Poly(vinyl acetal) resin compositions, layers, and interlayers having enhanced optical properties

Patent metadata

Field	Value
Publication number	US-10124563-B2
Application number	US-201715427844-A
Country	US
Kind code	B2
Filing date	Feb 8, 2017
Priority date	Dec 8, 2014
Publication date	Nov 13, 2018
Grant date	Nov 13, 2018

Abstract

Resin compositions, layers, and interlayers comprising two or more thermoplastic polymers and at least one RI balancing agent for adjusting the refractive index of at least one of the resins or layers is provided. Such compositions, layers, and interlayers exhibit enhanced optical properties while retaining other properties, such as impact resistance and acoustic performance.

First claim

What is claimed is:

1. An interlayer comprising:
a first resin layer comprising a first poly(vinyl acetal) resin and a first plasticizer; and
a second resin layer adjacent to said first resin layer, wherein said second resin layer comprises a second poly(vinyl acetal) resin and a second plasticizer, wherein said second poly(vinyl acetal) resin comprises residues of an aldehyde having a refractive index of at least 1.421, and wherein said second resin layer has a refractive index of greater than 1.470 and a glass transition temperature of not more than 10° C., and
wherein said second poly(vinyl acetal) resin further comprises at least 10 weight percent of residues of at least one other aldehyde selected from the group consisting of n-butyraldehyde, iso-butyraldehyde, 2-ethylhexanal, based on the total weight of aldehyde residues of said second poly(vinyl acetal) resin, and wherein said second poly(vinyl acetal) resin comprises at least 5 weight percent of the residues of said aldehyde having a refractive index of at least 1.421, based on the total weight of aldehyde residues of said second poly(vinyl acetal) resin,
wherein the refractive index of said first resin layer is not more than 0.010 higher than the refractive index of said second resin layer and wherein said interlayer has a damping loss factor (as measured by ISO 16940) of at least 0.10 at 20° C.

2. The interlayer of claim 1 , wherein the difference between the residual hydroxyl content of said first poly(vinyl acetal) resin and the residual hydroxyl content of said second poly(vinyl acetal) resin is at least 2 weight percent, and wherein the haze of said interlayer is less than 5 percent.

3. The interlayer of claim 1 , wherein said second layer further comprises another poly(vinyl acetal) resin comprising at least 50 weight percent of residues of an aldehyde having a refractive index less than 1.421, based on the total weight of the aldehyde residues of said second poly(vinyl acetal) resin, wherein each of said second poly(vinyl acetal) resin and said another poly(vinyl acetal) resin is present in said second resin layer in an amount of at least about 5 weight percent, based on the total weight of all resins in said second resin layer.

4. The interlayer of claim 1 , wherein at least one of said first and said second poly(vinyl acetal) resins has a residual acetate content of at least 5 weight percent.

5. The interlayer of claim 1 , wherein the difference between the glass transition temperature of said first resin layer and the glass transition temperature of said second resin layer is at least 3° C., wherein the first poly(vinyl acetal) resin has a residual hydroxyl content that is at least 2 weight percent higher or lower than the residual hydroxyl content of said second poly(vinyl acetal) resin, wherein said interlayer has a haze value of less than 5 percent.

6. The interlayer of claim 1 , further comprising a third resin layer comprising a third poly(vinyl acetal) resin and a third plasticizer,
wherein the second resin layer is adjacent to and in contact with the first resin layer and the third resin layer.

