Methods for arranging nanoscopic elements within networks, fabrics and films

Patent metadata

Field	Value
Publication number	US-10124367-B2
Application number	US-201615241495-A
Country	US
Kind code	B2
Filing date	Aug 19, 2016
Priority date	Jan 13, 2003
Publication date	Nov 13, 2018
Grant date	Nov 13, 2018

Abstract

A method for arranging nanotube elements within nanotube fabric layers and films is disclosed. A directional force is applied over a nanotube fabric layer to render the fabric layer into an ordered network of nanotube elements. That is, a network of nanotube elements drawn together along their sidewalls and substantially oriented in a uniform direction. In some embodiments this directional force is applied by rolling a cylindrical element over the fabric layer. In other embodiments this directional force is applied by passing a rubbing material over the surface of a nanotube fabric layer. In other embodiments this directional force is applied by running a polishing material over the nanotube fabric layer for a predetermined time. Exemplary rolling, rubbing, and polishing apparatuses are also disclosed.

First claim

What is claimed is:

1. A method for arranging nanotube elements within a nanotube fabric, comprising:
providing a plurality of nanotube elements over a material layer to obtain a substantially dry, fully formed, fixed nanotube fabric comprising a plurality of nanotube elements in a first operation, wherein said nanotube fabric is substantially free of any suspension medium; and
translating a rotational force over at least a portion of said substantially dry, fully formed, fixed nanotube fabric in a second operation to arrange at least a portion of said nanotube elements into an ordered network;
wherein said second operation is performed subsequent to said first operation; and
wherein said rotational force arranges said nanotube elements within said portion of said nanotube fabric into a plurality of ordered regions, wherein each ordered region is comprised of nanotube elements in a substantially uniform orientation.

2. The method of claim 1 wherein said rotational force is applied over said portion of said portion of said nanotube fabric at least once.

3. The method of claim 1 further comprising repeatedly applying said rotational force to said portion of said nanotube fabric.

4. The method of claim 1 wherein said material layer is rigid.

5. The method of claim 4 wherein said material layer is selected from a group consisting of elemental silicon, silicon oxide, silicon nitride, silicon carbides, PTFE, organic polymers, pvc, styrenes, polyvinyl alcohol, polyvinyl acetate, hydrocarbon polymers, inorganic backbone, boron nitride, gallium arsenide, group III/V compounds, group II/VI compounds, wood, metals, metal alloys, metal oxides, ceramics, and glass.

6. The method of claim 1 wherein said material layer is a rigid structural composite.

7. The method of claim 1 wherein said material layer is flexible.

8. The method of claim 7 wherein said material is selected from a group consisting of polyethylene terephthalate (PET), polymethylmethacrylate, polyamides, polysulfones, and polycyclic olefins.

9. The method of claim 1 wherein applying said rotational force arranges at least a portion of said nanotube fabric into a preselected orientation within at least one preselected region of said nanotube fabric.

10. The method of claim 1 further comprising depositing a lubricating medium over a portion of said nanotube fabric prior to said application of said rotational force.

11. The method of claim 10 wherein said lubricating medium is comprised of at least one material selected from the list consisting of water, halocarbon liquids, liquefied gases, hydrocarbon liquids, functionalized organic liquids, organo-siloxane based cyclics, linear liquids, molybdenum disulfide, boron nitride, graphite, and styrene beads.

12. The method of claim 1 wherein said nanotube fabric is formed via one of a spin coating operation, a spray coating operation, a dip coating operation, a silk screen printing operation, or a gravure printing operation.

13. The method of claim 1 wherein said nanotubes are carbon nanotubes.

14. The method of claim 1 wherein said nanotube fabric is a composite mixture of carbon nanotubes and other materials.

15. The method of claim 14 wherein said other materials are selected from the group consisting of buckyballs, amorphous carbon, silver nanotubes, quantum dots, colloidal silver, monodisperse polystyrene beads, and silica particles.

16. The method of claim 1 wherein said nanotube elements are functionalized carbon nanotubes.

17. The method of claim 16 wherein said functionalized carbon nanotubes are carbon nanotubes affixed with moieties which provide an electrically insulating barrier over the sidewalls of said carbon nanotubes.

18. The method of claim 17 wherein said moieties are organic functional groups.

19. The method of claim 17 wherein said moieties are silicon functional groups.

20. The method of claim 17 wherein said moieties include at least one of organosilicate, silicon oxide, organo silicon oxide, methylsilsequioxane, hydrogen silsequioxane, organosiloxane, dimethylsiloxane/polyorgano ether, organopolymer, DNA, and polyamide.

21. The method of claim 1 wherein said rotational force is applied through a polishing element.

22. The method of claim 21 wherein said polishing element in rotated within a plane parallel to said nanotube fabric layer.

23. The method of claim 21 wherein said polishing element comprises at least one of polyester microfiber, polyamide microfiber, polyester, polyamide, styrene, polyvinylalcohol foam, cotton, wool, cellulose, and rayon.

24. The method of claim 1 wherein said rotational force is applied to said nanotube fabric through an intervening material.

25. The method of claim 1 wherein said ordered regions are substantially free of gaps and voids.

26. The method of claim 1 wherein the orientation of nanotube elements within said ordered regions is responsive to the direction of said applied rotational force.

27. A method for arranging nanotube elements within a nanotube fabric, comprising:
providing a plurality of nanotube elements over a material layer to obtain a substantially dry, fully formed, fixed nanotube fabric comprising a plurality of nanotube elements in a first operation, wherein said nanotube fabric is substantially free of any suspension medium; and
translating a rotational force over at least a portion of said substantially dry, fully formed, fixed nanotube fabric in a second operation to arrange at least a portion of said nanotube elements into an ordered network;
wherein said second operation is performed subsequent to said first operation; and
wherein said rotational force arranges said nanotube elements such that said portion of said nanotube fabric is substantially free of gaps and voids.

Assignees

• Nantero Inc
• Nantero Inc

Inventors

• Roberts David A
• Lin Hao-Yu
• Bengtson Thomas R
• Rueckes Thomas
• Robinson Karl
• Manning H Montgomery
• Sen Rahul
• Monteiro Michel Pires

Classifications

• B05D1/28

  performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers · CPC title

• B05D1/18

  performed by dipping · CPC title

• B82Y40/00

  Manufacture or treatment of nanostructures · CPC title

• C01B32/168

  After-treatment · CPC title

• B05D1/40 Primary

  Distributing applied liquids or other fluent materials by members moving relatively to surface · CPC title