Separation of ionic liquids in coalescing devices

Patent metadata

Field	Value
Publication number	US-10137386-B2
Application number	US-201415039084-A
Country	US
Kind code	B2
Filing date	Dec 1, 2014
Priority date	Dec 2, 2013
Publication date	Nov 27, 2018
Grant date	Nov 27, 2018

Abstract

A process for separating a phase (A) comprising at least one ionic liquid from a phase (B), where phase (A) has a higher viscosity than phase (B), comprising: a) providing a stream (S1) comprising a dispersion (D1) in which phase (A) is dispersed in phase (B), b) introducing stream (S1) into a coalescing device (KV), where the inflow rate of stream (S1) is from 0.05 to 150 kg/(cm2*h) based on the average cross-sectional area of coalescing device (KV), wherein the packing density of coalescing device (KV) is from 50 to 500 kg/m3, separating phase (A) from phase (B) in coalescing device (KV), discharging a stream (S2) comprising at least 70% by weight of phase (A) from coalescing device (KV) and discharging a stream (S3) comprising at least 70% by weight of phase (B) from coalescing device (KV).

First claim

The invention claimed is:

1. A process for separating a phase (A) comprising at least one ionic liquid from a phase (B), wherein the phase (A) has a higher viscosity than the phase (B) and wherein the phase (B) comprises at least one hydrocarbon, which comprises the following steps:
a) providing a stream (S 1 ) comprising a dispersion (D 1 ) in which the phase (A) is dispersed in the phase (B);
b) introducing the stream (S 1 ) into a coalescing filter (KV), wherein the inflow rate of the stream (S 1 ) is from 0.05 to 150 kg/(cm 2 *h) based on the average cross-sectional area of the coalescing filter (KV), wherein the packing density of the coalescing filter (KV) is from 50 to 500 kg/m 3 , wherein the coalescing filter (KV) contains filter material wherein the filter material comprises at least 50% by weight of acrylic phenolic resin;
c) separating the phase (A) from the phase (B) in the coalescing filter (KV);
d) discharging a stream (S 2 ) comprising at least 70% by weight of phase (A) from the coalescing filter (KV); and
e) discharging a stream (S 3 ) comprising at least 70% by weight of phase (B) from the coalescing filter (KV).

2. The process according to claim 1 , wherein the stream (S 2 ) comprises at least 90% by weight of phase (A).

3. The process according to claim 1 , wherein the stream (S 3 ) comprises at least 90% by weight of phase (B).

4. The process according to claim 1 , wherein:
i) the inflow rate of the stream (S 1 ) is from 0.5 to 20 kg/(cm 2 h), based on the average cross-sectional area of the coalescing filter (KV), or
ii) at least one additional coalescing device is connected to the coalescing filter (KV) in parallel, with the at least one additional coalescing device, and the coalescing filter (KV) being operatable simultaneously or alternately.

5. The process according to claim 1 , wherein the inflow rate of the stream (S 1 ) is from 0.5 to 5 kg/(cm 2 *h), based on the average cross-sectional area of the coalescing filter (KV).

6. The process according to claim 1 , wherein;
i) the coalescing filter (KV) is used without adhesive bonding; or
ii) the pressure drop over the coalescing filter (KV) is from 0.001 to 1 bar.

7. The process according to claim 6 , wherein the pressure drop over the coalescing filter (KV) is from 0.001 to 0.5 bar.

8. The process according to claim 6 , wherein the pressure drop over the coalescing filter (KV) is from 0.001 to 0.2 bar.

9. The process according to claim 1 , wherein the at least one hydrocarbon comprises cyclohexane.

10. The process according to claim 1 , wherein the at least one ionic liquid in the phase (A) is an acidic ionic liquid having the composition K1Al n X (3n+1) , where K1 is a monovalent cation, X is halogen and 1<n<2.5.

11. The process according to claim 10 , wherein K1 comprises an at least partially alkylated ammonium ion or a heterocyclic cation or wherein X is Cl.

12. The process according to claim 1 , wherein the dispersion (D 1 ) comprises a maximum of 5% by weight of the phase (A).

13. The process according to claim 1 , wherein the stream (S 1 ) is obtained from a phase separation unit which is located upstream of the coalescing filter (KV) and downstream of a reaction apparatus or a cascade of reaction apparatuses.

14. The process according to claim 13 , wherein the phase separation unit is a phase separator.

15. The process according to claim 13 , further comprising:
f) discharging a stream (S 4 ) from the reaction apparatus or the cascade of reaction apparatuses, where stream (S 4 ) comprises a dispersion (D 2 ) in which the phase (B) is dispersed in the phase (A);
g) introducing a stream (S 5 ) comprising at least 70% by weight of the phase (B) into the stream (S 4 ), to form a stream (S 6 ) comprising a dispersion in which the phase (A) is dispersed in the phase (B);
h) introducing the stream (S 6 ) into the phase separation unit;
i) separating the stream (S 6 ) in the phase separation unit to provide the stream (S 1 ) and a stream (S 7 ) comprising at least 70% by weight of the phase (A); and
j) separating part of the stream (S 3 ) to provide the stream (S 5 ) and recirculating the stream (S 5 ) to step g).

16. The process according to claim 15 , wherein the stream (S 5 ) comprises at least 90% by weight of the phase (B).

17. The process according to claim 15 , wherein the stream (S 7 ) comprises at least 90% by weight of the phase (A).

18. The process according to claim 15 , wherein the introduction of the stream (S 5 ) into the stream (S 4 ) in step g) is carried out in a stirring or mixing apparatus to form the stream (S 6 ).

19. The process according to claim 15 , wherein the phase ratio of the phase (A) to the phase (B) in the dispersion of the stream (S 6 ) is ≤3 kg/kg.

20. The process according to claim 15 , wherein the phase ratio of the phase (A) to the phase (B) in the dispersion of the stream (S 6 ) is ≤0.9 kg/kg.

21. The process according to claim 15 , wherein the stream (S 4 ) is obtained from an isomerization.

22. The process according to claim 15 , wherein the stream (S 4 ) is obtained from an isomerization in the presence of the at least one ionic liquid.

23. The process according to claim 15 , wherein the stream (S 4 ) is obtained from an isomerization of methylcyclopentane (MCP) to cyclohexane in the presence of the at least one ionic liquid.

24. The process according to claim 15 , wherein the separating in step j) takes place outside of the phase separation unit.

25. The process according to claim 1 , wherein the stream (S 3 ) contains cyclohexane, and further comprising isolating cyclohexane from the stream (S 3 ).

Assignees

• Basf Se

Inventors

• Pfeiffer Daniel
• Bitterlich Stefan
• Hübner Michael

Classifications

• B01D17/10

  with stationary filtering elements · CPC title

• B01D17/08

  Thickening liquid suspensions by filtration · CPC title

• C07C7/005

  Processes comprising at least two steps in series · CPC title

• B01D17/045 Primary

  with coalescers · CPC title