Modification of layered double hydroxides

Patent metadata

Field	Value
Publication number	US-10131548-B2
Application number	US-201615168783-A
Country	US
Kind code	B2
Filing date	May 31, 2016
Priority date	Dec 22, 2011
Publication date	Nov 20, 2018
Grant date	Nov 20, 2018

Abstract

The present invention relates to a process for modifying a layered double hydroxide (LDH), the process comprising, a. providing a material comprising a layered double hydroxide of formula: [M z+ 1-x M′ y+ x (OH) 2 ] q+ (X n− ) q/n .bH 2 O wherein M and M′ are metal cations, z is 1 or 2, x is 0.1 to 1, b is 0 to 5, y is 3 or 4, X is an anion, n is 1 to 3 and q is determined by x, y and z, b. optionally washing the material at least once with a mixture of water and a mixing solvent miscible with water, and c. washing the material obtained in step a or b at least once with at least one first solvent, the first solvent being miscible with water and having a solvent polarity P′.

First claim

What is claimed is:

1. A modified layered double hydroxide obtained by washing a particulate comprising a layered double hydroxide at least once with a first solvent to obtain a modified layered double hydroxide, wherein the layered double hydroxide has the formula
[M z+ 1-x M′ y+ x (OH) 2 ] q+ (X n− ) q/n .b H 2 O

wherein M and M′ are metal cations, z is 1 or 2, x is 0.1 to 1, b is 0 to 5, y is 3 or 4, X is an anion, n is 1 to 3 and q is determined by x, y and z; and wherein the first solvent is a water miscible solvent having a solvent polarity P′ in the range of 3.8 to 9,
wherein the modified layered double hydroxide is dispersible in a hydrocarbon solvent.

2. The modified layered double hydroxide of claim 1 wherein X is selected from halide, inorganic oxyanion, anionic surfactants, anionic chromophores, anionic UV absorbers, or mixtures thereof.

3. The modified layered double hydroxide of claim 1 wherein the particle size of the layered double hydroxide particulate is in the range of 1 nm to 50 microns.

4. The modified layered double hydroxide of claim 1 wherein z is 2 and M is Ca, Mg, Zn, Fe, or a mixture thereof.

5. The modified layered double hydroxide of claim 1 wherein M′ is Al.

6. A hydrocarbon-dispersed layered double hydroxide dispersion formed by adding a hydrocarbon solvent to the modified layered double hydroxide of claim 1 .

7. The hydrocarbon-dispersed layered double hydroxide of claim 6 wherein the hydrocarbon solvent comprises an aromatic compound.

8. The hydrocarbon-dispersed layered double hydroxide of claim 7 wherein the aromatic compound is selected from benzene, toluene, xylene, mesitylene, benzyl alcohol, chlorobenzene, o-dichlorobenzene, trichlorobenzene, or a mixture of two or more thereof.

9. A polymer loaded hydrocarbon dispersion formed by dissolving a polymer in the hydrocarbon-dispersed layered double hydroxide of claim 6 .

10. The polymer loaded hydrocarbon dispersion of claim 9 wherein the polymer is selected from polyolefins, vinyl polymers, saturated polyesters, or mixtures thereof.

11. The polymer loaded hydrocarbon dispersion of claim 9 wherein the polymer is polyethylene, polypropylene, or a mixture thereof.

12. A composite composition obtained by precipitating the polymer loaded hydrocarbon dispersion of claim 9 .

13. The composite composition of claim 12 wherein the layered double hydroxide is present in the composition at 0.01 wt % to 85 wt % based on the weight of the polymer.

14. A method for forming a modified layered double hydroxide, the method comprising washing a particulate comprising a layered double hydroxide at least once with a first solvent to obtain a modified layered double hydroxide, wherein the layered double hydroxide has the formula
[M z+ 1-x M′ y+ x (OH) 2 ] q+ (X n− ) q/n .b H 2 O

wherein M and M′ are metal cations, z is 1 or 2, x is 0.1 to 1, b is 0 to 5, y is 3 or 4, X is an anion, n is 1 to 3 and q is determined by x, y and z; and wherein the first solvent is a water miscible solvent having a solvent polarity P′ in the range of 3.8 to 9,
wherein the modified layered double hydroxide is dispersible in a hydrocarbon solvent.

15. The method of claim 14 further comprising washing the layered double hydroxide with a mixture of water and a water miscible solvent prior to the washing with the first solvent.

16. The method of claim 15 wherein the water miscible solvent mixed with water is a C 1 to C 3 alcohol.

17. The method of claim 14 wherein the first solvent is selected from acetone, acetonitrile, dimethylformamide, dimethyl sulfoxide, dioxane, ethanol, methanol, n-propanol, 2-propanol, tetrahydrofuran, or a mixture of two or more thereof.

18. The method of claim 14 further comprising dispersing the modified layered double hydroxide in a hydrocarbon solvent to form a hydrocarbon-dispersed layered double hydroxide.

19. The method of claim 18 wherein the hydrocarbon solvent comprises an aromatic compound.

20. The method of claim 19 wherein the hydrocarbon solvent is selected from benzene, toluene, xylene, mesitylene, benzyl alcohol, chlorobenzene, o-dichlorobenzene, trichlorobenzene, or a mixture of two or more thereof.

Assignees

• Scg Chemicals Co Ltd

Inventors

• O'Hare Dermot
• Wang Qiang

Classifications

• C01P2002/50

  Solid solutions · CPC title

• C08K2003/3045

  Sulfates · CPC title

• C01F11/00

  Compounds of calcium, strontium, or barium (C01F7/00 takes precedence) · CPC title

• C01P2004/04

  obtained by TEM, STEM, STM or AFM · CPC title

• C09C1/40

  Compounds of aluminium {(C09C1/0009, C09C1/0015, C09C1/0078, C09C1/32 take precedence)} · CPC title