Catalyst component for the preparation of nucleated polyolefins

Patent metadata

Field	Value
Publication number	US-10138308-B2
Application number	US-201515318344-A
Country	US
Kind code	B2
Filing date	Jun 9, 2015
Priority date	Jun 27, 2014
Publication date	Nov 27, 2018
Grant date	Nov 27, 2018

Abstract

Catalyst composition comprising a phthalate-free electron donor, which is highly effective during polymerization in the presence of a polymeric nucleating agent, and its use and a process for its preparation.

First claim

The invention claimed is:

1. A process of obtaining a catalyst composition containing a catalyst component, the process comprising:
a1) providing a solution of at least a Group 2 metal alkoxy compound (Ax) being the reaction product of a Group 2 metal compound (MC) and a monohydric alcohol (A) comprising in addition to the hydroxyl moiety at least one ether moiety optionally in an organic liquid reaction medium; or
a2) providing a solution of at least a Group 2 metal alkoxy compound (Ax′) being the reaction product of a Group 2 metal compound (MC) and an alcohol mixture of the monohydric alcohol (A) and a monohydric alcohol (B) of formula ROH, optionally in an organic liquid reaction medium; or
a3) providing a solution of a mixture of the Group 2 metal alkoxy compound (Ax) and a Group 2 metal alkoxy compound (Bx) being the reaction product of a Group 2 metal compound (MC) and the monohydric alcohol (B), optionally in an organic liquid reaction medium; or
a4) providing a solution of Group 2 metal alkoxy compound of formula M(OR1) n (OR2) m X 2-n-m or mixture of Group 2 alkoxides M(OR1) n′ X 2-n′ and M(OR2) m′ X 2-m′ , where M is Group 2 metal, X is halogen, R1 and R2 are different alkyl groups of C2 to C16 carbon atoms, and 0<n<2, 0<m<2 and n+m+(2-n-m)=2, provided that both n and m≠0, 0<n′<2 and 0<m′<2; and
b) adding said solution from step a) to at least one compound (TC) of a transition metal of Group 4 to 6, and
c) obtaining the solid catalyst component particles,
d) washing said solidified particles,
e) recovering the solidified particles of the olefin polymerisation catalyst component, wherein an electron donor is added at any step prior to step c) and is a non-phthalic internal electron donor, and
wherein the catalyst component is further modified by a polymeric nucleating agent comprising vinyl compound units;
wherein the catalyst component is washed in step d) at least three times with at least one toluene and at least one TiCl4 washing step and 1 to 3 further washing steps with an aromatic and/or aliphatic hydrocarbon selected from toluene, heptane or pentane; and
wherein internal donor is added to either the toluene wash step and/or to the TiCl4 wash step, whereby the amount of donor added to the washing steps is in the range of 10 to 60 wt % of the total amount of donor used in catalyst preparation steps a) to d).

2. The process of claim 1 , wherein the polymeric nucleating agent is selected from the group of vinyl alkanes or vinyl cycloalkanes, 3-methyl-1-butene, 3-ethyl-1-hexene, 3-methyl-1-pentene, 4-methyl-1-pentene or mixtures thereof.

3. The process of claim 1 , wherein the internal donor (ID) used in the preparation of the catalyst component is selected from (di)esters of non-phthalic carboxylic (di)acids, 1,3-diethers, derivatives and mixtures thereof.

4. The process of claim 1 , wherein the electron donor for the catalyst component is selected from diesters of mono-unsaturated dicarboxylic acids, belonging to the group comprising malonates, maleates, succinates, citraconates, glutarates, cyclohexene-1,2-dicarboxylates and benzoates, and any derivatives and/or mixtures thereof.

5. The process of claim 1 , wherein the catalyst composition comprises the modified catalyst component together with a co-catalyst and an external donor for the polymerisation of propylene, optionally with co-monomers selected from C2 or C4 to C12 monomers.

Assignees

• Borealis Ag

Inventors

• Vestberg Torvald

Classifications

• C08F4/6548

  magnesium or compounds thereof, not provided for in C08F4/6543 or C08F4/6546 · CPC title

• C08F2500/12

  Melt flow index or melt flow ratio · CPC title

• C08F4/6492

  containing aliphatic unsaturation · CPC title

• C08F4/6465

  containing silicium · CPC title

• C08F2500/15

  Isotactic · CPC title