Electrochemical cells for supply of acid water

Patent metadata

Field	Value
Publication number	US-10131553-B2
Application number	US-201414648808-A
Country	US
Kind code	B2
Filing date	Jan 30, 2014
Priority date	Jan 30, 2013
Publication date	Nov 20, 2018
Grant date	Nov 20, 2018

Abstract

Provided are water treatment systems where acid water from electrochemical devices are provided to waste streams of ion reduction devices. Specifically, electro-chemical cells having strong acid cation resins are operated to produce acid water that is supplied to the waste stream of an aqueous separation unit, for example an ion reduction device that includes, but it not limited to: deionization systems, continuous or batch-wise, and reverse-osmosis systems.

First claim

What is claimed is:

1. A water treatment system comprising: an ion reduction device and an electrochemical cell in fluid communication with a waste stream of the ion reduction device, the electrochemical device supplying acid water to the waste stream to flush ions from an ion concentration compartment of the ion reduction device; and
wherein the ion reduction device further comprises: an inlet stream, an outlet stream; and a plurality of compartments each separated by an ion-permeable membrane, wherein each compartment comprises one or more deionized liquid compartments that receive the inlet stream and supply the outlet stream and one or more ion concentration compartments that are in fluid communication with the waste stream; and
the electrochemical cell has a service mode and a recharge mode, the electrochemical cell comprising:
a first product compartment containing a strong acid cation resin;
a first catholyte compartment and a first anolyte compartment;
a cation-permeable membrane and a bipolar membrane; and
a first cathode adjacent to the first catholyte compartment and an anode adjacent to the first anolyte compartment;
wherein during the service mode, water that is acidic flows from the product compartment into the waste stream of the ion reduction device.

2. The water treatment system of claim 1 , wherein the waste stream comprises a recycle loop and a slip stream.

3. The water treatment system of claim 1 , wherein the acidic water has a pH that is sufficient to reduce scale and/or prevent precipitation of salts in the one or more ion concentration compartments.

4. The water treatment system of claim 1 , wherein the electrochemical cell is operated batch-wise and during the service mode no current density is applied to the electrochemical cell and during the recharge mode a current density is applied to the electrochemical cell.

5. The water treatment system of claim 4 , wherein the current density is a low current density effective to substantially keep dissolved ions in solution in regions adjacent to the surfaces of the cation-permeable and bipolar membranes during the recharge mode.

6. The of water treatment system claim 1 , wherein the electrochemical cell comprises two or more product compartments being separated by one or more concentrate compartments and containing strong cation resins, each product compartment bounded by a pair of cation-permeable and bipolar membranes.

7. The water treatment system of claim 1 , wherein the electrochemical cell further comprises:
a second product compartment comprising a strong cation resin;
a second cathode adjacent to a second catholyte compartment that is adjacent to the second product compartment and a second anolyte compartment that is adjacent to the anode.

8. The water treatment system of claim 2 , wherein the electrochemical cell further comprises a scale inhibition device.

9. The water treatment system of claim 8 , wherein the scale inhibition device comprises a control system for applying the low current density to the electrochemical cell, for pulsing the low current density to the electrochemical cell, or both.

10. The water treatment system of claim 8 , wherein the scale inhibition device comprises one or more fluid conveyance layers.

11. The water treatment system of claim 10 , wherein the surfaces of the one or more fluid conveyance layers comprise non-smooth surface features.

12. A method of treating water comprising: operating an ion reduction device, flowing water through an electrochemical cell to produce acid water, supplying the acid water to a waste stream of the ion reduction device to flush ions from an ion concentration compartment of the ion reduction device; and wherein
the ion reduction device comprises:
an inlet stream, an outlet stream, and a waste stream;
a plurality of compartments each separated by an ion-permeable membrane, wherein each compartment comprises one or more deionized liquid compartments that receive the inlet stream and supply the outlet stream and one or more ion concentration compartments that are in fluid communication with the waste stream;
and the electrochemical cell has a service mode and a recharge mode, the electrochemical cell comprising:
a first product compartment containing a strong acid cation resin;
a first catholyte compartment and a first anolyte compartment;
a cation-permeable membrane and a bipolar membrane; and
a first cathode adjacent to the first catholyte compartment and an anode adjacent to the first anolyte compartment;
wherein acid water is produced from the product compartment during the service mode.

13. The method of claim 12 , wherein the waste stream comprises a recycle loop and a slip stream and the acid water is provided to the recycle loop.

14. The method of claim 12 , comprising reducing scale and/or preventing precipitation of salts in the one or more ion concentration compartments.

15. The method of claim 12 , wherein the step of providing the acid water to the waste stream occurs at intervals based on time, quality of the waste stream, or combinations thereof.

16. The method of claim 12 , further comprising ceasing supplying the acid water to the waste stream at intervals based on time, quality of the waste stream, or combinations thereof.

17. The method of claim 15 , wherein the quality of the waste stream comprises conductivity, pH, total dissolved solids, LSI (Langelier Saturation Index), temperature, or combinations thereof.

18. The method of claim 16 , wherein the quality of the waste stream comprises conductivity, pH, total dissolved solids, LSI (Langelier Saturation Index), temperature, or combinations thereof.

19. The method of claim 12 , wherein the electrochemical cell is operated batch-wise, and during the service mode no current density is applied to the electrochemical cell during the recharge mode a current density is applied to the electrochemical cell.

20. The method of claim 19 , wherein the current density is a low current density is effective to substantially keep dissolved ions in solution in regions adjacent to the surfaces of the cation-permeable and bipolar membranes during the recharge mode.

21. The method of claim 19 , wherein during the service mode where no current density is applied to the electrochemical cell, the water passes through the first product compartment and contacts the strong acid cation resin, exiting the first product compartment in an acidic form; and wherein during the recharge mode where the current density is applied to the electrochemical cell, a concentrate stream enters the first catholyte and the first anolyte compartments and contacts the cation-permeable and the bipolar membranes, exiting first catholyte and the first anolyte compartments with an increased amount of ions as compared to when the concentrate stream entered the first catholyte and the first anolyte compartments, and after the recharge mode, the strong acid cation resin has fewer ions as compared to when the recharge mode started.

22. The method of claim 19 , wherein the electrochemical cell comprises two or more product compartments being separated by one or more concentrate compartments and containing strong cation resins, each product compartment bounded by a pair of cation-permeable and bipolar membranes;
wherein during the service mode where no current density is applied to the electrochemical cell, the water passes through the two or more product compartments and contacts the strong acid cation resins, exi

Assignees

• 3M Innovative Properties Co

Inventors

• Astle Robert E

Classifications

• C02F1/42 Primary

  by ion-exchange (ion-exchange in general B01J) · CPC title

• C02F2201/46105

  Details relating to the electrolytic devices · CPC title

• C25B15/08

  Supplying or removing reactants or electrolytes; Regeneration of electrolytes · CPC title

• C02F2001/46185

  only anodic or acidic water, e.g. for oxidizing or sterilizing · CPC title

• C02F1/4618 Primary

  for producing "ionised" acidic or basic water · CPC title