Formulated isocyanate-reactive blends including olefin based blowing agent

Patent metadata

Field	Value
Publication number	US-10125235-B2
Application number	US-201515107501-A
Country	US
Kind code	B2
Filing date	Mar 20, 2015
Priority date	Mar 20, 2014
Publication date	Nov 13, 2018
Grant date	Nov 13, 2018

Abstract

A storage stable isocyanate-reactive composition has ethylene oxide content from 1 wt % to 50 wt %, based on the total weight of an isocyanate-reactive component that includes a polyol component, a catalyst component, and a blowing agent component. The polyol component includes at least one polyol, the catalyst component includes at least one amine catalyst, and the blowing agent component includes at least one hydrohaloolefin based blowing agent. The isocyanate-reactive component is storable at least at one of room temperature and a higher temperature for a period of at least 1 day with a less than 10 second change in gel time when reacted with an isocyanate component at an isocyanate index from 100 to 150, compared to when the same isocyanate-reactive component is stored for a period of less than 1 day at room temperature and reacted with the same isocyanate component at the same isocyanate index from 100 to 150.

First claim

The invention claimed is:

1. A storage stable isocyanate-reactive composition, comprising:
a total ethylene oxide content from 10 wt % to 20 wt %, based on the total weight of an isocyanate-reactive component that includes a polyol component, a catalyst component, and a blowing agent component, wherein:
the polyol component includes at least one polyol, the catalyst component includes at least one amine catalyst, the blowing agent component includes at least one hydrohaloolefin based blowing agent, and the at least one polyol includes from 1 wt % to 20 wt % of a low functionality alcohol initiated polyether polyol that is a diol or triol, from 10 wt % to 30 wt % of a high functionality alcohol initiated polyether polyol having a nominal hydroxyl functionality of 4 or greater, from 20 wt % to 60 wt % of an aromatic amine initiated polyether polyol, based on a total weight of the isocyanate-reactive component; and
the isocyanate-reactive component is storable at room temperature and a higher temperature of 50° C. for a period of at least 10 days with a less than 10 second change in gel time when reacted with an isocyanate component at an isocyanate index from 100 to 150, compared to when the same isocyanate-reactive component is stored for a period of less than 1 day at room temperature and reacted with the same isocyanate component at the same isocyanate index from 100 to 150.

2. The storage stable isocyanate-reactive composition as claimed in claim 1 , wherein the at least one hydrohaloolefin based blowing agent is a hydrochlorofluoroolefin based blowing agent and the at least one amine catalyst is a diamine or triamine.

3. The storage stable isocyanate-reactive composition as claimed in claim 1 , wherein the at least one hydrohaloolefin based blowing agent is a 1-chloro-3,3,3 trifluoropropene based blowing agent.

4. The storage stable isocyanate-reactive composition as claimed in claim 1 , wherein the isocyanate-reactive component is storable at 50° C. for a period of at least 10 days with a less than 6 second change in gel time when reacted with the isocyanate component at the isocyanate index from 100 to 150, compared to when the same isocyanate-reactive component is stored for the period of less than 1 day at room temperature and reacted with the same isocyanate component at the same isocyanate index from 100 to 150.

5. A polyurethane article, comprising the reaction product the storage stable isocyanate-reactive composition as claimed in claim 1 and the isocyanate component.

6. A rigid foam, comprising the reaction product the storage stable isocyanate-reactive composition as claimed in claim 1 and the isocyanate component.

