Process for the production of a coated substance comprising cellulosic fibres

Patent metadata

Field	Value
Publication number	US-10138599-B2
Application number	US-201515535456-A
Country	US
Kind code	B2
Filing date	Dec 14, 2015
Priority date	Dec 18, 2014
Publication date	Nov 27, 2018
Grant date	Nov 27, 2018

Abstract

The present invention relates to process for the production of a coated substrate comprising cellulosic fibers, the process comprising the steps of:
i) providing a first substrate comprising cellulosic fibers and having a dry content of less than 50%; ii) applying a coating composition to the first substrate in an amount of more than 5 g/m 2 , calculated as dry weight of the coating composition, wherein the coating composition comprises:
microfibrillated cellulose (MFC), and optionally a water retention agent selected from carboxymethyl cellulose (CMC), anionic polyacrylamide (A-PAM), sodium polyacrylates, polyacrylic acid derivatives, guar gum, alginate, MFC prepared from carboxymethylated fibers, MFC prepared from oxidized fibers, MFC prepared by CMC-functionalized fibers, and/or combinations thereof; and
iii) mechanically dewatering the first substrate.

The present process provides an energy efficient coating process which can be performed online.

First claim

The invention claimed is:

1. A process for the production of a coated substrate comprising cellulosic fibres, the process comprising the steps of:
i) providing a first substrate comprising cellulosic fibres and having a dry content of less than 50% by weight;
ii) applying a coating composition to the first substrate in an amount of more than 5 g/m 2 , calculated as dry weight of the coating composition, wherein the coating composition comprises:
microfibrillated cellulose (MFC), and
a water retention agent selected from carboxymethyl cellulose (CMC), anionic polyacrylamide (A-PAM), sodium polyacrylates, polyacrylic acid derivatives, guar gum, alginate, MFC prepared from carboxymethylated fibers, MFC prepared from oxidized fibers, MFC prepared by CMC-functionalized fibers, and/or combinations thereof; and

iii) mechanically dewatering the first substrate,
wherein the coating composition comprises the water retention agent in an amount of at least 1% by weight, calculated as dry weight and based on the dry weight of the MFC.

2. The process according to claim 1 , wherein the process further comprises in step i) providing a second substrate comprising cellulosic fibres and having a dry content of less than 50% by weight, and in step iii) attaching the second substrate to the first substrate, such that the coating composition is placed between the first and second substrates, and subsequently mechanically dewatering the attached first and second substrates.

3. The process according to claim 2 , wherein the step (ii) further comprises applying the coating composition in an amount of more than 5 g/m 2 , calculated as dry weight of the coating composition, to the second substrate.

4. The process according to claim 1 , wherein the coating composition comprises the microfibrillated cellulose in an amount of at least 90% by weight, calculated as dry weight.

5. The process according to claim 1 , wherein in case the coating composition is applied in step ii) in an amount of more than 15 g/m 2 , calculated as dry weight of the coating composition, the coating composition comprises the water retention agent in an amount of at least 2% by weight, calculated as dry weight and based on the dry weight of the MFC.

6. The process according to claim 1 , wherein in case the coating composition is applied in step ii) in an amount of more than 10 g/m 2 , calculated as dry weight of the coating composition, the coating composition comprises the water retention agent in an amount of at least 3% by weight, calculated as dry weight and based on the dry weight of the MFC.

7. The process according to claim 1 , wherein the coating composition comprises the water retention agent in an amount of up to about 10% by weight, calculated as dry weight and based on the dry weight of the MFC.

8. The process according to claim 7 , wherein the coating composition comprises the water retention agent in an amount of up to about 8.5% by weight, calculated as dry weight and based on the dry weight of the MFC.

9. The process according to claim 1 , wherein the coating composition is applied in step ii) to the first substrate and optionally a second substrate in a total amount of up to and including about 50 g/m 2 .

10. The process according to claim 9 , wherein the coating composition is applied in step ii) to the first substrate and optionally the second substrate in a total amount of about 10-40 g/m 2 .

11. The process according to claim 2 , wherein the first and/or second substrates have a dry content of less than 30-40% by weight.

12. The process according to claim 2 , wherein the first and/or second substrates have a dry content of less than 10-30% by weight.

13. The process according to claim 1 , wherein the water retention agent is CMC.

14. The process according to claim 1 , wherein the coating composition is applied by means of spray coating, roller coating, slot coating, immersion coating, gravure coating and/or reverse direct gravure coating, extrusion coating, curtain coating, rod coating, and/or gap coating or combinations thereof.

15. The process according to claim 14 , wherein the coating composition is added by means of spray coating.

16. The process according to claim 1 , wherein the step of mechanical dewatering comprises pressing.

17. The process according to claim 1 , wherein after the step iii) the process further comprises a step of:
iv) drying the substrate.

18. A paper or board produced by the process according to claim 1 .

19. The paper or board according to claim 18 , wherein the coating provides a barrier against oxygen and other gases, aroma, oil, grease and organic solvents.

20. A paper or board product comprising a first substrate upon which a coating composition has been applied, wherein the first substrate comprises cellulosic fibres, and wherein the coating composition comprises:
microfibrillated cellulose (MFC), and
a water retention agent selected from carboxymethyl cellulose (CMC), anionic polyacrylamide (A-PAM), sodium polyacrylates, polyacrylic acid derivatives, guar gum, alginate, MFC prepared from carboxymethylated fibers, MFC prepared from oxidized fibers, MFC prepared by CMC-functionalized fibers, and/or combinations thereof;
characterised by that the coating composition has been applied in an amount of more than 5 g/m 2 ,
wherein the coating composition comprises the water retention agent in an amount of at least 1% by weight, calculated as dry weight and based on the dry weight of the MFC.

21. A method of use of the paper or board according to claim 18 as a packaging material for perishable goods and/or healthcare products, the method comprising packaging the perishable goods and/or healthcare products in the paper or board.

Assignees

• Stora Enso Oyj

Inventors

• Aulin Christian
• Axrup Lars
• Flodberg Göran
• Hillergren Magnus
• Lindström Tom
• Ljungqvist Carl-Henrik
• Ström Göran

Classifications

• D21H23/50

  Spraying or projecting (D21H23/44, D21H23/66 take precedence) · CPC title

• D21H27/10

  Packing paper (packaging materials of special type or form B65D65/38) · CPC title

• D21H11/18

  Highly hydrated, swollen or fibrillatable fibres · CPC title

• D21H23/70

  Multistep processes; Apparatus for adding one or several substances in portions or in various ways to the paper, not covered by another single group of this main group · CPC title

• B32B37/153

  at least one layer is extruded and immediately laminated while in semi-molten state · CPC title