Systems and methods for producing hydrogen from a hydrocarbon and using the produced hydrogen in a hydrogenation reaction

Patent metadata

Field	Value
Publication number	US-10131593-B2
Application number	US-201414910161-A
Country	US
Kind code	B2
Filing date	Aug 5, 2014
Priority date	Aug 6, 2013
Publication date	Nov 20, 2018
Grant date	Nov 20, 2018

Abstract

To reduce the emission of carbon dioxide and improve the energy efficiency in a hydrogen supply system. The hydrogen supply system (1) comprises: a reformer (5) for performing steam reforming of a hydrocarbon; a shift reaction unit (6) for producing a gas containing hydrogen and carbon dioxide by causing a water gas shift reaction of a gas obtained from the reformer; a first absorber (36) for absorbing the carbon dioxide contained in the gas obtained from the shift reaction unit in an absorption liquid; a hydrogenation reaction unit (8) for producing a hydrogenated aromatic compound by causing a hydrogenation reaction of an aromatic compound with a gas that has passed through the first absorber; and a regenerator (37) for separating the carbon dioxide from the absorption liquid by re-circulating the absorption liquid from the first absorber and heating the absorption liquid with heat generated from the hydrogenation reaction.

First claim

The invention claimed is:

1. A hydrogen supply system, comprising:
a reformer configured to perform steam reforming of a hydrocarbon mainly consisting of methane to produce a gas containing hydrogen and carbon dioxide;
a shift reaction unit configured to produce the gas containing hydrogen and carbon dioxide by causing a water gas shift reaction of a gas obtained from the reformer;
a first absorber configured to absorb the carbon dioxide contained in the gas obtained from the shift reaction unit in an absorption liquid to thereby produce a gas freed from the carbon dioxide;
a hydrogen purification unit configured to receive the gas produced by the first absorber and separate the hydrogen from the gas received from the first absorber such that the separated hydrogen constitutes purified hydrogen;
a hydrogenation reaction unit connected to the hydrogen purification unit to receive the purified hydrogen from the hydrogen purification unit and configured to produce a hydrogenated aromatic compound by causing a hydrogenation reaction of an aromatic compound with the purified hydrogen received from the hydrogen purification unit;
a regenerator connected to the first absorber and configured to separate the carbon dioxide from the absorption liquid by re-circulating the absorption liquid from the first absorber and heating the absorption liquid with heat generated from the hydrogenation reaction;
a heating furnace configured to receive the gas remaining after the hydrogen is separated by the hydrogen purification unit, combust the received gas, and supply combustion heat generated thereby to the reformer; and
a pressure injection unit configured to pressure inject the carbon dioxide that is separated from the absorption liquid by the regenerator into a pressure injection well in order to increase a fluidity of the fossil fuel buried underground when extracting fossil fuel buried underground, the reformer being connected to a production well and configured to extract the fossil fuel and reform at least a part of product gas produced as the fossil fuel or associated gas thereof that is extracted from the production well.

2. The hydrogen supply system according to claim 1 , further comprising
a second absorber configured to absorb carbon dioxide generated from the heating furnace in an absorption liquid;
wherein the second absorber re-circulates the absorption liquid to the regenerator, and the absorption liquid that has absorbed the carbon dioxide in the second absorber is heated in the regenerator to separate the carbon dioxide therefrom.

3. The hydrogen supply system according to claim 1 , wherein the heat generated by the hydrogenation reaction is supplied to the regenerator as steam at a temperature of 100 to 200° C. and a pressure of 0.10 to 1.62 MPaA.

4. The hydrogen supply system according to claim 1 , further comprising a first separation unit having an inorganic membrane configured to separate the hydrogen and the carbon dioxide in the gas obtained from the shift reaction unit from each other.

5. The hydrogen supply system according to claim 4 , wherein the production well is provided in a shale formation for extracting natural gas, and the natural gas is extracted as the fossil fuel.

6. The hydrogen supply system according to claim 5 , wherein the product gas includes the natural gas extracted from the shale formation and the pressure injected carbon dioxide, and the system further comprises a second separation unit configured to separate the natural gas and the carbon dioxide of the product gas from each other,
the reformer reforming at least part of the natural gas separated by the second separation unit, and the pressure injection unit pressure injecting the carbon dioxide separated by the second separation unit into the pressure injection well in order to increase a fluidity of the fossil fuel buried underground.

7. The hydrogen supply system according to claim 1 , wherein the production well is provided in an oil field for extracting petroleum, and the petroleum is extracted as the fossil fuel.

8. The hydrogen supply system according to claim 1 , further comprising a desulfurization unit configured to remove a sulfur content from the product gas before the product gas is reformed by the reformer.

Assignees

• Chiyoda Corp

Inventors

• Okada Yoshimi
• Shirasaki Tomohiko
• Ikeda Osamu
• Imagawa Kenichi
• Kawai Hironori
• Shiraga Masato
• Ishiyama Tatsuo

Classifications

• B01D2257/304

  Hydrogen sulfide · CPC title

• B01J2219/00051

  Controlling the temperature · CPC title

• B01D53/265

  by refrigeration (condensation) · CPC title

• B01D53/75

  Multi-step processes · CPC title

• C01B2203/0405

  Purification by membrane separation · CPC title