Process for purifying hydrocarbons

Patent metadata

Field	Value
Publication number	US-10130896-B2
Application number	US-201414770649-A
Country	US
Kind code	B2
Filing date	Feb 26, 2014
Priority date	Feb 26, 2013
Publication date	Nov 20, 2018
Grant date	Nov 20, 2018

Abstract

A process for washing hydrocarbons said process comprising: (I) distilling a crude acetone mixture preferably obtained from the cleavage of cumene hydroperoxide and containing hydrocarbons and water so as to form a bottoms fraction containing said hydrocarbons in an organic phase and an aqueous phase; (II) contacting at least a part of said bottoms fraction with an aqueous metal hydroxide solution so as to provide a concentration of 0.1 to 5 wt % MOH, where M is an alkali metal, in the aqueous phase; (III) separating the aqueous phase and the organic phase; (IV) contacting at least a part the organic phase from step (III) with an aqueous metal hydroxide solution so as to provide a concentration of 6 to 20 wt % MOH in the aqueous phase; (V) separating the organic phase and aqueous phase formed in step (IV); (VI) washing at least a part of the organic phase of step (V) with water.

First claim

The invention claimed is:

1. A process comprising:
(I) distilling a crude acetone mixture containing hydrocarbons and water to form a bottoms fraction containing an organic phase and an aqueous phase, wherein the organic phase contains cumene and alpha methyl styrene; wherein the crude acetone mixture is obtained from the cleavage of cumene hydroperoxide;
(II) contacting at least a part of said bottoms fraction with an aqueous metal hydroxide solution, thereby forming an organic phase and an aqueous phase, wherein the aqueous metal hydroxide solution provides a concentration of 0.1 to 5 wt % MOH, where M is an alkali metal, in the aqueous phase;
(III) separating the aqueous phase and the organic phase from step (II);
(IV) contacting at least a part the organic phase from step (III) with a second aqueous metal hydroxide solution, thereby forming an organic phase and a second aqueous phase, wherein the second aqueous metal hydroxide solution provides a concentration of 6 to 20 wt % MOH, where M is an alkali metal, in the second aqueous phase;
(V) separating the organic phase and the second aqueous phase from step (IV); and
(VI) washing at least a part of the organic phase from step (V) with water;
wherein each of steps (II), (IV), and (VI) are carried out in separate vessels.

2. The process as claimed in claim 1 , wherein MOH is NaOH.

3. The process as claimed in claim 1 , wherein a third aqueous phase is formed in step (VI) and at least a part of the third aqueous phase is used to dilute hydroxide to form the MOH solution added in step (IV).

4. The process as claimed in claim 1 , wherein at least a part of the second aqueous phase from step (IV) is diluted with water to form the hydroxide added in step (II).

5. The process as claimed in claim 1 , wherein at least a part of the aqueous phase from step (II) is used to neutralize the cleavage products of an acid catalyzed cumene hydroperoxide reaction.

6. The process as claimed in claim 1 , wherein the aqueous phase from step (II) contains a metal phenolate and at least a part of the aqueous phase from step (II) is de-phenolated thereby neutralizing the aqueous phase by converting the metal phenolate to a phenol, and then stripping the neutralized aqueous phase with steam in order to remove the phenol from the neutralized aqueous phase.

7. The process as claimed in claim 6 , wherein 5 to 30 wt % of the aqueous phase from step (II) is used to neutralize the cleavage products of an acid catalyzed cumene hydroperoxide reaction and 70 to 95% of the aqueous phase from step (II) passes to dephenolation.

8. The process as claimed in claim 1 , wherein the concentration of MOH in the aqueous phase in step (II) is about 1 wt %.

9. The process as claimed in claim 1 , wherein the concentration of MOH in the second aqueous phase in step (IV) is about 15 wt %.

10. The process as claimed in claim 1 , wherein a temperature in at least one of steps (II), (IV) or (VI) is from 30 to 50° C.

11. The process as claimed in claim 1 , wherein a pressure in at least one of steps (II), (IV) or (VI) is atmospheric.

12. The process as claimed in claim 1 , wherein a temperature in all of steps (II), (IV) and (VI) is from 30 to 50° C.

13. The process as claimed in claim 1 , wherein a pressure is atmospheric in all of steps (II), (IV) and (VI).

Assignees

• Borealis Ag

Inventors

• Saukonoja Jouni
• Lindholm Tero
• Pakala Tero
• Pakala Timo

Classifications

• C07C15/085

  Isopropylbenzene · CPC title

• C07C49/08

  Acetone · CPC title

• C07C15/44

  the hydrocarbon substituent containing a carbon-to-carbon double bond · CPC title

• C07C37/08 Primary

  by decomposition of hydroperoxides, e.g. cumene hydroperoxide · CPC title

• C07C39/04

  Phenol · CPC title