Thermoplastic elastomer composition, stopper for medical container, and medical container

Patent metadata

Field	Value
Publication number	US-10131780-B2
Application number	US-201515304036-A
Country	US
Kind code	B2
Filing date	Apr 15, 2015
Priority date	Apr 16, 2014
Publication date	Nov 20, 2018
Grant date	Nov 20, 2018

Abstract

This thermoplastic elastomer composition comprises: 100 parts by mass of a hydrogenated block copolymer (a); from 3 to 50 parts by mass of a polypropylene-based resin (b), from 5 to 100 parts by mass of a polyphenylene ether resin (c), and from 50 to 200 parts by mass of a non-aromatic softener (d), the hydrogenated block copolymer (a) is able to be formed by hydrogenating a block copolymer that comprises at least one polymer block A comprising a vinyl aromatic hydrocarbon compound monomer unit as a primary component and at least one polymer block B comprising a conjugated diene compound monomer unit as a primary component, and a weight average molecular weight of the hydrogenated block copolymer (a) is from 100,000 to 350,000.

First claim

The invention claimed is:

1. A thermoplastic elastomer composition comprising:
100 parts by mass of a hydrogenated block copolymer (a);
from 3 to 50 parts by mass of a polypropylene-based resin (b);
from 5 to 100 parts by mass of a polyphenylene ether resin (c); and
from 50 to 200 parts by mass of a non-aromatic softener (d),
wherein
the hydrogenated block copolymer (a) comprises:
a hydrogenated block copolymer (a-1′) that is able to be formed by hydrogenating a block copolymer that comprises at least one polymer block A1 comprising a vinyl aromatic hydrocarbon compound monomer unit as a primary component and at least one polymer block B1 comprising a conjugated diene compound monomer unit as a primary component; and
a hydrogenated block copolymer (a-2) that is able to be formed by hydrogenating a block copolymer that comprises at least one polymer block A2 comprising a vinyl aromatic hydrocarbon compound monomer unit as a primary component and at least one polymer block B2 comprising a conjugated diene compound monomer unit as a primary component,
a weight average molecular weight of the hydrogenated block copolymer (a-1′) is from 140,000 to 350,000,
a weight average molecular weight of the hydrogenated block copolymer (a-2) is from 50,000 to 120,000, and
a mass ratio ((a-1′)/(a-2)) of the hydrogenated block copolymer (a-1′) and the hydrogenated block copolymer (a-2) is from 70/30 to 95/5.

2. The thermoplastic elastomer composition according to claim 1 , wherein a total content of vinyl aromatic hydrocarbon compound monomer units in the hydrogenated block copolymer (a-2) is from 10 to 25 mass %.

3. The thermoplastic elastomer composition according to claim 1 , wherein a vinyl bond content before hydrogenation in the conjugated diene compound monomer units in the hydrogenated block copolymer (a-2) is from 40 to 60 mol. %.

4. The thermoplastic elastomer composition according to claim 1 , wherein heat of crystal fusion (AH) of the hydrogenated block copolymer (a-2) is less than 0.5 J/g.

5. The thermoplastic elastomer composition according to claim 1 , wherein a total content of vinyl aromatic hydrocarbon compound monomer units in the hydrogenated block copolymer (a-1′) is from 26 to 70 mass %.

6. The thermoplastic elastomer composition according to claim 1 , wherein a vinyl bond content before hydrogenation in the conjugated diene compound monomer units in the hydrogenated block copolymer (a-1′) is from 30 to 60 mol. %.

7. The thermoplastic elastomer composition according to claim 1 , wherein
the hydrogenated block copolymer (a-1′) has at least two polymer blocks A1 and at least two polymer blocks B1, and
at least one of the polymer blocks B1 is located at a polymer end and a content of said polymer block B1 located at a polymer end is from 0.5 to 9 mass %.

8. The thermoplastic elastomer composition according to claim 1 , wherein a reduced viscosity of the polyphenylene ether resin (c) is from 0.15 to 0.70 dL/g.

9. The thermoplastic elastomer composition according to claim 1 , wherein the non-aromatic softener (d) is a non-aromatic softener (d-1) having a kinematic viscosity at 40° C. of from 300 to 400 mm 2 /sec.

10. The thermoplastic elastomer composition according to claim 1 , wherein the non-aromatic softener (d) is a non-aromatic softener (d-2) having a kinematic viscosity at 40° C. of 100 mm 2 /sec or less.

11. The thermoplastic elastomer composition according to claim 1 , wherein
the non-aromatic softener (d) is a mixture of a non-aromatic softener (d-1) having a kinematic viscosity at 40° C. of from 300 to 400 mm 2 /sec and a non-aromatic softener (d-2) having a kinematic viscosity at 40° C. of 100 mm 2 /sec or less,
a mass ratio ((d-1)/(d-2)) of the non-aromatic softener (d-1) and the non-aromatic softener (d-2) is from 30/70 to 60/40, and
a total content of the non-aromatic softener (d-1) and the non-aromatic softener (d-2) is from 100 to 200 parts by mass relative to 100 parts by mass of the hydrogenated block copolymer (a).

12. The thermoplastic elastomer composition according to claim 1 , wherein
a number average molecular weight Mn(A1′) of a block chain of a polymer block A1′ that has the greatest number average molecular weight among the polymer blocks A1 is from 5,000 to 60,000,
the number average molecular weight Mn(c) of the polyphenylene ether resin (c) is from 1,000 to 50,000, and
Mn(A1′)/Mn(c)=1.2-3.0.

13. The thermoplastic elastomer composition according to claim 1 , wherein a content of the polypropylene-based resin (b) is from 15 to 50 parts by mass relative to 100 parts by mass of the hydrogenated block copolymer (a).

14. The thermoplastic elastomer composition according to claim 1 , wherein an average particle diameter of the polyphenylene ether resin (c) is from 100 to 500 μm.

15. The thermoplastic elastomer composition according to claim 1 , which has a hardness of 40 or lower and a compression set of 35% or lower.

16. The thermoplastic elastomer composition according to claim 1 , further comprising carbon black (e) and/or an inorganic filler (f) at a quantity of from 3 to 100 parts by mass relative to 100 parts by mass of the hydrogenated block copolymer (a).

17. The thermoplastic elastomer composition according to claim 1 , which is partially crosslinked in the presence of an organic peroxide (g).

18. A stopper for a medical container, comprising a sealing material that comprises the thermoplastic elastomer composition according to claim 1 .

19. A medical container comprising the stopper for a medical container according to claim 18 .

Assignees

• Asahi Chemical Ind

Inventors

• Yagi Noriko
• Horiuchi Mika

Classifications

• C08L2205/03

  containing three or more polymers in a blend · CPC title

• C08L2205/06

  having improved processability or containing aids for moulding methods · CPC title

• C08L91/00

  Compositions of oils, fats or waxes; Compositions of derivatives thereof · CPC title

• A61J1/1406

  Septums, pierceable membranes · CPC title

• C08L53/025 Primary

  modified · CPC title