Lithium secondary battery

Patent metadata

Field	Value
Publication number	US-10135095-B2
Application number	US-201314429694-A
Country	US
Kind code	B2
Filing date	Nov 22, 2013
Priority date	Nov 22, 2012
Publication date	Nov 20, 2018
Grant date	Nov 20, 2018

Abstract

Disclosed is a lithium secondary battery including: (i) a cathode active material including a lithium metal phosphate according to Formula 1 below; (ii) an anode active material including amorphous carbon; and (iii) an electrolyte for lithium secondary batteries including a lithium salt and an ether based solvent, wherein propylene carbonate (PC) is included in an amount of 1 wt % to 60 wt % in the electrolyte for lithium secondary batteries, based on the total weight of the electrolyte,

Li 1+a M(PO 4−b )X b   (1)
wherein M is at least one selected from metals of Groups II to XII; X is at least one selected from F, S and N, −0.5≤a≤+0.5, and 0≤b≤0.1.

First claim

The invention claimed is:

1. A lithium secondary battery comprising:
a cathode active material comprising a lithium metal phosphate according to Formula 1 below;
an anode active material consisting of amorphous carbon having an average particle diameter of 0.01 μm to 30 μm and a specific surface area with respect to a capacity thereof of 0.015 m 2 /mAh to 0.055 m 2 /mAh; and
an electrolyte for lithium secondary batteries consisting of a lithium salt, dibutyl ether, and propylene carbonate (PC),
wherein propylene carbonate (PC) is comprised in an amount of 1 wt % to 60 wt % in the electrolyte for lithium secondary batteries, based on a total weight of the electrolyte,
Li 1+a M(PO 4−b )X b   (1)

wherein M is at least one selected from metals of Groups II to XII; X is at least one selected from F, S and N, −0.5≤a≤+0.5, and 0≤b≤0.1.

2. The lithium secondary battery according to claim 1 , wherein the propylene carbonate (PC) is comprised in an amount of 1 to 40 wt % based on a total weight of the electrolyte.

3. The lithium secondary battery according to claim 1 , wherein the lithium salt is selected from the group consisting of LiCl, LiBr, LiI, LiClO 4 , LiBF 4 , LiB 10 Cl 10 , LiPF 6 , LiCF 3 SO 3 , LiCF 3 CO 2 , LiAsF 6 , LiSbF 6 , LiPF 6 , LiAlCl 4 , CH 3 SO 3 Li, CF 3 SO 3 Li, (CF 3 SO 2 ) 2 NLi, chloroborane lithium, lithium tetraphenyl borate, and imides, and has a concentration of 0.5 to 3 M in the electrolyte.

4. The lithium secondary battery according to claim 1 , wherein the lithium metal phosphate is a lithium iron phosphate having an olivine crystal structure according to Formula 2 below:
Li 1+a Fe 1−x M′ x (PO 4−b )X b   (2)

wherein M′ is at least one selected from Al, Mg, Ni, Co, Mn, Ti, Ga, Cu, V, Nb, Zr, Ce, In, Zn, and Y,
X is at least one selected from F, S, and N, and
−0.5≤a≤+0.5, 0≤x≤0.5, and 0≤b≤0.1.

5. The lithium secondary battery according to claim 4 , wherein the lithium iron phosphate having the olivine crystal structure is LiFePO 4 .

6. The lithium secondary battery according to claim 5 , wherein the lithium iron phosphate having the olivine crystal structure is coated with conductive carbon.

7. The lithium secondary battery according to claim 1 , wherein the amorphous carbon is hard carbon and/or soft carbon.

8. A battery module comprising the lithium secondary battery according to claim 1 as a unit cell.

9. A battery pack comprising the battery module according to claim 8 .

10. A device comprising the battery pack according to claim 9 .

11. The device according to claim 10 , wherein the device is a hybrid electric vehicle, a plug-in hybrid electric vehicle, or a system for storing power.

12. A lithium secondary battery according to claim 1 wherein the cathode active material comprising a lithium metal phosphate according to Formula 1 is composed of first and second particles in which the first particles are physically aggregated.

Assignees

• Lg Chemical Ltd

Inventors

• Yoon Yourim
• Jung Jong Mo
• Chae Jonghyun
• Lee Chul Haeng
• Chung Geun Chang
• Choi Young Cheol
• Choi Young Geun
• Yoon Seung Jae

Classifications

• H01M2300/0037

  Mixture of solvents · CPC title

• H01M4/136

  Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M10/0569 Primary

  characterised by the solvents · CPC title

• H01M2220/20

  Batteries in motive systems, e.g. vehicle, ship, plane · CPC title