Polycarbonate compositions having improved adhesion to polyurethane layers

Patent metadata

Field	Value
Publication number	US-10138370-B2
Application number	US-201415027180-A
Country	US
Kind code	B2
Filing date	Oct 15, 2014
Priority date	Oct 18, 2013
Publication date	Nov 27, 2018
Grant date	Nov 27, 2018

Abstract

The present invention relates to compositions and composite components formed from these compositions and a polyurethane layer, which are notable for improved adhesion between the two layers, and a process for producing the composite components.

First claim

The invention claimed is:

1. A composition comprising the following components:
A) 30 to 45 parts by weight of at least one polymer selected from the group consisting of aromatic polycarbonate and aromatic polyester carbonate,
B) 32 to 54 parts by weight of at least one polyalkylene terephthalate,
C) 16 to 23 parts by weight of at least one mixture comprising at least one polybutadiene-based graft polymer and at least one butadiene-free vinyl (co)polymer,
D) 0.1 to 20.0 parts by weight (based in each case on the sum total of the components A to C) of at least one polymer additive,
where the polybutadiene content based on the sum total of the parts by weight of the components A to C is 8% to 18% by weight,
and where the total content of butadiene-free vinyl (co)polymer from the component C based on the sum total of the parts by weight of the components A to C is 3% to 12% by weight, and where the sum total of the parts by weight of the components A to C in the composition is normalized to 100.

2. The composition according to claim 1 , wherein
A) 32 to 45 parts by weight of at least one polymer selected from the group consisting of aromatic polycarbonate and aromatic polyester carbonate,
B) 32 to 50 parts by weight of at least one polyalkylene terephthalate,
C) 17 to 22 parts by weight of at least one mixture comprising at least one polybutadiene-based graft polymer and at least one butadiene-free vinyl (co)polymer,
D) 0.2 to 15.0 parts by weight (based in each case on the sum total of the components A to C) of at least one polymer additive,
where the polybutadiene content based on the sum total of the parts by weight of the components A to C is 9% to 17% by weight,
and where the total content of butadiene-free vinyl (co)polymer from the component C based on the sum total of the parts by weight of the components A to C is 4% to 11% by weight, and where the sum total of the parts by weight of the components A to C in the composition is normalized to 100.

3. The composition according to claim 1 , comprising
A) 35 to 45 parts by weight of at least one polymer selected from the group consisting of aromatic polycarbonate and aromatic polyester carbonate,
B) 32 to 45 parts by weight of at least one polyalkylene terephthalate,
C) 18 to 21 parts by weight of at least one mixture comprising at least one polybutadiene-based graft polymer and at least one butadiene-free vinyl (co)polymer,
D) 0.3 to 10.0 parts by weight (based in each case on the sum total of the components A to C) of at least one polymer additive,
where the polybutadiene content based on the sum total of the parts by weight of the components A to C is 10% to 16% by weight,
and where the total content of butadiene-free vinyl (co)polymer from the component C based on the sum total of the parts by weight of the components A to C is 5% to 10% by weight, and where the sum total of the parts by weight of the components A to C in the composition is normalized to 100.

4. The composition according to claim 1 ,
wherein the component C comprises the following components:
C.1 5% to 60% by weight, based on the component C.1, of at least one vinyl monomer on
C.2 95% to 40% by weight, based on the component C.1, of one or more polybutadiene-based graft bases.

5. The composition according to claim 4 , wherein the component C.1 comprises mixtures of
C.1.1 50 to 99 parts by weight, based on C.1, of vinylaromatics and/or ring-substituted vinylaromatics and/or (C 1 -C 8 )-alkyl methacrylates, and
C.1.2 1 to 50 parts by weight, based on C.1, of vinyl cyanides (unsaturated nitriles) and/or (C 1 -C 8 )-alkyl (meth)acrylates.

6. The composition of claim 1 ,
wherein the component D comprises one or more of thermal stabilizers, demoulding agents, colourants and UV absorbers.

7. The composition of claim 1 , wherein the component B is polybutylene terephthalate.

8. A composite component comprising
a) a carrier composed of a thermoplastic composition according to the composition of claim 1
b) at least one polyurethane layer selected from the group of coating materials, foams and compact skins, comprising
at least one polyisocyanate component,
at least one polyfunctional H-active compound, and
optionally at least one polyurethane additive and/or processing aid,

and having a molar ratio of NCO- to H-active groups of 1:1 to 1.1:1.

9. The composite component according to claim 8 , wherein the polyurethane layer is a coating material having a layer thickness of 50-300 μm.

10. The composite component according to claim 8 , wherein the polyurethane layer is a foam having a layer thickness of 1 mm to 1 cm.

11. The composite component according to claim 8 , wherein the polyurethane layer is a compact skin having a layer thickness of 1 mm to 4 mm.

12. A process for producing the composite component according to claim 8 , wherein the polyurethane layer has been produced by full polymerization of a reactive polyurethane raw material mixture comprising
at least one polyisocyanate component,
at least one polyfunctional H-active compound, and
optionally at least one polyurethane additive and/or processing aid,

in direct contact with the carrier which has been shaped beforehand from the thermoplastic composition and solidified.

13. A process for producing the composite component according to claim 8 ,
(i) injecting a melt of the thermoplastic composition into a first mould cavity and then cooling,
(ii) transferring the cooled thermoplastic component into a larger cavity and producing a defined gap thereby,
(iii) the gap which thus results between the thermoplastic component and the mould surface of the enlarged cavity is injected with a reactive polyurethane raw material mixture comprising
at least one polyisocyanate component,
at least one polyfunctional H-active compound, and
optionally at least one polyurethane additive and/or processing aid,

the polyurethane raw material mixture polymerizing fully in direct contact with the surface of the thermoplastic carrier to give a compact polyurethane layer or to give a polyurethane foam layer,
(iv) the composite component is demoulded from the mould cavity, wherein (i) to (iv) following one another in immediate succession.

14. The process according to claim 13 , wherein, in (iii) the surface of the injection mould in contact with the thermoplastic composition is heated to a temperature in the range of 60 to 90° C. and the surface of the injection mould in contact with the reactive polyurethane mixture to a temperature in the range of 60 to 90° C.

15. The composite component according to claim 8 capable of being used as an interior or exterior component of a rail vehicle, aircraft or motor vehicle or of an electrical/electronic component.

16. The composition according to claim 5 , wherein the component C.1.1 comprises at least one of styrene, α-methylstyrene, p-methylstyrene, and p-chlorostyrene.

17. The composition according to claim 5 , wherein the component C.1.1 comprises at least one of methyl methacrylate and ethyl methacrylate.

18. The composition according to claim 5 , wherein the component C.1.2 comprises at least one of acrylonitrile and methacrylonitrile.

19. The composition according to claim 5 , wherein the component C.1.2 further comprises at least one of anhydrides and imides.

20. The composition according to claim 5 , wherein the component C.1.2 further comprises at least one of maleic anhydride and N-phenylmaleimide.

21. The composition according

Assignees

• Covestro Deutschland Ag

Inventors

• Hufen Ralf
• Eckel Thomas
• Hobeika Sven
• Kuhlmann Timo
• Helmig Jan

Classifications

• C08L67/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds (C08L67/06 takes precedence) · CPC title

• B32B27/08

  of synthetic resin · CPC title

• B32B2255/10

  on synthetic resin layer or on natural or synthetic rubber layer · CPC title

• C08L69/00 Primary

  Compositions of polycarbonates; Compositions of derivatives of polycarbonates · CPC title

• C08L69/005

  Polyester-carbonates · CPC title