Device for extraction of pollutants by multichannel tubular membrane

Patent metadata

Field	Value
Publication number	US-10137385-B2
Application number	US-201515319920-A
Country	US
Kind code	B2
Filing date	Jun 25, 2015
Priority date	Jun 25, 2014
Publication date	Nov 27, 2018
Grant date	Nov 27, 2018

Abstract

A device for extraction of pollutants by multichannel tubular membrane containing at least one fluid channel allowing the fluid to go through a feed inlet to an outlet end characterized in that membrane comprises at least an extraction channel filled with molten salt in order to adsorb said pollutants having to be extracted from the said fluid. Advantageously, the membrane is a ceramic membrane. An application is for the treatment of traces of pollutants in a liquid or gaseous fluid. For example, the removal of small pollutants as volatile organic compounds from an aqueous stream in industrial wastewater treatment or other water treatment applications, or the separation of aromatic compounds form an hydrocarbon feed in petrochemical applications. Another application is in the removal of water traces in products of high added value as pharmaceutical, cosmetic or biocarburant for example.

First claim

The invention claimed is:

1. A device for extraction of pollutants in a fluid, the device comprising at least one multichannel tubular membrane containing two or more fluid channels allowing the fluid to go through a feed inlet to an outlet end wherein the membrane comprises at least one extraction channel and molten salt, the at least one extraction channel and the two or more fluid channels are parallel, the at least one extraction channel being filled with the molten salt configured to adsorb said pollutants having to be extracted from the said fluid by diffusing from the two or more fluid channels to the molten salt placed in the parallel extraction channel.

2. The device according to claim 1 , wherein the circumference of the tubular membrane is leak-proof on its outside in order to avoid permeation through the circumference of the tubular membrane.

3. The device according to claim 1 , wherein the nature of the membrane is organic or mineral.

4. The device according to claim 1 , wherein the membrane is a ceramic membrane.

5. The device according to claim 1 , wherein the membrane comprises one extraction channel for one fluid channel.

6. The device according to claim 1 , wherein the at least one extraction channel is sealed at its extremities.

7. The device according to claim 1 , comprising a circuit of molten salt connected to at least one extraction channel comprising molten salt configured to run along the at least one extraction channel.

8. The device according to claim 7 , further comprising a circuit of fluid having to be treated connected to the inlet of at least one fluid channel of the two or more fluid channels, and wherein the circuit of molten salt is connected to an inlet of at least one extraction channel and wherein the inlet of the at least one fluid channel of the two or more fluid channels and the inlet of at least one extraction channel are placed on the same side or on the opposite side of the membrane and configured so that the molten salt is running forward or rearward of the direction of fluid contained in the at least one fluid channel.

9. The device according to claim 1 , further comprising a catalyst on the extraction channel.

10. The device according to claim 1 , wherein the molten salt is ionic liquid.

11. The device according to claim 1 , wherein the said fluid is a liquid or a gas.

12. The device according to claim 1 , wherein the more than two fluid channels and at least one extraction channel have a diameter size between 0.5 and 50 mm.

13. The device according to claim 1 , wherein the membrane has pores of a size between 1 nm and 8 μm.

14. The system comprising several devices according to claim 1 .

15. The method for extracting pollutant in a fluid with a device according to claim 1 wherein:
a first step of extraction wherein the fluid having to be treated goes through at least two fluid channels of the two or more fluid channels of the membrane and the pollutant is adsorbed on the molten salt, and
a second step of recycling the device wherein the way of said fluid is stopped and the device is heated on the boiling point of the pollutant in order to desorb the pollutant from the molten salt.

16. A method for extracting pollutant in a fluid with a device according to claim 1 , the method comprising:
a step of extraction wherein the fluid having to be treated goes through at least two fluid channels of the two or more fluid channels of the membrane and the pollutant is adsorbed on the molten salt going through the extraction channel, and
a step of recycling wherein the molten salt is going through the extraction channel and wherein once outside the membrane, the molten salt is heated on the boiling point of the pollutants in order to desorb the pollutant from the molten salt and wherein the molten salt is then reintroduced in the channel extraction, the steps of extraction and recycling being simultaneous.

17. The device according to claim 1 , wherein the total number of fluid channels and extraction channels ranges from 3 to 52.

18. The device according to claim 14 , wherein the several devices each comprise from 2 to 99 membranes.

Assignees

• Univ Aix Marseille
• Centre Nat Rech Scient
• Centre Nat Rech Scient

Inventors

• Anguille Stephane
• Moulin Philippe
• Testa Fabrice

Classifications

• B01D71/68

  Polysulfones; Polyethersulfones · CPC title

• C02F1/44

  by dialysis, osmosis or reverse osmosis {(general membrane separation processes B01D61/00, membrane modules B01D63/00, electrodialysis C02F1/4693, combination of membrane modules and bioreactors C02F3/1268)} · CPC title

• C02F1/26 Primary

  by extraction · CPC title

• B01D2325/20

  Specific permeability or cut-off range · CPC title

• B01D53/1425

  Regeneration of liquid absorbents · CPC title