Interlaced filtration barrier

Patent metadata

Field	Value
Publication number	US-10137394-B2
Application number	US-201414562779-A
Country	US
Kind code	B2
Filing date	Dec 8, 2014
Priority date	Dec 9, 2013
Publication date	Nov 27, 2018
Grant date	Nov 27, 2018

Abstract

A filtration barrier comprises at least one barrier layer which includes polymeric nanofibers interlaced with microfibers, and at least one substrate layer which includes polymeric microfibers. The filtration barrier can be made by electrospinning process.

First claim

What is claimed is:

1. A filtration barrier, comprising:
at least one barrier layer that includes an interlaced structure that includes a plurality of first polymer-based nanofibers and a plurality of second polymer-based microfibers that are interlaced with the first polymer-based nanofibers in a same layer; and
at least one substrate layer that includes a plurality of third polymer-based microfibers and that is attached onto the barrier layer,
wherein the first polymer-based nanofibers and the second polymer-based microfibers that are interlaced with the first polymer-based nanofibers in the barrier layer both include a combination of cellulose acetate (CA) and polyethylene oxide (PEO), the first polymer-based nanofibers are electrospun nanofibers, the second polymer-based microfibers are electrospun microfibers, the first polymer-based nanofibers account for 60%-70% by weight of the barrier layer, and the interlaced structure of the barrier layer has a pore size of 100-10000 nanometers; and further wherein the first polymer-based nanofibers and the second polymer-based microfibers are made from a same polymer solution that includes the combination of the CA and the PEO, wherein the first polymer-based nanofibers and the second polymer-based microfibers are discharged together from the same polymer solution during electrospinning to form the interlaced structure.

2. The filtration barrier of claim 1 , wherein the second polymer-based microfibers account for 30%-40% by weight of the barrier layer;
and the barrier layer has a porosity of 80%-98%.

3. The filtration barrier of claim 1 , wherein the CA and the PEO have a ratio of weight percentage as 50:1-400:1.

4. The filtration barrier of claim 1 , wherein the first polymer-based nanofibers have a diameter of 10 nanometers to 1000 nanometers; the second polymer-based microfibers have a diameter of 1 micron to 10 microns.

5. The filtration barrier of claim 1 , wherein the first polymer-based nanofibers and the second polymer-based microfibers bear positive electrostatic charges.

6. The filtration barrier of claim 1 , wherein the third polymer-based microfibers include polypropylene.

7. The filtration barrier of claim 1 , wherein the substrate layer is a nonwoven fabric made of 10-100 gsm polypropylene.

8. The filtration barrier of claim 1 , wherein the barrier layer includes a combination of the CA and the PEO at a weight of 0.8 gsm.

9. The filtration barrier of claim 1 comprising:
five barrier layers, five substrate layers and a supporting layer, wherein one of the five barrier layers is sandwiched between the supporting layer and one of the five substrate layers.

10. The filtration barrier of claim 1 , wherein a supporting layer is attached to the barrier layer and the supporting layer is a nonwoven fabric made of 40-120 gsm polypropylene.

11. The filtration barrier of claim 1 , wherein a supporting layer is attached to the barrier layer and includes polypropylene microfibers with a diameter of 1 micron to 10 microns.

12. The filtration barrier of claim 1 further comprising:
a biocide that is crosslinked to the barrier layer, wherein the biocide is selected from a group consisting of chlorhexidine, copper oxide, silver nanoparticles, calcium peroxide, N-halamines, and antibiotics.

13. The filtration barrier of claim 1 , wherein both of the first polymer-based nanofibers and the second polymer-based microfibers further include benzyltriethylammonium chloride.

14. A filtration barrier, comprising:
a barrier layer that includes nanofibers that are interlaced with first microfibers in the barrier layer; and
a substrate layer that is attached to the barrier layer and that includes second microfibers,
wherein polymers of both the nanofibers and the first microfibers include a combination of cellulose acetate (CA) and polyethylene oxide (PEO), polymers of the second microfibers are selected from a group consisting of polyester, nylon, polyethylene, polyurethane, cellulose, polybutylene terephthalate, polycarbonate, polymethylpentene and polystyrene, the nanofibers account for 60%-70% by weight of the barrier layer, the nanofibers are electrospun nanofibers, and the first microfibers are electrospun microfibers, and the nanofibers and the first microfibers are interlaced such that the nanofibers cross over and under the microfibers to form the barrier layer having a pore size of 100-10000 nanometers.

15. The filtration barrier of claim 14 , wherein the CA and the PEO have a ratio of weight percentage as 100:1 or 150:1.

16. The filtration barrier of claim 14 , wherein a perimeter of the barrier layer is attached onto a perimeter of the substrate layer via ultrasonic welding.

17. The filtration barrier of claim 14 , wherein the barrier layer has a thickness of 5 microns to 100 microns, and the substrate layer has a thickness of 90 microns to 200 microns.

18. The filtration barrier of claim 14 , wherein the nanofibers have a diameter of 20 nanometers to 500 nanometers, and the first microfibers have a diameter of 1 microns to 3 microns.

19. A filtration barrier, comprising:
a barrier layer that includes a plurality of nanofibers that are interlaced with a plurality of microfibers in the barrier layer; and
a substrate layer that is attached to the barrier layer and that includes polypropylene,
wherein the nanofibers and the microfibers are made of a combination of cellulose acetate (CA) and polyethylene oxide (PEO), the barrier layer includes the combination of the CA and the PEO at a weight of 0.8 gsm, the nanofibers account for 60%-70% by weight of the barrier layer, the nanofibers are electrospun nanofibers, the microfibers are electrospun microfibers, and the nanofibers and the microfibers are interlaced to form the barrier layer having a pore size of 100-10000 nanometers.

20. The filtration barrier of claim 19 , wherein the CA and the PEO have a ratio of weight percentage as 50:1-400:1.

Assignees

• Nano & Advanced Materials Inst Ltd
• Nano And Advanced Mat Institute Ltd

Inventors

• Tong Ho Wang
• Kwok Sau Kuen Connie

Classifications

• B01D2239/0435

  Electret · CPC title

• B01D2239/064

  The fibres being mixed · CPC title

• B01D2239/0442

  Antimicrobial, antibacterial, antifungal additives · CPC title

• B29C48/18

  the components being layers · CPC title

• B01D39/1623 Primary

  of synthetic origin · CPC title