7. The interlayer of claim 6 , wherein the first and third poly(vinyl acetal) resins are the same.

8. The interlayer of claim 6 , wherein the first and third plasticizers are the same.

9. A multiple layer panel comprising said interlayer of claim 1 and at least one rigid substrate.

10. An interlayer comprising:
a first resin layer comprising a first poly(vinyl acetal) resin and a first plasticizer;
a second resin layer adjacent to said first resin layer, wherein said second resin layer comprises a second poly(vinyl acetal) resin and a second plasticizer, wherein said second poly(vinyl acetal) resin comprises residues of an aldehyde having a refractive index of at least 1.421 based on the total weight of the aldehyde residues of said second poly(vinyl acetal) resin, and wherein said second resin layer has a refractive index of greater than 1.470 and a glass transition temperature of not more than 10° C.,
wherein said second layer further comprises another poly(vinyl acetal) resin comprising at least 50 weight percent of residues of an aldehyde having a refractive index less than 1.421, based on the total weight of the aldehyde residues of said second poly(vinyl acetal) resin, wherein each of said second poly(vinyl acetal) resin and said another poly(vinyl acetal) resin is present in said second resin layer in an amount of at least about 5 weight percent, based on the total weight of all resins in said second resin layer, and
a third resin layer comprising a third poly(vinyl acetal) resin and a third plasticizer, wherein the second resin layer is adjacent to and in contact with the first resin layer and the third resin layer,
wherein the refractive index of said first resin layer is not more than 0.010 higher than the refractive index of said second resin layer and wherein said interlayer has a damping loss factor (as measured by ISO 16940) of at least 0.10 at 20° C.

11. The interlayer of claim 10 , wherein the first and third poly(vinyl acetal) resins are the same.

12. The interlayer of claim 10 , wherein the first and third plasticizers are the same.

13. The interlayer of claim 10 , wherein the difference between the residual hydroxyl content of at least one of said first resin layer and said third resin layer and the residual hydroxyl content of said second poly(vinyl acetal) resin is at least 2 weight percent, and wherein the haze of said interlayer is less than 5 percent.

14. The interlayer of claim 10 , wherein the difference between the glass transition temperature of at least one of said first resin layer and said third resin layer and the glass transition temperature of said second resin layer is at least 3° C., wherein at least one of the first poly(vinyl acetal) resin and the third poly(vinyl acetal) resin has a residual hydroxyl content that is at least 2 weight percent higher or lower than the residual hydroxyl content of said second poly(vinyl acetal) resin, wherein said interlayer has a haze value of less than 5 percent.

15. A multiple layer panel comprising said interlayer of claim 10 and at least one rigid substrate.

16. An interlayer comprising:
a first resin layer comprising a first poly(vinyl acetal) resin and a first plasticizer;
a second resin layer adjacent to said first resin layer, wherein said second resin layer comprises a second poly(vinyl acetal) resin and at least 45 parts per hundred parts of resin (phr) of a second plasticizer, wherein said second poly(vinyl acetal) resin comprises residues of an aldehyde having a refractive index of at least 1.421 based on the total weight of the aldehyde residues of said second poly(vinyl acetal) resin, and wherein said second resin layer has a refractive index of greater than 1.470 and a glass transition temperature of not more than 10° C.,
wherein said second poly(vinyl acetal) resin further comprises at least 10 weight percent of residues of at least one other aldehyde selected from the group consisting of n-butyraldehyde, iso-butyraldehyde, 2-ethylhexanal, based on the total weight of aldehyde residues of said second poly(vinyl acetal) resin, and wherein said second poly(vinyl acetal) resin comprises at least 5 weight percent of the residues of said aldehyde having a refractive index of at least 1.421, based on the total weight of aldehyde residues of said second poly(vinyl acetal) resin, and
a third resin layer comprising a third poly(vinyl acetal) resin and a third plasticizer, wherein the second resin layer is adjacent to and in contact with the first resin

Assignees

• Solutia Inc

Inventors

• Lu Jun
• Li Zhou

Classifications

• C08J5/18

  Manufacture of films or sheets · CPC title

• B32B2419/00

  Buildings or parts thereof · CPC title

• B32B2307/418

  Refractive · CPC title

• B32B17/10605

  Type of plasticiser · CPC title

• B32B2307/558

  Impact strength, toughness · CPC title