CO2 sorption by supported amino acid ionic liquids

Patent metadata

Field	Value
Publication number	US-10130911-B2
Application number	US-201715428017-A
Country	US
Kind code	B2
Filing date	Feb 8, 2017
Priority date	Jul 13, 2012
Publication date	Nov 20, 2018
Grant date	Nov 20, 2018

Abstract

The present invention concerns the absorption and desorption behavior of carbon dioxide (CO 2 ) using ionic liquids derived from amino acids adsorbed on porous carrier materials.

First claim

What is claimed:

1. A method for absorption of gaseous CO 2 from a gas stream and desorption of the absorbed CO 2 , which method comprises contacting said gas stream with a composition at ambient temperature and pressure, wherein the composition comprises:
an ionic compound [A + ][B − ] supported on a porous material, wherein
[A + ] is an ammonium ion ([N6666]) of Formula I

wherein R 1 , R 2 , R 3 and R 4 are linear C 6 alkyl chains, and

[B − ] is an anion selected from the group consisting of L-Isoleucinate ([Ile]), Glycinate ([Gly]), L-Tyrosinate ([Tyr]) and L-Prolinate ([Pro]), and
desorbing the CO 2 absorbed on the composition by temperature swing absorption (TSA), by increasing the temperature of the composition, by decreasing the total pressure surrounding it, and/or by flushing it with a gas stream with no or lower CO 2 content than the gas stream originally applied for the absorption.

2. The method according to claim 1 , wherein the composition contains 40% w/w of an ionic compound selected from the group consisting of [N6666][Ile], [N6666][Gly] and [N6666][Pro].

3. The method according to claim 1 , wherein the absorption takes place from a gas stream which contains 1-100 mol % CO 2 with an absorption capacity of over 1 mol CO 2 /mol of the ionic compound [A + ][B − ].

4. The method according to claim 1 , wherein the gas stream is a flue-gas stream generated from combustion by large point stationary sources.

5. The method according to claim 4 , wherein the large point stationary sources are power plants.

6. The method according to claim 1 , wherein the contact between the gas stream and the composition takes place in a fixed-bed or movable-bed reactor.

7. The method according to claim 1 , wherein the anion is selected from the group consisting of L-Isoleucinate ([Ile]), Glycinate ([Gly]) and L-Prolinate ([Pro]).

8. The method according to claim 1 , wherein the porous material is selected from the group consisting of porous (including mesoporous) inorganic, carbonaceous or polymeric materials.

9. The method according to claim 8 , wherein the porous material is selected from the group consisting of silica, hydrophobic mesoporous silica, controlled pore glass, alumina, titania (anatase), zirconia, alkaline earth metal oxides, clays and zeolites, or mixtures hereof.

10. The method according to claim 1 , wherein the composition contains between 5-45 w/w of the ionic compound [A + ][B − ].

11. The method according to claim 10 , wherein the composition contains 10% w/w of the ionic compound [A + ][B].

12. The method according to claim 10 , wherein the composition contains 20% w/w of the ionic compound [A + ][B − ].

13. The method according to claim 10 , wherein the composition contains 30% w/w of the ionic compound [A + ][B − ].

14. The method according to claim 10 , wherein the composition contains 40% w/w of the ionic compound [A + ][B − ].

Assignees

• Univ Danmarks Tekniske

Inventors

• Fehrmann Rasmus
• Riisager Anders
• Kolding Helene
• Shunmugavel Saravanamurugan

Classifications

• B01D53/1475

  Removing carbon dioxide · CPC title

• B01D53/62 Primary

  Carbon oxides · CPC title

• B01D2252/30

  Ionic liquids and zwitter-ions · CPC title

• B01D53/1493

  Selection of liquid materials for use as absorbents · CPC title

• B01J20/3204 Primary

  Inorganic carriers, supports or substrates · CPC title