Heatable pipe

Patent metadata

Field	Value
Publication number	US-10139022-B2
Application number	US-201615076028-A
Country	US
Kind code	B2
Filing date	Mar 21, 2016
Priority date	Mar 20, 2015
Publication date	Nov 27, 2018
Grant date	Nov 27, 2018

Abstract

A heatable pipe contains a layer (layer I) of a moulding compound containing at least 40 wt. % of the following components: 1) 60 to 99 parts by wt. of a copolyamide based on hexamethylenediamine, terephthalic acid and an aliphatic dicarboxylic acid having 8 to 19 carbon atoms, and 2) 40 to 1 parts by wt. of an olefinic copolymer as impact modifier, wherein the parts by wt. of 1) and 2) sum to 100; and a conductor for electrical current which is embedded between an electrically insulating outer layer and an electrically insulating inner layer. The heatable pipe exhibits a high heat distortion temperature, very good impact resistance and a high elongation at break and is used for producing an SCR conduit, a conduit for diesel fuel or a conduit for a fuel cell system.

First claim

The invention claimed is:

1. A heatable pipe, comprising:
a layer (layer I) of a moulding compound comprising a east 40 wt. % of the following components:
1) 60 to 99 parts by wt. of a partly aromatic copolyamide containing monomer units obtained from
α) 30 to 90 mol % of a combination of hexamethylenediamine and terephthalic acid, and
β) 70 to 10 mol % of a combination of hexamethylenediamine and a linear aliphatic dicarboxylic acid having 8 to 19 carbon atoms;

wherein the mol % values relate to the sum of α) and β) and
wherein not more than 20% of the hexamethylenediamine is optionally replaced by the equivalent amount of another diamine and/or
wherein not more than 20% of the terephthalic acid is optionally replaced by the equivalent amount of another aromatic dicarboxylic acid and/or 1,4-cyclohexanedicarboxylic acid and/or
wherein not more than 20% of the repeating units containing hexamethylenediamine and linear aliphatic dicarboxylic acid are optionally replaced by the equivalent amount of units obtained from a lactam/an ω-aminocarboxylic acid having 6 to 12 carbon atoms,
2) 40 to 1 parts by wt. of an olefinic copolymer as impact modifier,
wherein the parts by wt. of 1) and 2) sum to 100; and
a conductor for electrical current which is embedded between an electrically insulating outer layer and an electrically insulating inner layer.

2. The heatable pipe according to claim 1 , wherein the layer I is the inner layer, the conductor for electrical current is a metallic conductor installed directly between the inner layer and the outer layer and the outer layer is a protective cover which is subsequently mechanically applied.

3. The heatable pipe according to claim 1 , wherein the layer I is the outer layer, the conductor for electrical current is a metallic conductor installed directly between the inner layer and the outer layer and the outer layer is a protective cover which is subsequently mechanically applied.

4. The heatable pipe according to claim 1 , wherein the layer I is the inner layer, the conductor for electrical current is a metallic conductor installed directly between the inner layer and the outer layer and the outer layer is a protective cover which is applied by extrusion.

5. The heatable pipe according to claim 1 , wherein the layer I is the outer layer, the conductor for electrical current is a metallic conductor installed directly between the inner layer and the outer layer and the outer layer is a protective cover which is applied by extrusion.

6. The heatable pipe according to claim 1 , wherein the crystallite melting point T m of the copolyamide of layer I is in the range from 220° C. to 300° C. when measured as per ISO 11357 at 2nd heating.

7. The heatable pipe according to claim 1 , wherein either the outer layer or the inner layer or both the outer layer and the inner layer are an electrically insulating layer and wherein the conductor for electrical current is a middle layer of an electrically conductive thermoplastic moulding compound in which at least one pair of electrical conductors which are spaced apart from one another is embedded.

8. The heatable pipe according to claim 7 , wherein the electrically conductive moulding compound of the middle layer comprises a member selected from the group consisting of conductive carbon black, graphite powder, graphite fibrils and mixtures thereof.

9. The heatable pipe according to claim 8 , wherein the electrically conductive moulding compound of the middle layer has a specific resistance in the range from 10 −3 to 10 10 Ωm, wherein measurement is performed as per DIN IEC 60093 in the range from 10 4 Ωm and above and as per EN ISO 3915 in the range below 10 4 Ωm.

10. The heatable pipe according to claim 9 , wherein the electrically conductive thermoplastic moulding compound of the middle layer is a moulding compound based on an aliphatic polyamide.

11. The heatable pipe according to claim 8 , wherein the electrically conductive thermoplastic moulding compound of the middle layer is a moulding compound based on an aliphatic polyamide.

12. The heatable pipe according to claim 1 , wherein the moulding compound of layer comprises 0.01 to 60 wt. % of at least one further additive.

13. The heatable pipe according to claim 12 , wherein one of the further additives is a copper-containing stabilizer.

14. An SCR conduit, a conduit for diesel fuel or a conduit for a fuel cell system, comprising:
the heatable pipe according to claim 1 .

15. A method of producing an SCR conduit, a conduit for diesel fuel or a conduit for fuel cell systems, said method comprising:
attaching a connecting element, a connector, a clip, a holder, a cable, a plug or a sealing ring to the heatable pipe according to claim 1 .

16. A method of producing an SCR conduit, a conduit for diesel fuel or conduit for fuel cell systems, said method comprising:
thermoforming of the heatable pipe according to claim 1 to impart a flexuous shape.

Assignees

• Goering Ranier
• Berger Jasmin
• Boeer Michael
• Evonik Degussa Gmbh

Inventors

• Goering Ranier
• Berger Jasmin
• Boeer Michael

Classifications

• B32B27/32

  comprising polyolefins {(comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30)} · CPC title

• C08L77/02

  Polyamides derived from omega-amino carboxylic acids or from lactams thereof (C08L77/10 takes precedence) · CPC title

• B32B2307/202

  Conductive · CPC title

• C08L77/06 Primary

  Polyamides derived from polyamines and polycarboxylic acids (C08L77/10 takes precedence) · CPC title

• B32B2262/106

  Carbon fibres, e.g. graphite fibres · CPC title