Electrodes containing iridium nanoparticles for the electrolytic production of oxygen from water

Patent metadata

Field	Value
Publication number	US-10125429-B2
Application number	US-201615191003-A
Country	US
Kind code	B2
Filing date	Jun 23, 2016
Priority date	Oct 4, 2013
Publication date	Nov 13, 2018
Grant date	Nov 13, 2018

Abstract

Electrodes employing as active material iridium nanoparticles synthesized by a novel route are provided. The nanoparticle synthesis is facile and reproducible, and provides iridium nanoparticles of very small dimension and high purity for a wide range of metals. The electrodes utilizing these nanoparticles have excellent efficiency catalyzing the electrolytic production of oxygen from water.

First claim

What is claimed is:

1. A method for preparing an electrode comprising iridium nanoparticles, the method comprising:
synthesizing iridium nanoparticles by adding surfactant to a reagent complex having a formula,
Ir 0 ·X y ,

wherein Ir 0 is iridium, formally in oxidation state zero, X is a hydride molecule, and y is an integral or fractional value greater than zero, and wherein the iridium is in oxidation state zero prior to addition of surfactant to the reagent complex, such that surfactant quenches the hydride molecule; and
preparing an electrode using the iridium nanoparticles.

2. The method as recited in claim 1 , comprising:
ball milling a mixture that includes a powder of the hydride molecule and an iridium powder to produce the reagent complex.

3. The method as recited in claim 1 , wherein the hydride molecule is a borohydride.

4. The method as recited in claim 1 , wherein the hydride molecule is lithium borohydride.

5. The method as recited in claim 1 , wherein adding surfactant to the reagent complex produces iridium nanoparticles having an average maximum dimension less than about 100 nm.

6. The method as recited in claim 1 , wherein adding surfactant to the reagent complex produces iridium nanoparticles having an average maximum dimension less than about 10 nm.

7. The method as recited in claim 1 , wherein adding surfactant to the reagent complex produces iridium nanoparticles having an average maximum dimension less than about 5 nm.

8. The method as recited in claim 1 , wherein preparing the electrode using the iridium nanoparticles comprises:
mixing the iridium nanoparticles with a binder, a conductive powder, and a solvent to produce a catalyst ink; and
drop casting the catalyst ink on a current collector.

9. A method for preparing an electrode comprising iridium nanoparticles, the method comprising:
ball milling a substantially solvent-free mixture that includes a hydride molecule and a preparation composed of iridium to produce a reagent complex a reagent complex having a formula,
Ir 0 ·X y ,

wherein Ir 0 is iridium, formally in oxidation state zero, X is a hydride molecule, and y is an integral or fractional value greater than zero, and wherein the iridium is in oxidation state zero prior to addition of surfactant to the reagent complex, such that surfactant quenches the hydride molecule
synthesizing iridium nanoparticles by adding surfactant to the reagent complex; and
preparing an electrode using the iridium nanoparticles.

Assignees

• Toyota Eng & Mfg North America

Inventors

• Mcdonald Kenneth J
• Rowe Michael Paul

Classifications

• B22F1/054

  Nanosized particles · CPC title

• B22F9/24

  starting from liquid metal compounds, e.g. solutions · CPC title

• C25B1/04 Primary

  by electrolysis of water · CPC title

• B22F2009/043

  by ball milling · CPC title

• B22F2304/054

  Particle size between 1 and 100 nm · CPC title