Frequency dependent light emitting devices

Patent metadata

Field	Value
Publication number	US-10121993-B2
Application number	US-201815904569-A
Country	US
Kind code	B2
Filing date	Feb 26, 2018
Priority date	Sep 27, 2013
Publication date	Nov 6, 2018
Grant date	Nov 6, 2018

Abstract

An electroluminescent device described herein, in one aspect, comprises a first electrode and second electrode and a light emitting layer positioned between the first and second electrodes. A current injection gate is positioned between the first electrode and the light emitting layer or the second electrode and the light emitting layer. In some embodiments, the current injection gate comprises a semiconductor layer of electronic structure restricting injected current flow from the first or second electrode through the semiconductor layer as a function of alternating current voltage frequency applied to the first and second electrodes.

First claim

The invention claimed is:

1. A method of preparing an electroluminescent device comprising:
depositing a first electrode layer on a substrate;
depositing a current injection gate layer on the first electrode layer, the current injection gate layer comprising a semiconductor layer of electronic structure restricting injected current flow as a function of alternating current voltage frequency;
depositing an organic light emitting layer on the current injection gate layer, the organic light emitting layer comprising a triplet emitter phase; and
depositing a second electrode layer on the organic light emitting layer.

2. The method of claim 1 , wherein the first electrode, second electrode, or both the first electrode and the second electrode are radiation transmissive.

3. The method of claim 1 , wherein the organic light emitting layer further comprises a singlet emitter phase.

4. The method of claim 3 , wherein the singlet emitter phase comprises one or more conjugated polymers or oligomers, small molecules, or mixtures thereof.

5. The method of claim 3 , wherein the triplet emitter phase is dispersed in the singlet emitter phase.

6. The method of claim 5 , wherein the organic light emitting layer comprises a dielectric host for the singlet emitter phase and the triplet emitter phase.

7. The method of claim 1 , wherein the triplet emitter phase comprises a phosphorescent transition metal complex.

8. The method of claim 1 , wherein the organic light emitting layer further comprises a nanoparticle phase.

9. The method of claim 8 , wherein the nanoparticle phase comprises carbon nanoparticles, inorganic nanoparticles, or mixtures thereof.

10. The method of claim 9 , wherein the nanoparticle phase is dispersed uniformly throughout the organic light emitting layer, or heterogeneously distributed in the organic light emitting layer.

11. The method of claim 1 , wherein injected current flow through the semiconductor layer of the gate decreases with increasing frequency of the applied alternating current voltage.

12. The method of claim 1 , wherein the semiconductor layer is a composite layer comprising inorganic particles dispersed in a conjugated polymeric matrix.

13. The method of claim 1 , wherein the semiconductor layer is formed of an intrinsic semiconductor.

14. The method of claim 13 , wherein the intrinsic semiconductor is an inorganic semiconductor.

15. The method of claim 13 , wherein the intrinsic semiconductor is an organic semiconductor.

16. The method of claim 1 , wherein the semiconductor layer is formed of a material having a bandgap of at least 2 eV.

17. The method of claim 1 , further comprising:
depositing an electron dopant layer on a first side of the light emitting organic layer.

18. The method of claim 17 , further comprising:
depositing a hole dopant layer on an opposite second side of the light emitting organic layer.

19. The method of claim 1 , wherein the light emitting organic layer comprises an electron dopant and a hole dopant.

20. The method of claim 1 having an efficiency of at least 100 lm W −1 .

Assignees

• Univ Wake Forest

Inventors

• Carroll David
• Summers Robert
• Chen Yonghua

Classifications

• H01L51/50

  Electricity · mapped topic

• H01L51/5296 Primary

  Electricity · mapped topic

• H01L2251/5376

  Electricity · mapped topic

• H01L51/0077

  Electricity · mapped topic

• H01L51/0043

  Electricity · mapped topic