Process for manufacturing paper using a base copolymer that has reacted with an aldehyde as a dry strength, retention, drainage and runnability aid

Patent metadata

Field	Value
Publication number	US-10132039-B2
Application number	US-201615296756-A
Country	US
Kind code	B2
Filing date	Oct 18, 2016
Priority date	Feb 27, 2012
Publication date	Nov 20, 2018
Grant date	Nov 20, 2018

Abstract

Process for manufacturing a sheet of paper and/or of paperboard and the like, according to which, the cellulosic material is brought into contact with at least one dry strength aid, characterized in that said dry strength aid is a cationic or amphoteric (co)polymer derived from the reaction between at least one aldehyde and at least one base (co)polymer comprising at least one nonionic monomer, said base copolymer being modified with at least one polyfunctional compound comprising at least three heteroatoms chosen from N, S, O and P, in which at least three of these heteroatoms each have at least one mobile hydrogen.

First claim

The invention claimed is:

1. A process for manufacturing a sheet of paper and/or of paperboard, said process comprising:
before or after formation of said sheet, bringing cellulosic material into contact with at least one additive, wherein said additive is a cationic or amphoteric (co)polymer derived from the reaction between at least one aldehyde and at least one base (co)polymer comprising at least one nonionic monomer selected from the group consisting of acrylamide, methacrylamide, N,N-dimethylacrylamide, and acrylonitrile, said base copolymer being modified, prior to the reaction with the at least one aldehyde, with at least one polyfunctional compound comprising at least three heteroatoms chosen from N, S, O and P, in which at least three of these heteroatoms each have at least one mobile hydrogen,
wherein the base (co)polymer is modified with at least one polyfunctional compound either by incorporation of the at least one polyfunctional compound(s) before or during polymerization of the constituent comonomers of the base (co)polymer, or by grafting of the at least one polyfunctional compound(s) to the base (co)polymer,
wherein the base (co)polymer, prior to the reaction with the at least one aldehyde, is modified in the absence of glyoxal,
wherein the polyfunctional compound(s) are selected from the group consisting of polyethyleneimines, primary polyamines, secondary polyamines, polyallylamines, polythiols, polyalcohols, polyamide-epichlorohydrin resins and polyamine amides, and
wherein the aldehyde is selected from the group consisting of glyoxal, glutaraldehyde furandialdehyde, 2-hydroxyadipaldehyde, succinaldehyde, dialdehyde starch, 2,2-dimethoxyethanal, diepoxy compounds, and combinations thereof.

2. The process according to claim 1 , wherein the polyfunctional compound is selected from the group consisting of polyethyleneimine and polyamine amide.

3. The process according to claim 2 , wherein the base copolymer is branched in the presence of a radical branching agent.

4. The process according to claim 3 , wherein the radical branching agent is selected from the group consisting of methylenebisacrylamide, ethylene glycol diacrylate, polyethylene glycol dimethacrylate, diacrylamide, cyanomethyl acrylate, vinyloxyethyl acrylate or methacrylate, and triallylamine.

5. The process according to claim 2 , wherein the aldehyde is glyoxal.

6. The process according to claim 1 , wherein the base copolymer is branched in the presence of a radical branching agent.

7. The process according to claim 6 , wherein the aldehyde is glyoxal.

8. The process according to claim 6 , wherein the radical branching agent is selected from the group consisting of methylenebisacrylamide, ethylene glycol diacrylate, polyethylene glycol dimethacrylate, diacrylamide, cyanomethyl acrylate, vinyloxyethyl acrylate or methacrylate, and triallylamine.

9. The process according to claim 8 , wherein the final cationic or amphoteric (co)polymer is derived from a reaction between:
15 to 25 wt % of glyoxal,
a base (co)polymer branched by means of a radical branching agent and comprising:
at least 5 mol % of acrylamide,
at least 100 ppm of polyethyleneimine,
5 to 50 mol % of at least one unsaturated cationic ethylenic comonomer, selected from the group consisting of monomers of dialkylaminoalkyl (meth)acrylamide, diallylamine and methyldiallylamine type and the quaternary ammonium or acid salts thereof, and
at least 100 ppm of a radical branching agent.

10. The process according to claim 1 , wherein the aldehyde is glyoxal.

11. The process according to claim 1 , wherein the cationic or amphoteric (co)polymer is derived from the reaction between:
from 1 to 30 wt % of at least one aldehyde selected from the group consisting of glyoxal, glutaraldehyde, furandialdehyde, 2-hydroxyadipaldehyde, succinaldehyde, dialdehyde starch, 2,2-dimethoxyethanal, diepoxy compounds, and combinations thereof,
with at least one base (co)polymer optionally branched by means of a radical branching agent and containing:
at least 5 mol % of a nonionic monomer selected from the group consisting of acrylamide, methacrylamide, N,N-dimethylacrylamide, and/or acrylonitrile,
at least 100 ppm of at least one polyfunctional compound selected from the group consisting of polyethyleneimine, primary polyamines, secondary polyamines polyallylamine, polythiols, polyalcohols, polyamide-epichlorohydrin resins and polyamine amides,
optionally at least:
one unsaturated cationic ethylenic monomer, selected from the group consisting of monomers of dialkylaminoalkyl (meth)acrylamide, diallylamine and methyldiallylamine type and the quaternary ammonium or acid salts thereof,
and/or a nonionic monomer selected from the group consisting of N-vinyl acetamide, N-vinyl formamide, N-vinylpyrrolidone and/or vinyl acetate,
and/or an anionic monomer of acid or anhydride type selected from the group consisting of (meth)acrylic acid, acrylamidomethylpropylsulphonic acid, itaconic acid, maleic anhydride, maleic acid, methallylsulphonic acid, vinyl sulphonic acid and salts thereof.

12. The process according to claim 11 , wherein the at least one additional polyfunctional compound includes polyethyleneimine.

13. The process according to claim 11 , wherein the optional at least one unsaturated cationic ethylenic monomer is selected from the group consisting of diallyldimethylammonium chloride, acrylamidopropyltrimethylammonium chloride, and methacrylamidopropyltrimethylammonium chloride.

14. The process according to claim 13 , wherein the at least one additional polyfunctional compound is selected from the group consisting of polyethyleneimine and polyamine amide.

15. The process according to claim 1 , wherein the final cationic or amphoteric (co)polymer is derived from reaction between:
15 to 25 wt % of glyoxal,
a base (co)polymer branched by means of a radical branching agent and comprising:
at least 5 mol % of acrylamide,
at least 100 ppm of polyethyleneimine,
5 to 50 mol % of at least one unsaturated cationic ethylenic comonomer, selected from the group consisting of monomers of dialkylaminoalkyl (meth)acrylamide, diallylamine and methyldiallylamine type and the quaternary ammonium or acid salts thereof, and
at least 100 ppm of a radical branching agent.

16. The process according to claim 15 , wherein the at least one unsaturated cationic ethylenic comonomer includes diallyldimethylammonium chloride.

Assignees

• Spcm Sa
• Spcm Sa

Inventors

• Hund René
• Barriere Cyril

Classifications

• C08F2800/10

  as molar percentages · CPC title

• D21H17/72

  of organic material · CPC title

• D21H17/455 Primary

  comprising tertiary amine or being at least partially quaternised · CPC title

• C08F8/28

  Condensation with aldehydes or ketones · CPC title

• D21H17/56

  Polyamines; Polyimines; Polyester-imides · CPC title