Powder coating composition

Patent metadata

Field	Value
Publication number	US-10131796-B2
Application number	US-201314438478-A
Country	US
Kind code	B2
Filing date	Mar 14, 2013
Priority date	Oct 26, 2012
Publication date	Nov 20, 2018
Grant date	Nov 20, 2018

Abstract

A coating composition comprising a blend of one or more polyester resins having a lower average molecular weight and higher melt flow index, where the coating composition is in the form of a powder having particles with a fine particle size distribution, and where the coating composition is configured to form a thin coating ( 34 ) that is substantially free of pores.

First claim

The invention claimed is:

1. A method for forming a coating on a container, the method comprising:
providing a coating composition comprising from about 50% by weight to 100% by weight of a blend of:
at least 70% by weight of one first semi-crystalline polyester with an average glass transition temperature ranging from about −20° C. to about 40° C., wherein the first semi-crystalline polyester has a weight average molecular weight from about 20,000 to about 50,000, a melt flow index of 80grams/10 minutes to 170 grams/10 minutes, and a melt viscosity of less than 200 Pascal-seconds; and
at least one second amorphous polyester with a glass transition temperature from 40° C. to 100° C., wherein the second amorphous polyester has a weight average molecular weight from about 40,000 to about 70,000, a melt flow index of 25 grams/10 minutes to 75 grams/10 minutes, and a melt viscosity greater than the melt viscosity of the first semi-crystalline polyester;
wherein the coating composition is in the form of a powder having particles with particle sizes such that at least about 95% by weight of the particles are capable of passing through a 63-micrometer sieve;

applying the coating composition in powder form to at least a portion of a substrate of the container;
melting the coating composition on the substrate or the portion thereof; and
solidifying a molten coating composition to form a coating adhered to the substrate or the portion thereof, the coating having an average coating thickness less than about 40 micrometers, and wherein the coating is substantially free of pores.

2. The method of claim 1 , and further comprising forming the substrate as a side seam of the container, and wherein applying the coating composition in powder form to the substrate or portion thereof comprises applying the coating composition to the side seam.

3. The method of claim 1 , wherein the average coating thickness ranges from about 25 micrometers to about 35 micrometers.

4. The method of claim 1 , wherein the blend of one or more polyesters has a melt viscosity less than about 200 Pascal-seconds.

5. A container comprising:
a side seam; and
a coating disposed on at least a portion of the side seam with an average coating thickness less than about 40 micrometers, wherein the coating is substantially free of pores, and is formed from a coating composition comprising:
at least 70% by weight of one first semi-crystalline polyester with an average glass transition temperature ranging from about −20° C. to about 40° C., wherein the first semi-crystalline polyester has a weight average molecular weight from about 20,000 to about 50,000, a melt flow index of 80 grams/10 minutes to 170 grams/10 minutes, and a melt viscosity of less than 200 Pascal-seconds; and
at least one second amorphous polyester with a glass transition temperature from 40° C. to 100° C., wherein the second amorphous polyester has a weight average molecular weight from about 40,000 to about 70,000, a melt flow index of 25 grams/10 minutes to 75 grams/10 minutes, and a melt viscosity greater than the melt viscosity of the first semi-crystalline polyester;
wherein the coating composition is in the form of a powder having particles with particle sizes such that at least about 95% by weight of the particles are capable of passing through a 63-micrometer sieve.

6. The container of claim 5 , wherein the average coating thickness ranges from about 25 micrometers to about 35 micrometers.

7. The container of claim 5 , wherein the blend of one or more polyesters comprises at least one first polyester having an average melting temperature ranging from about 120° C. to about 200° C.

8. The container of claim 5 , wherein the coating composition is substantially free or free of epoxy-functional compounds.

9. The container of claim 5 , wherein the blend of one or more polyesters has a melt viscosity less than about 200 Pascal-seconds.

10. A coating composition comprising:
from about 50% by weight to 100% by weight of a blend of:
at least 70% by weight of one first semi-crystalline polyester with an average glass transition temperature ranging from about −20° C. to about 40° C., wherein the first semi-crystalline polyester has a weight average molecular weight from about 20,000 to about 50,000, a melt flow index of 80 grams/10 minutes to 170 grams/10 minutes, and a melt viscosity of less than 200Pascal-seconds; and
at least one second amorphous polyester with a glass transition temperature from 40° C. to 100° C., wherein the second amorphous polyester has a weight average molecular weight from about 40,000 to about 70,000, a melt flow index of 25 grams/10 minutes to 75 grams/10 minutes, and a melt viscosity greater than the melt viscosity of the first semi-crystalline polyester;
wherein the coating composition is in the form of a powder having particles with particle sizes such that at least about 95% by weight of the particles are capable of passing through a 63-micrometer sieve; and
wherein the coating composition, when applied on a substrate, forms a coating having an average coating thickness less than about 40 micrometers, and wherein the coating is substantially free of pores.

11. The coating composition of claim 10 , wherein the blend of one or more polyesters comprises at least one first polyester having an average melting temperature ranging from about 120° C. to about 200° C.

12. The coating composition of claim 10 , wherein the blend of one or more polyesters has a melt viscosity less than about 200 Pascal-seconds.

13. The coating composition of claim 10 , wherein the melt flow index of the coating composition is greater than about 80 grams/10 minutes.

Assignees

• Valspar Sourcing Inc
• Sherwin Williams Co

Inventors

• Martinoni Raffaele
• Frischkopf Rolf

Classifications

• C09D167/02 Primary

  Polyesters derived from dicarboxylic acids and dihydroxy compounds (C09D167/06 takes precedence) · CPC title

• B65D7/42

  Details of metal walls (casks, barrels or drums in their entirety B65D7/045; other container details B65D23/00, B65D25/00) · CPC title

• B05D1/12

  Applying particulate materials (B05D1/06, B05D1/10 take precedence) · CPC title

• B05D3/0254

  After-treatment · CPC title

• C09D5/03 Primary

  Powdery paints · CPC title