 1 , the texturing elements having a size ranging from 0.1 mm to 10 mm. 11. A process for manufacturing a photovoltaic structure as defined in claim 1 , comprising: positioning texturing elements in a bottom of a mold; positioning one or more photovoltaic cells in the mold; and injecting or casting a non-opaque material in the fluid state into or in the mold to cover the one or more photovoltaic cells, and to retain the texturing elements. 12. A process for manufacturing a photovoltaic structure as defined in claim 1 , comprising: positioning one or more photovoltaic cells in a mold; injecting or casting a non-opaque material in fluid state into or in the mold; and before curing the material, embedding texturing elements in its surface. 13. A process for manufacturing a photovoltaic structure as defined in claim 1 , comprising: depositing a transparent polymer film on one or more photovoltaic cells; depositing texturing elements on its surface; and subjecting the structure to a hot pressurized laminator, heat ensuring softening of the film and enabling aggregates to be embedded therein. 14. The roadway as claimed in claim 1 , the roadway having a grip suitable for traffic on a pedestrian and vehicular roadway. 15. The roadway as claimed in claim 1 , the PSV value of resistance being of at least PSV 50 . 16. The roadway as claimed in claim 1 , the mean texture depth being at least 0.6 mm. 17. The roadway as claimed in claim 1 , the non-opaque surfacing having a degree of transparency of greater than 50% in a range of 500 nm to 700 nm. 18. The roadway as claimed in claim 1 , the non-opaque matrix being selected from materials of synthetic or plant origin, bituminous binders, having a penetration class according to the EN 1426 standard of 160/220, 100/150, 70/100, 50/70, 40/60, 35/50, 30/45, or 20/30 (in tenths of mm), and clear road binders of synthetic or plant origin, having a penetration class according to the EN 1426 standard of 160/220, 100/150, 70/100, 50/70, 40/60, 35/50, 30/45, or 20/30 (in tenths of mm), and polymeric binders. 19. The roadway as claimed in claim 1 , a texture of the outer surface being defined at least partially by non-opaque texturing elements of irregular shape. 20. The roadway as claimed in claim 1 , the texturing elements being arranged in a single layer sunk to mid-thickness approximately in the matrix of the non-opaque surfacing. 21. The roadway as claimed in claim 1 , the texturing elements being selected from aggregates of polycarbonate or of glass. 22. The process according to claim 11 , the texturing elements being aggregates of irregular shape arranged in a single layer. 23. The process according to claim 12 , the texturing elements being aggregates of irregular shape arranged in a single layer. 24. A roadway for pedestrian and vehicular traffic, comprising a photovoltaic structure comprising at least one photovoltaic module covered by a non-opaque surfacing having an outer surface textured with non-opaque texturing elements embedded in a non-opaque matrix, wherein the non-opaque texturing elements form reliefs of different shapes and different sizes on an outer surface of the non-opaque surfacing, the photovoltaic module being adhesively bonded directly to the surface of the roadway made of bituminous mixes or made of cement concrete. 25. The roadway as claimed in claim 1 , the photovoltaic module comprising at least one photovoltaic cell, a rear face of the photovoltaic module being sufficiently rigid and solid to protect the at least one photovoltaic cell from any puncturing by surface asperities of the road. 26. The roadway as claimed in claim 1 , a rear face of the photovoltaic module being defined by a fluorinated resin layer. 27. The roadway as claimed in claim 26 , the fluorinated resin layer having a thickness of 0.2 to 5 mm. 28. The roadway as claimed in claim 1 , the photovoltaic structure comprising a tie layer adhesively bonding the photovoltaic module to the road. 29. The roadway as claimed in claim 1 , the tie layer having been directly spread on the surface of the road, spread out as a thin layer before the photovoltaic module having been deposited thereon while the tie layer has not cured or is still viscous and tacky. 30. The roadway as claimed in claim 1 , the texturing elements having a size in a range from 0.1 mm to 1.4 mm. 31. The roadway as claimed in claim 1 , wherein a thickness of the photovoltaic structure is in a range from 0.5 to 30 mm. 32. The roadway as claimed in claim 1 , wherein a thickness of the photovoltaic structure is in a range from 0.6 to 12 mm. 33. The roadway as claimed in claim 1 , wherein the photovoltaic module comprises at least one photovoltaic cell and a layer of polymer beneath the photovoltaic cell, the layer of polymer defining a rear face of the photovoltaic module. 34. The roadway as claimed in claim 33 , the layer of polymer being fluorinated.
Electricity · mapped topic
Special pavings (specially adapted for playgrounds or sports grounds E01C13/00, for footpaths, sidewalks or cycle tracks E01C15/00); Pavings for special parts of roads or airfields (pavement lights E01C17/00; manholes or like covers or frames E02D29/14) · CPC title
in the form of floor constructions, grounds or roads · CPC title
Solar thermal · CPC title
Photovoltaic [PV] · CPC title
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