Lithium-ion secondary battery, fabricating method therof, and electronic device

Patent metadata

Field	Value
Publication number	US-10128529-B2
Application number	US-201615346932-A
Country	US
Kind code	B2
Filing date	Nov 9, 2016
Priority date	Nov 13, 2015
Publication date	Nov 13, 2018
Grant date	Nov 13, 2018

Abstract

A lithium-ion secondary battery with a high capacity retention rate is provided. In addition, a fabricating method of a lithium-ion secondary battery with a high capacity retention rate is provided. The lithium-ion secondary battery includes a positive electrode, a negative electrode, and an electrolyte solution. The negative electrode includes a negative electrode active material layer. The electrolyte solution includes at least one of lithium bis(trifluoromethanesulfonyl)amide (LiTFSA) and lithium bis(fluorosulfonyl)amide (LiFSA). The electrolyte solution includes vinylene carbonate (VC). A coating film including lithium oxide is on a surface of the negative electrode active material layer. A fabricating method of a lithium-ion secondary battery includes a first step of enclosing a positive electrode, a negative electrode, and an electrolyte solution in an exterior body, and a second step of annealing the exterior body enclosing the positive electrode, the negative electrode, and the electrolyte solution for 24 hours or longer after the first step. The annealing in the second step is performed at a temperature higher than or equal to 80° C. and lower than or equal to 100° C.

First claim

What is claimed is:

1. A lithium-ion secondary battery comprising:
a positive electrode;
a negative electrode; and
an electrolyte solution,
wherein the negative electrode comprises a negative electrode active material layer,
wherein the electrolyte solution comprises at least one of lithium bis(trifluoromethanesulfonyl)amide and lithium bis(fluorosulfonyl)amide and comprises vinylene carbonate,
wherein a coating film is on a surface of the negative electrode active material layer,
wherein the coating film comprises lithium oxide, lithium hydroxide, lithium carbonate, and lithium fluoride, and
wherein a proportion of lithium oxide in the coating film is greater than or equal to 4% and less than or equal to 20%.

2. The lithium-ion secondary battery according to claim 1 ,
wherein the negative electrode further comprises a negative electrode current collector,
wherein the negative electrode current collector comprises copper, and
wherein the negative electrode active material layer comprises graphite particles.

3. The lithium-ion secondary battery according to claim 1 ,
wherein the electrolyte solution further comprises ethylene carbonate and diethyl carbonate.

4. The lithium-ion secondary battery according to claim 1 ,
wherein a capacity retention rate of the lithium-ion secondary battery as a function of the square root of the number of cycles can be represented as a straight line having a slope less than or equal to −0.21, and
wherein the lithium-ion secondary battery has been submitted to an annealing performed at a temperature higher than or equal to 60° C.

5. An electronic device comprising:
the lithium-ion secondary battery according to claim 1 ;
a switch; and
a display portion.

6. A lithium-ion secondary battery comprising:
a positive electrode;
a negative electrode; and
an electrolyte solution,
wherein the positive electrode comprises a positive electrode current collector and a positive electrode active material layer,
wherein the positive electrode current collector comprises aluminum,
wherein the positive electrode active material layer comprises a graphene compound or lithium iron phosphate,
wherein the negative electrode comprises a negative electrode active material layer,
wherein the electrolyte solution comprises at least one of lithium bis(trifluoromethanesulfonyl)amide and lithium bis(fluorosulfonyl)amide and comprises vinylene carbonate,
wherein a coating film is on a surface of the negative electrode active material layer,
wherein the coating film comprises lithium oxide, lithium hydroxide, lithium carbonate, and lithium fluoride, and
wherein a proportion of lithium oxide in the coating film is greater than or equal to 4% and less than or equal to 20%.

7. The lithium-ion secondary battery according to claim 6 ,
wherein the negative electrode further comprises a negative electrode current collector,
wherein the negative electrode current collector comprises copper, and
wherein the negative electrode active material layer comprises graphite particles.

8. The lithium-ion secondary battery according to claim 6 ,
wherein the electrolyte solution further comprises ethylene carbonate and diethyl carbonate.

9. The lithium-ion secondary battery according to claim 6 ,
wherein a capacity retention rate of the lithium-ion secondary battery as a function of the square root of the number of cycles can be represented as a straight line having a slope less than or equal to −0.21, and
wherein the lithium-ion secondary battery has been submitted to an annealing performed at a temperature higher than or equal to 60° C.

10. An electronic device comprising:
the lithium-ion secondary battery according to claim 6 ;
a switch; and
a display portion.

11. A fabricating method of a lithium-ion secondary battery comprising:
a first step of enclosing a negative electrode comprising a negative electrode active material layer, a positive electrode, and an electrolyte solution in an exterior body; and
a second step of annealing the exterior body enclosing the positive electrode, the negative electrode, and the electrolyte solution for 24 hours or longer after the first step,
wherein the annealing in the second step is performed at a temperature higher than or equal to 80° C. and lower than or equal to 100° C.,
wherein the electrolyte solution comprises at least one of lithium bis(trifluoromethanesulfonyl)amide and lithium bis(fluorosulfonyl)amide and comprises vinylene carbonate,
wherein the positive electrode comprises a positive electrode current collector comprising aluminum,
wherein the positive electrode comprises a positive electrode active material layer comprising a graphene compound, and
wherein a coating film is on a surface of the negative electrode active material layer.

12. The fabricating method of a lithium-ion secondary battery, according to claim 11 ,
wherein the negative electrode comprises a negative electrode current collector comprising copper, and
wherein the negative electrode active material layer comprises graphite particles.

13. The fabricating method of a lithium-ion secondary battery, according to claim 11 ,
wherein the coating film changes in quality in the second step.

14. The fabricating method of a lithium-ion secondary battery, according to claim 11 , further comprising a third step of connecting the positive electrode and the negative electrode to a device and performing charging and discharging,
wherein the third step is performed between the first step and the second step, and
wherein the coating film is formed in the third step.

15. The fabricating method of a lithium-ion secondary battery, according to claim 11 , wherein the coating film comprises lithium oxide, lithium hydroxide, lithium carbonate, and lithium fluoride.

Assignees

• Semiconductor Energy Lab

Inventors

• Nakagawa Ai
• Oguni Teppei
• Kimura Kai
• Yatabe Rika

Classifications

• H02J7/52

  for charge balancing, e.g. equalisation of charge between batteries · CPC title

• H01M4/366

  as layered products · CPC title

• H01M4/62

  Selection of inactive substances as ingredients for active masses, e.g. binders, fillers · CPC title

• H01M10/425

  Structural combination with electronic components, e.g. electronic circuits integrated to the outside of the casing (printed circuits H05K1/00) · CPC title

• H01M4/136

  Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy · CPC title