Process to produce polycarbamate, polycarbamate produced thereby and a coating composition comprising the polycarbamate

US10131746B2 · US · B2

Patent metadata
FieldValue
Publication numberUS-10131746-B2
Application numberUS-201414912160-A
CountryUS
Kind codeB2
Filing dateAug 15, 2014
Priority dateAug 15, 2013
Publication dateNov 20, 2018
Grant dateNov 20, 2018

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  1. Title

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  2. Abstract

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  3. Assignees and inventors

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  4. Key dates

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  5. First independent claim

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Abstract

Official abstract text for this publication.

A process to prepare polycarbamate comprising adding urea to a polyol in the presence of at least one catalyst selected from the group consisting of compounds having the following formula M m Z n ; wherein M is a tetravalent metal, and Z is an anionic functionality or a functionality capable of forming a covalent bond with M and wherein n times a valence number of Z equals X and m times four equals Y wherein the absolute value of X equals the absolute value of Y is provided. Also provided are a polycarbamate produced according to the process and a coating composition comprising the polycarbamate.

First claim

Opening claim text (preview).

We claim: 1. A process to prepare polycarbamate comprising: adding urea to an acrylic polyol in the presence of at least one catalyst selected from the group consisting of Titanium(IV) isopropoxide, Zr(IV) acetylacetonate, and Zirconium (IV) 2-ethylhexanoate, wherein the process exhibits equal to or greater than 50% hydroxyl conversion at a reaction time from 10 to 20 hours and a reaction temperature from 138-142° C., to form a polycarbamate polymer, and separating a solid reaction product wherein the solid reaction product contains less than 2.5 wt % combined amounts of biuret, cyanuric acid and polyallophanate. 2. The process according to claim 1 , wherein a second catalyst selected from the group consisting of carbamylation catalysts is present. 3. The process according to claim 2 , wherein the second catalyst is dibutyltin oxide and/or dibutyltin acetate. 4. A polycarbamate produced according to the process of claim 1 , wherein said polycarbamate includes less than 2.5 wt % of combined amounts of biuret, cyanuric acid and polyallophanate. 5. A coating comprising the polycarbamate according to claim 1 . 6. The polycarbamate of claim 4 , wherein a 100% solids product of the polycarbamate comprises less than 1 wt % of total biuret, cyanuric acid, and polyallophanate.

Assignees

Inventors

Classifications

  • from compounds containing nitrogen and active hydrogen, the nitrogen atom not being part of an isocyanate group · CPC title

  • acyclic · CPC title

  • acyclic · CPC title

  • Polyurethanes · CPC title

  • C08G71/04Primary

    Polyurethanes · CPC title

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What does patent US10131746B2 cover?
A process to prepare polycarbamate comprising adding urea to a polyol in the presence of at least one catalyst selected from the group consisting of compounds having the following formula M m Z n ; wherein M is a tetravalent metal, and Z is an anionic functionality or a functionality capable of forming a covalent bond with M and wherein n times a valence number of Z equals X and m times four eq…
Who is the assignee on this patent?
Dow Global Technologies Llc
What technology area does this patent fall under?
Primary CPC classification C08G71/04. Mapped technology areas include Chemistry & Metallurgy.
When was this patent published?
Publication date Tue Nov 20 2018 00:00:00 GMT+0000 (Coordinated Universal Time) (B2). Legal status and post-grant events are not shown on this page.
What related patents are in patentsdb?
We list 2 related publications on this page (citations in our corpus or others sharing the same primary CPC).