Coating agent based on a copper-nanoparticle biohybrid and use thereof as a biocidal agent
US-2024180162-A1 · Jun 6, 2024 · US
US10131482B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10131482-B2 |
| Application number | US-201414331439-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 15, 2014 |
| Priority date | Jul 16, 2013 |
| Publication date | Nov 20, 2018 |
| Grant date | Nov 20, 2018 |
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A packaging material includes an antimicrobial agent adhered to a substrate. The antimicrobial agent can include copper, and the packaging material can include cellulose. The substrate can be paperboard, and the copper can be a copper salt, such as copper sulfate. The packaging material may be provided by causing adherence between the substrate and the antimicrobial agent, such as by coating the substrate with the antimicrobial agent. Then, the packaging material may be cut into sheets. The sheets may be formed into cartons or other suitable packages.
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What is claimed is: 1. A package comprising a carton and a plurality of beverage containers, the carton comprising: a substrate comprising paperboard, the substrate extending at least partially around an interior of the carton, the substrate comprising an interior surface facing the interior of the carton; and a coating adhered to at least a portion of the interior surface of the substrate so that the coating extends at least partially around the interior of the carton, the coating comprising an antimicrobial agent that is at least partially exposed to the interior of the carton on an innermost surface of the carton, the antimicrobial agent comprising copper salt; wherein the plurality of beverage containers are disposed in the interior of the carton and a beverage that has leaked from at least one beverage container of the plurality of beverage containers is in the interior of the carton, and the beverage is at least partially in contact with the coating on the innermost surface of the carton so that the copper salt is at least partially dispersed in the beverage that has leaked from the at least one beverage container in the interior of the carton. 2. The packaging material of claim 1 , wherein the antimicrobial agent further comprises an inorganic salt. 3. The packaging material of claim 1 , wherein the copper salt comprises copper sulfate. 4. The packaging material of claim 1 , wherein: the copper salt is a first inorganic material, and the antimicrobial agent further comprises a second inorganic material. 5. The packaging material of claim 4 , wherein the second inorganic material is a salt. 6. The packaging material of claim 4 , wherein the second inorganic material is calcium hydroxide. 7. The packaging material of claim 1 , further comprising a coating adhered to the outer surface of the substrate, wherein the coating adhered to the outer surface of the substrate comprises an antimicrobial agent. 8. The packaging material of claim 7 , wherein the coating adhered to the outer surface of the substrate further comprises pigment. 9. The packaging material of claim 1 , wherein the antimicrobial agent further comprises an organic biocide. 10. The packaging material of claim 9 , wherein the organic biocide comprises isothiazolone. 11. The packaging material of claim 1 , wherein the coating further comprises pigment. 12. A package comprising a carton and a plurality of beverage containers, the carton comprising: a substrate comprising paperboard, the substrate extending at least partially around an interior of the carton, the substrate comprising an interior surface facing the interior of the carton; and a coating adhered to at least a portion of the interior surface of the substrate so that the coating extends at least partially around the interior of the carton, the coating comprising an antimicrobial agent that is at least partially exposed to the interior of the carton on the innermost surface of the carton, the antimicrobial agent comprising copper sulfate; wherein the plurality of beverage containers are disposed in the interior of the carton and a beverage that has leaked from at least one beverage container of the plurality of beverage containers is in the interior of the carton, and the beverage is at least partially in contact with the coating on the innermost surface of the carton so that the copper sulfate is at least partially dispersed in the beverage that has leaked from the at least one beverage container in the interior of the carton. 13. The packaging material of claim 12 , wherein: the copper sulfate is a first inorganic material, and the antimicrobial agent further comprises a second inorganic material selected from the group consisting of a salt and calcium hydroxide. 14. The packaging material of claim 12 , wherein the antimicrobial agent further comprises an organic biocide. 15. The packaging material of claim 12 , wherein the coating further comprises pigment. 16. The packaging material of claim 12 , further comprising a coating adhered to the outer surface of the substrate, wherein the coating adhered to the outer surface of the substrate comprises an antimicrobial agent. 17. The packaging material of claim 16 , wherein the coating adhered to the outer surface of the substrate further comprises pigment. 18. A method, comprising: at least partially providing a packaging material, the packaging material comprising a substrate and a coating adhered to a first surface of the substrate, wherein the substrate comprises cellulose, the coating comprises an antimicrobial agent, the antimicrobial agent comprises copper salt, and the packaging material is in the form of a carton blank; then forming the carton blank into a carton so that the packaging material extends at least partially around an interior space of the carton, the first surface faces toward the interior space, and a second surface of the substrate faces away from the interior space, wherein the first and second surfaces of the substrate are opposite from one another; loading a plurality of beverage containers at least partially into the interior space; and dispersing the copper salt in a beverage that has leaked from at least one beverage container of the plurality of beverage containers in the interior space. 19. The method of claim 18 , wherein: the at least partially providing is comprised of printing the coating on the first side of the substrate, and the coating further comprises pigment. 20. The method of claim 18 , wherein the coating is an ink that comprises the antimicrobial agent. 21. The method of claim 18 , wherein: the substrate comprises paperboard, and the copper salt comprises copper sulfate.
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