Porous carbon, humidity control adsorbent, adsorption heat pump, and fuel cell

Patent metadata

Field	Value
Publication number	US-10137405-B2
Application number	US-201414911593-A
Country	US
Kind code	B2
Filing date	Jun 16, 2014
Priority date	Sep 6, 2013
Publication date	Nov 27, 2018
Grant date	Nov 27, 2018

Abstract

A porous carbon that can sufficiently adsorb water vapor on a high humidity side is provided.
A porous carbon is characterized by having mesopores and micropores and having a water vapor adsorbed amount ratio, as defined by the following expression (1), of 1.8 or higher. It is particularly preferable that the water vapor adsorbed amount ratio as defined by the following expression (1) be 2.0 or higher. It is also preferable that the water vapor adsorbed amount at a relative humidity of 70% be 50 mg/g or greater.

Water vapor adsorbed amount ratio=water vapor adsorbed amount at a relative humidity of 90%/water vapor adsorbed amount at a relative humidity of 70%.  (1)

First claim

The invention claimed is:

1. A porous carbon characterized by comprising mesopores and micropores and having a mesopore volume of from 0.9 mL/g to 2.0 mL/g and a water vapor adsorbed amount ratio of 2.0 or higher, the water vapor adsorbed amount ratio being defined by the following expression:
Water vapor adsorbed amount ratio=water vapor adsorbed amount at a relative humidity of 90%/water vapor adsorbed amount at a relative humidity of 70%.

2. The porous carbon according to claim 1 , wherein the mesopores have a pore diameter of from 3 nm to 50 nm.

3. The porous carbon according to claim 2 , wherein the mesopores have a pore diameter of from 4.5 nm to 50 nm.

4. The porous carbon according to claim 1 , wherein the water vapor adsorbed amount at a relative humidity of 70% is 50 mg/g or greater.

5. The porous carbon according to claim 1 , wherein the water vapor adsorbed amount at a relative humidity of 90% is from 300 mg/g to 700 mg/g.

6. The porous carbon according to claim 1 , wherein the micropore volume is from 0.3 mL/g to 0.7 mL/g.

7. A porous carbon characterized by comprising mesopores and micropores and having a water vapor adsorbed amount ratio of 1.8 or higher, the water vapor adsorbed amount ratio being defined by the following expression, and wherein the water vapor adsorbed amount at a relative humidity of 90% is from 512 mg/g to 700 mg/g:
water vapor adsorbed amount ratio=water vapor adsorbed amount at a relative humidity of 90%/water vapor adsorbed amount at a relative humidity of 70%, wherein the mesopores have a pore diameter of from 3 nm to 50 nm, and the mesopore volume is from 0.9 mL/g to 2.0 mL/g.

8. The porous carbon according to claim 7 , wherein the water vapor adsorbed amount ratio is 2.0 or higher.

9. The porous carbon according to claim 7 , wherein the water vapor adsorbed amount at a relative humidity of 70% is 50 mg/g or greater.

10. The porous carbon according to claim 8 , wherein the water vapor adsorbed amount at a relative humidity of 70% is 50 mg/g or greater.

11. The porous carbon according to claim 7 , wherein the mesopores have a pore diameter of from 4.5 nm to 50 nm.

12. The porous carbon according to claim 7 , wherein the micropore volume is from 0.3 mL/g to 0.7 mL/g.

13. A humidity control adsorbent, characterized by using the porous carbon according to claim 1 as an adsorbent.

14. An adsorption heat pump, characterized by using a porous carbon as an adsorbent, wherein
the porous carbon comprises mesopores and micropores and having a mesopore volume of from 0.9 mL/g to 2.0 mL/g and a water vapor adsorbed amount ratio of 1.8 or higher, the water vapor adsorbed amount ratio being defined by the following expression:
Water vapor adsorbed amount ratio=water vapor adsorbed amount at a relative humidity of 90%/water vapor adsorbed amount at a relative humidity of 70%.

15. A fuel cell, characterized by using a porous carbon as an adsorbent, wherein
the porous carbon comprises mesopores and micropores and having a mesopore volume of from 0.9 mL/g to 2.0 mL/g and a water vapor adsorbed amount ratio of 1.8 or higher, the water vapor adsorbed amount ratio being defined by the following expression:
Water vapor adsorbed amount ratio=water vapor adsorbed amount at a relative humidity of 90%/water vapor adsorbed amount at a relative humidity of 70%.

Assignees

• Toyo Tanso Co

Inventors

• Kawano Takanori
• Morishita Takahiro
• Orikasa Hironori

Classifications

• B01J2220/46

  Materials comprising a mixture of inorganic and organic materials (materials coated or impregnated on a carrier B01J20/32) · CPC title

• C01B31/00

  Chemistry & Metallurgy · mapped topic

• B01J20/3078

  Thermal treatment, e.g. calcining or pyrolizing · CPC title

• B01D53/261

  by adsorption · CPC title

• B01J20/20

  comprising free carbon; comprising carbon obtained by carbonising processes · CPC title