Method and device for monitoring the quality of nanofibrillar cellulose

Patent metadata

Field	Value
Publication number	US-10119919-B2
Application number	US-201515321204-A
Country	US
Kind code	B2
Filing date	Apr 27, 2015
Priority date	Jun 30, 2014
Publication date	Nov 6, 2018
Grant date	Nov 6, 2018

Abstract

One embodiment provides a method for monitoring the quality of nanofibrillar cellulose produced in a process comprising disintegrating fibers of cellulose pulp, the method comprising measuring in real-time optically the turbidity of a dispersion containing nanofibrillar cellulose obtained from a disintegrating process, and determining the quality of said produced nanofibrillar cellulose using a correlation between the measured turbidity and said quality of the produced nanofibrillar cellulose, wherein lowered turbidity indicates increased quality of the nanofibrillar cellulose. One embodiment provides a device for monitoring the quality of nanofibrillar cellulose produced in a process comprising disintegrating fibers of cellulose pulp, arranged to carry out said method.

First claim

The invention claimed is:

1. A method for monitoring the quality of nanofibrillar cellulose produced in a process comprising disintegrating fibers of cellulose pulp, characterized in that the method comprises
measuring in real-time optically the turbidity of a dispersion containing nanofibrillar cellulose obtained from said disintegrating process, and
correlating the measured turbidity to the quality of the produced nanofibrillar cellulose to determine the quality of said produced nanofibrillar cellulose, wherein lowered turbidity indicates increased quality of the nanofibrillar cellulose.

2. The method of claim 1 , wherein the turbidity measurement is carried out at a consistency of said dispersion in the range of 0.15-10%.

3. The method of claim 1 , wherein the turbidity measurement is carried out at a consistency of said dispersion in the range of 0.5-8%.

4. The method of claim 1 , wherein the turbidity measurement is carried out at a consistency of said dispersion in the range of 1-5%.

5. The method of claim 1 , wherein the turbidity measurement is carried out at a consistency of said dispersion in the range of 1.5-4%.

6. The method of claim 1 , wherein the quality of the nanofibrillar cellulose comprises a fibrillation degree of said nanofibrillar cellulose.

7. The method of claim 1 , wherein the quality of the nanofibrillar cellulose comprises a viscosity degree of said nanofibrillar cellulose.

8. The method of claim 1 , wherein the turbidity measurement is a light scattering measurement.

9. The method of claim 8 , wherein a change in the polarization of the scattered light is measured.

10. The method of claim 8 , wherein the polarization of the scattered light is measured.

11. The method of claim 1 , wherein the turbidity measurement is an absorption measurement.

12. The method of claim 1 , wherein the optical measurement is carried out at a wavelength in the range of 260-900 nm.

13. The method of claim 1 , wherein the optical measurement is carried out at a wavelength in the range of 400-890 nm.

14. The method of claim 1 , wherein the flow rate of the dispersion containing nanofibrillar cellulose is in the range of 0.01 m/s-5 m/s.

15. The method of claim 1 , wherein the flow rate of the dispersion containing nanofibrillar cellulose is in the range of 0.1-3 m/s.

16. The method of claim 1 , wherein the pulp is non-modified pulp.

17. The method of claim 1 , wherein the pulp is modified pulp.

18. The method of claim 17 wherein the modified pulp is chemically modified pulp.

19. The method of claim 17 wherein the modified pulp is oxidized pulp.

20. The method of claim 19 wherein the oxidized pulp is TEMPO oxidized pulp.

21. The method of claim 17 wherein the modified pulp is anionic pulp.

22. The method of claim 17 wherein the modified pulp is cationic pulp.

23. The method of claim 17 wherein the modified pulp is enzymatically modified pulp.

24. The method of claim 1 , wherein the disintegrating process is a continuous process.

25. The method of claim 1 , wherein the real-time measurement is carried out as an in-line measurement from the process flow.

26. The method of claim 1 , wherein the real-time measurement is carried out as an on-line measurement from a side flow.

27. A device for monitoring the quality of nanofibrillar cellulose produced in a disintegrating process comprising disintegrating fibers of cellulose pulp, characterized in that the disintegrating process comprises:
measuring in real-time optically the turbidity of a dispersion containing nanofibrillar cellulose obtained from said disintegrating process, and
correlating the measured turbidity to the quality of the produced nanofibrillar cellulose to determine the quality of said produced nanofibrillar cellulose, wherein lowered turbidity indicates increased quality of the nanofibrillar cellulose,
the device being arranged to monitor a dispersion containing said produced nanofibrillar cellulose obtained from a disintegrating device, characterized in that the monitoring device comprises
means for measuring optically the turbidity of said dispersion in real-time, and
means for determining the quality of said produced nanofibrillar cellulose using a correlation between the measured turbidity and said quality of the produced nanofibrillar cellulose, wherein lowered turbidity indicates increased quality of the nanofibrillar cellulose.

28. The device of claim 27 , wherein the means for measuring optically the turbidity of said dispersion in real-time comprise a turbidimeter.

29. The device of claim 28 , wherein the means for measuring optically the turbidity of said dispersion in real-time comprise an absorption turbidimeter.

30. The device of claim 28 , wherein the means for measuring optically the turbidity of said dispersion in real-time comprise a transmission turbidimeter.

31. The device of claim 27 , wherein the means for measuring optically the turbidity of said dispersion in real-time comprise a nephelometer.

32. A device setup comprising the device of claim 27 connected to at least one pulp disintegrating device.

33. The device setup of claim 32 , wherein the pulp disintegrating device is selected from a rotor-rotor dispergator, a disperser, a homogenizer, a refiner, a grinder, a colloider, a friction grinder, a pin mill, an ultrasound sonicator, and a fluidizer.

34. The device setup of claim 32 , wherein the means for measuring optically the turbidity of said dispersion in real-time are connected directly to a disintegrating device.

35. The device setup of claim 32 , wherein the means for measuring optically the turbidity of said dispersion in real-time are connected to a separate bypass line or outlet tube coming from a disintegrating device.

36. The device setup of claim 32 , wherein the setup comprises at least two disintegrating devices.

37. The device setup of claim 36 , wherein the setup comprises at least two devices for monitoring the quality of nanofibrillar cellulose each connected to a different one of said at least two disintegrated devices.

38. The device setup of claim 32 , comprising controlling means arranged to control said at least one disintegrating device as a feedback for the monitored quality of the nanofibrillar cellulose obtained from said at least one disintegrating device.

39. The device setup of claim 38 , wherein the controlling means are arranged to control said at least one disintegrating device by changing the speed of the disintegrating device.

40. The device setup of claim 38 , wherein the controlling means are arranged to control said at least one disintegrating device by changing the flow rate of the pulp dispersion into the disintegrating device.

Assignees

• Upm Kymmene Corp

Inventors

• Nuopponen Markus
• Tamper Juha
• Kajanto Isko

Classifications

• G01N21/49 Primary

  within a body or fluid · CPC title

• D21C3/00

  Pulping cellulose-containing materials (digesters D21C7/00) · CPC title

• C08L1/00

  Compositions of cellulose, modified cellulose or cellulose derivatives · CPC title

• G01N2021/3188

  band-limited · CPC title

• C08L1/02 Primary

  Cellulose; Modified cellulose · CPC title