Carbon spheres and methods of making the same

Patent metadata

Field	Value
Publication number	US-10138129-B2
Application number	US-201615163297-A
Country	US
Kind code	B2
Filing date	May 24, 2016
Priority date	May 24, 2016
Publication date	Nov 27, 2018
Grant date	Nov 27, 2018

Abstract

Carbon particles are disclosed, as well as methods and systems for forming the particles. In one embodiment, the system may include a receiving vessel configured to receive a liquid carbon precursor and at least one orifice at a bottom of the receiving vessel and configured to release droplets of the precursor. A cooling vessel may be positioned below the receiving vessel to receive the droplets and configured to hold a coolant for solidifying the droplets into carbon precursor particles. The method may include introducing a liquid carbon precursor into a tank having a plurality of orifices defined therein such that droplets of the precursor are released from the orifices and solidifying the droplets in a cooling vessel positioned to receive the droplets from the orifices. The method may then include carbonizing the solidified droplets to form carbon particles. The particles may be solid or hollow.

First claim

What is claimed is:

1. A system comprising:
a receiving vessel configured to receive a liquid carbon precursor;
at least one orifice at a receiving vessel bottom, the at least one orifice configured to release droplets of the precursor;
a cooling vessel positioned below the receiving vessel to receive the droplets and configured to hold a coolant for solidifying the droplets into carbon precursor particles; and
an oven configured to carbonize the carbon precursor particles into carbon particles comprising at least 90 wt. % carbon.

2. The system of claim 1 , wherein the receiving vessel includes at least one tube and each of the at least one orifice is defined at an end of one of the at least one tube.

3. The system of claim 2 , wherein the at least one tube includes a main body portion and a narrower tip portion.

4. The system of claim 2 , wherein the at least one tube includes an inner lumen configured to receive a fluid and an outer lumen configured to receive the liquid carbon precursor.

5. The system of claim 4 , wherein an end of the inner lumen extends past an end of the outer lumen.

6. The system of claim 4 , wherein the at least one tube is configured to release droplets of the precursor having an inner core comprised of the fluid.

7. The system of claim 6 , wherein the fluid is a gas.

8. The system of claim 6 , wherein the fluid is a liquid polymer.

9. The system of claim 6 , wherein the inner core comprises at least 10% of a diameter of the droplets.

10. The system of claim 1 , wherein the receiving vessel includes a gas inlet connected to a pressurized gas source and a gas valve configured to control gas flow from the pressurized gas source into the vessel.

11. The system of claim 10 , wherein the receiving vessel includes a pressure sensor and a gas vent configured to release gas from the receiving vessel to reduce an air pressure in the receiving vessel.

12. The system of claim 1 , wherein the at least one orifice includes at least 100 orifices.

13. The system of claim 1 , wherein the at least one orifice is configured to release droplets having a diameter of 10 to 400 μm.

14. A system comprising:
a receiving vessel for a liquid carbon precursor and including at least one orifice at a bottom thereof for releasing droplets of the precursor;
a cooling vessel below the receiving vessel for receiving the droplets and for solidifying the droplets into carbon precursor particles; and
an oven for carbonizing the carbon precursor particles into carbon particles comprising at least 90 wt. % carbon.

15. The system of claim 14 , wherein the oven provides an inert atmosphere.

16. The system of claim 14 , wherein the oven provides an oxygen-free atmosphere.

17. The system of claim 14 , further comprising an electrochemical or electrolytic bath for surface treating the carbon particles.

Assignees

• Ford Global Tech Llc

Inventors

• Zhao Haibo
• Blanchard Patrick James

Classifications

• C01B32/05

  Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30 · CPC title

• C08K7/18 Primary

  inorganic · CPC title

• B01J13/04

  by physical processes, e.g. drying, spraying · CPC title

• B01J4/02

  for feeding measured {, i.e. prescribed} quantities of reagents · CPC title

• C01P2004/32

  Spheres · CPC title