Column with separative installations for separating a mixture of hydrocarbons and/or hydrocarbon derivatives by means of an extractive distillation using a selective solvent

Patent metadata

Field	Value
Publication number	US-10125063-B2
Application number	US-201515323802-A
Country	US
Kind code	B2
Filing date	Jul 7, 2015
Priority date	Jul 8, 2014
Publication date	Nov 13, 2018
Grant date	Nov 13, 2018

Abstract

What is proposed is a column (K) comprising separatory internals (E) for separating a mixture of hydrocarbons and/or hydrocarbon derivatives ( 1 ) by extractive distillation with a selective solvent ( 2 ),
with supply of the selective solvent ( 2 ) in the upper region of the column and supply of the mixture of hydrocarbons and/or hydrocarbon derivatives to be separated ( 1 ) below the supply of the selective solvent ( 2 ), the selective solvent ( 2 ) becoming laden in the column (K) with the components from the mixture to be separated ( 1 ) for which it has greater affinity and being withdrawn from the lower region of the column as laden selective solvent ( 3 ),

while, by contrast, the components from the mixture to be separated for which the selective solvent ( 2 ) has a lower affinity remain in the vapor phase and are withdrawn as top stream ( 4 ),

which is completely or partially condensed to obtain a condensate ( 5 ),

some of which is withdrawn as product stream ( 6 ), the remainder being reintroduced to the column (K) as reflux ( 7 ),

wherein
said column comprises in the region of the column above the separatory internals (E) a first, substantially horizontal feed pipe (R 1 ) for supplying the selective solvent, wherein the first, substantially horizontal feed pipe (R 1 ) exhibits a cross-sectional narrowing to a narrowest point (V), said pipe widening again downstream of the cross-sectional narrowing, and wherein said column comprises a second feed pipe (R 2 ) for supplying the reflux ( 7 ), said pipe joining the first, substantially horizontal feed pipe (R 1 ) in the region of the narrowest point (V) of the cross-sectional narrowing.

First claim

The invention claimed is:

1. A column (K), comprising separatory internals (E) for separating a mixture of hydrocarbons and/or hydrocarbon derivatives ( 1 ) by extractive distillation with a selective solvent ( 2 ),
with supply of the selective solvent ( 2 ) in the upper region of the column and supply of the mixture of hydrocarbons and/or hydrocarbon derivatives to be separated ( 1 ) below the supply of the selective solvent ( 2 ), the selective solvent ( 2 ) becoming laden in the column (K) with the components from the mixture to be separated ( 1 ) for which it has greater affinity and being withdrawn from the lower region of the column as laden selective solvent ( 3 ),
while, by contrast, the components from the mixture to be separated for which the selective solvent ( 2 ) has a lower affinity remain in the vapor phase and are withdrawn as top stream ( 4 ),
which is completely or partially condensed to obtain a condensate ( 5 ),
some of which is withdrawn as product stream ( 6 ), the remainder being reintroduced to the column (K) as reflux ( 7 ),
wherein
said column comprises in the region of the column above the separatory internals (E) a first, substantially horizontal feed pipe (R 1 ) for supplying the selective solvent,
wherein the first, substantially horizontal feed pipe (R 1 ) exhibits a cross-sectional narrowing to a narrowest point (V), said pipe widening again downstream of the cross-sectional narrowing, and wherein
said column comprises a second feed pipe (R 2 ) for supplying the reflux ( 7 ), said pipe joining the first, substantially horizontal feed pipe (R 1 ) in the region of the narrowest point (V) of the cross-sectional narrowing.

2. The column (K) according to claim 1 , wherein there is a liquid distributor (F) disposed above the separatory internals (E) in the column (K).

3. The column (K) according to claim 1 , wherein said column has a diameter of >0.5 m.

4. The column (K) according to claim 1 , wherein the ratio of the cross section of the first, substantially horizontal feed pipe (R 1 ) upstream of the cross-sectional narrowing to the cross section of the first, horizontal feed pipe (R 1 ) at the narrowest point (V) of the cross-sectional narrowing is chosen such that the pressure inside the first, substantially horizontal feed pipe (R 1 ) at the narrowest point (V) of the cross-sectional narrowing is lower than the pressure outside the first, substantially horizontal feed pipe (R 1 ) immediately proximal to the narrowest point (V) of the cross-sectional narrowing.

5. The column (K) according to claim 1 , wherein the diameter of the first, substantially horizontal feed pipe (R 1 ) upstream of the cross-sectional narrowing is chosen such that the flow velocity in the first, substantially horizontal feed pipe (R 1 ) upstream of the cross-sectional narrowing is in the range of from 0.1 to 5.0 m/s.