7. An appliance comprising the rigid foam as claimed in claim 6 .

8. A method of producing a polyurethane article, comprising:
storing a storage stable isocyanate-reactive component at room temperature and a higher temperature of 50° C. for a period of at least 10 days;
providing an isocyanate component;
providing the storage stable isocyanate-reactive component, after the storing the storage stable isocyanate-reactive component, the storage stable isocyanate-reactive component having a total ethylene oxide content from 10 wt % to 20 wt %, based on the total weight of the isocyanate-reactive component that includes a polyol component, a catalyst component, and a blowing agent component, the polyol component including at least one polyol, the catalyst component including at least one amine catalyst, the blowing agent component including at least one hydrohaloolefin based blowing agent, and the at least one polyol includes from 1 wt % to 20 wt % of a low functionality alcohol initiated polyether polyol that is a diol or triol, from 10 wt % to 30 wt % of a high functionality alcohol initiated polyether polyol having a nominal hydroxyl functionality of 4 or greater, from 20 wt % to 60 wt % of an aromatic amine initiated polyether polyol, based on a total weight of the isocyanate-reactive component; and
reacting the isocyanate component with the storage stable isocyanate-reactive component at an isocyanate index from 100 to 150, whereas a less than 10 second change in gel time is realized when reacting the isocyanate component with the storage stable isocyanate-reactive component after the storing the storage stable isocyanate-reactive component, compared to when the same isocyanate-reactive component is stored for a period of less than 1 day at room temperature and reacted with the same isocyanate component at the same isocyanate index from 100 to 150.

9. The storage stable isocyanate-reactive composition as claimed in claim 1 , wherein:
the low functionality alcohol initiated polyether polyol has a number average molecular weight of less than 1500 g/mol, and
the high functionality alcohol initiated polyether polyol has a number average molecular weight of less than 1500 g/mol.

10. The storage stable isocyanate-reactive composition as claimed in claim 1 , wherein the polyol component further includes from 5 wt % to 30 wt % of a polyester polyol, based on the total weight of the isocyanate-reactive component.

11. The storage stable isocyanate-reactive composition as claimed in claim 10 , wherein the at least one hydrohaloolefin based blowing agent includes 1,3,3,3-tetrafluoropropene (HFO-1234ze); 1,1,3,3-tetrafluoropropene; 1,2,3,3,3-pentafluoropropene (HFO-1225ye), 1,1,1-trifluoropropene; 1,1,1,3,3-pentafluoropropene (HFO-1225zc); 1,1,1,3,3,3-hexafluorobut-2-ene; 1,1,2,3,3-pentafluoropropene (HFO-1225yc); 1,1,1,2,3-pentafluoropropene (HFO-1225yez); 1-chloro-3,3,3-trifluoropropene (HFCO-1233zd); or 1,1,1,4,4,4-hexafluorobut-2-ene.

12. The method of producing the polyurethane article as claimed in claim 8 , wherein:
the low functionality alcohol initiated polyether polyol has a number average molecular weight of less than 1500 g/mol, and
the high functionality alcohol initiated polyether polyol has a number average molecular weight of less than 1500 g/mol.

13. The method of producing the polyurethane article as claimed in claim 8 , wherein the polyol component further includes from 5 wt % to 30 wt % of a polyester polyol, based on the total weight of the isocyanate-reactive component.

14. The method of producing the polyurethane article as claimed in claim 8 , wherein the at least one hydrohaloolefin based blowing agent includes 1,3,3,3-tetrafluoropropene (HFO-1234ze); 1,1,3,3-tetrafluoropropene; 1,2,3,3,3 -pentafluoropropene (HFO-1225ye), 1,1,1-trifluoropropene; 1,1,1,3,3-pentafluoropropene (HFO-1225zc); 1,1,1,3,3,3-hexafluorobut-2-ene; 1,1,2,3,3-pentafluoropropene (HFO-1225yc); 1,1,1,2,3-pentafluoropropene (HFO-1225yez); 1-chloro-3,3,3-trifluoropropene (HFCO-1233zd); or 1,1,1,4,4,4-hexafluorobut-2-ene.

Assignees

• Dow Global Technologies Llc

Inventors

• Riccio Rossella
• Parenti Vanni
• Kramer Hans
• Rose Melissa M

Classifications

• C08G18/2036

  having at least three nitrogen atoms in the ring · CPC title

• C08G2101/0025

  Chemistry & Metallurgy · mapped topic

• C08G18/225

  of alkali or alkaline earth metals · CPC title

• C08J2201/022

  premixing or pre-blending a part of the components of a foamable composition, e.g. premixing the polyol with the blowing agent, surfactant and catalyst and only adding the isocyanate at the time of foaming · CPC title

• C08G18/14

  Manufacture of cellular products · CPC title