6. The column (K) according to claim 1 , wherein the second feed pipe (R 2 ) that joins the first, substantially horizontal feed pipe (R 1 ) in the region of the narrowest point (V) of the cross-sectional narrowing preferably protrudes into said pipe by a protrusion depth of from 0.1 to 0.8 times the diameter of the second feed pipe (R 2 ).

7. The column (K) according to claim 6 , wherein the second feed pipe protruding into the first, substantially horizontal pipe terminates slantedly at an angle to the longitudinal axis of said second feed pipe in the range of from 4° to 65°.

8. The column (K) according to claim 1 , wherein the first, substantially horizontal feed pipe has disposed in it, downstream of the narrowest point of the cross-sectional narrowing and substantially transversely to the longitudinal axis of said pipe, a static mixing element (M) that partially blocks the cross section of said pipe.

9. The column (K) according to claim 8 , wherein the static mixing element (M) is spaced apart from the point of the narrowest cross section (V) in the first, substantially horizontal feed pipe (R 1 ) by at least double the diameter of the first, substantially horizontal feed pipe (R 1 ) at the point of the narrowest cross section (V).

10. The column (K) according to claim 8 , wherein the static mixing element (M) is eccentrically disposed in the cross section of the first, substantially horizontal feed pipe (R 1 ) and is in contact with the interior wall of said pipe or is close to the wall thereof but in the upper region of the first, substantially horizontal feed pipe (R 1 ) is spaced apart from the interior wall of said pipe.

11. The column (K) according to claim 10 , wherein the static mixing element (M) eccentrically disposed in the first, substantially horizontal feed pipe (R 1 ) is in the shape of an annulus.

12. The column (K) according to claim 11 , wherein the static mixing element (M) eccentrically disposed in the first, substantially horizontal feed pipe (R 1 ) is in the shape of an annulus which is open at the top, said annulus preferably being secured to the interior wall by means of supports in the upper region of said interior wall.

13. A process for separating a mixture of hydrocarbons and/or hydrocarbon derivatives ( 1 ) by extractive distillation with a selective solvent ( 2 ) in a column (K) according to claim 1 ,
with supply of the selective solvent ( 2 ) in the upper region of the column and supply of the mixture of hydrocarbons and/or hydrocarbon derivatives to be separated ( 1 ) below the supply of the selective solvent ( 2 ), the selective solvent ( 2 ) becoming laden in the column (K) with the components from the mixture to be separated for which it has greater affinity and being withdrawn from the lower region of the column as laden selective solvent ( 3 ),
while, by contrast, the components from the mixture of hydrocarbons and/or hydrocarbon derivatives ( 1 ) to be separated for which the selective solvent ( 2 ) has a lower affinity remain in the vapor phase and are withdrawn as top stream ( 4 ),
which is completely or partially condensed to obtain a condensate ( 5 ),
some of which is withdrawn as product stream ( 6 ), the remainder being reintroduced to the column as reflux ( 7 ),
wherein
the selective solvent ( 2 ) is supplied into the upper region of the column above the separatory internals (E) via a first, substantially horizontal feed pipe (R 1 ), wherein the first, substantially horizontal feed pipe (R 1 ) exhibits a cross-sectional narrowing to a narrowest point (V), said pipe widening again downstream of the cross-sectional narrowing, and wherein
the reflux ( 7 ) is supplied via a second feed pipe (R 2 ) which joins the first, substantially horizontal feed pipe (R 1 ) at the narrowest point (V) of the cross-sectional narrowing.

14. The process according to claim 13 , wherein said process is an extractive distillation of C 4 cuts to obtain butanes and/or butenes and/or 1,3-butadiene with a selective solvent selected from N-methylpyrrolidone or mixtures thereof with water, dimethylformamide and acetonitrile or an extractive distillation of aromatics-containing mixtures to obtain benzene and/or toluene and/or xylene.

Assignees

• Basf Se

Inventors

• Heida Bernd
• Hofinger Julia
• Renze Peter

Classifications

• C07C9/10

  with four carbon atoms · CPC title

• C07C7/08 Primary

  by extractive distillation · CPC title

• C07C11/08

  with four carbon atoms · CPC title

• B01F2005/0636

  Operations & Transport · mapped topic

• B01D3/32 Primary

  Other features of fractionating columns {; Constructional details of fractionating columns not provided for in groups B01D3/16 - B01D3/30} · CPC title