Treatment process for a zirconium alloy, zirconium alloy resulting from this process and parts of nuclear reactors made of this alloy

Patent metadata

Field	Value
Publication number	US-10119181-B2
Application number	US-201314759791-A
Country	US
Kind code	B2
Filing date	Jan 11, 2013
Priority date	Jan 11, 2013
Publication date	Nov 6, 2018
Grant date	Nov 6, 2018

Abstract

A treatment process for a zirconium alloy is provided. The process includes the following steps:
a zirconium alloy ingot is prepared, the composition of which is:
0.40%≤Nb≤1.05%; traces≤Sn≤2%; (0.5Nb−0.25) %≤Fe≤0.50%; traces≤Ni≤0.10%; traces≤(Cr+V) %≤0.50%; traces≤S≤35 ppm; 600 ppm≤O≤2000 ppm, preferably 1200 ppm≤O≤1600 ppm; traces≤Si≤120 ppm; traces≤C≤150 ppm;
the remaining being Zr and unavoidable impurities; the ingot undergoes at least one reheating and hot shaping step, and possibly a reheating and quenching step following a hot shaping step; optionally the hot-shaped ingot undergoes an annealing; the hot-shaped and possibly annealed ingot undergoes at least one cycle of cold rolling-annealing steps; the annealing of at least one of the cold rolling-annealing steps being performed at a temperature comprised between 600° C. and the lowest of either 700° C. or (710−20×Nb %)° C., and the annealings of the other cold rolling-annealing steps, if any, being performed at a temperature not higher than 600° C. Also provided are a Zr alloy so obtained, and part of a fuel assembly for a light water nuclear reactor made of it.

First claim

What is claimed is:

1. A treatment process for a zirconium alloy for use in a nuclear reactor, comprising:
preparing a zirconium alloy ingot, the zirconium alloy ingot having a composition of which is in weight % or weight ppm:
0.40%≤Nb≤1.05%;
traces ≤Sn≤2%;
(0.5 Nb−0.25) %≤Fe≤0.50%;
traces ≤Ni≤0.10%;
traces <(Cr+V) %<0.50%;
traces ≤S≤35 ppm;
600 ppm≤O≤2000 ppm;
traces ≤Si≤120 ppm;
traces ≤C≤150 ppm;
If 0.50%≤Nb≤1.05%, then (Cr+V) %≤(0.2 +3/4Fe−1/4Nb) %; and
the remaining being Zr and unavoidable impurities;

at least one step of reheating and hot shaping the zirconium alloy ingot;
at least one cycle of cold rolling-annealing steps on the zirconium alloy ingot after the at least one step of reheating and hot shaping, a last annealing of the at least one cycle of cold rolling-annealing steps being a final annealing step which gives a product formed therefrom a final stress-relieved, partially recrystallized or completely recrystallized condition,
the annealing of at least one of the cold rolling-annealing steps being performed at a temperature comprised between 650° C. and the lowest of either 700° C. or (710−20×Nb %)° C., and the annealings of the other cold rolling-annealing steps, if any, being performed at a temperature not higher than 600° C.

2. The treatment process as recited in claim 1 wherein the at least one step of reheating and hot shaping the zirconium alloy ingot includes a reheating and quenching step following a hot shaping step.

3. The treatment process as recited in claim 1 further comprising an annealing the ingot after the at least one step of reheating and hot shaping the zirconium alloy ingot.

4. The treatment process as recited in claim 1 wherein (0.02+1/3Fe) %≤(Cr+V) %.

5. The treatment process as recited in claim 1 wherein 0.50%≤Nb≤1.05%, and (0.02+1/3Fe)%≤(Cr+V)%≤(0.2 +3/4Fe−1/4Nb)%.

6. The treatment process as recited in claim 1 wherein the at least one cycle of cold rolling-annealing steps is at least two cycles of cold rolling-annealing.

7. The treatment process as recited in claim 1 wherein the temperatures and durations of the reheating and annealing steps are chosen so that arithmetic mean sizes of the precipitates is between 50 and 250 nm.

8. The treatment process as recited in claim 1 wherein the composition of the prepared zirconium alloy ingot is: 1200 ppm≤O≤1600 ppm.

9. A zirconium alloy having a composition in weight% or weight ppm comprising:
0. 40%≤Nb≤1.05%;
traces≤Sn≤2%;
(0.5 Nb−0.25)%≤Fe≤0.50%;
traces ≤Ni≤0.10%;
traces ≤(Cr+V)%≤0.50%;
traces ≤S≤35 ppm;
600 ppm≤O≤2000 ppm;
traces ≤Si≤120 ppm;
traces ≤C≤150 ppm;
if 0.50%≤Nb≤1.05%, then (Cr+V)%≤(0.2 +3/4Fe−1/4Nb) %;
(0.02+1/3Fe)%≤(Cr+V)%; and
the remaining being Zr and unavoidable impurities;
wherein the zirconium alloy has undergone treatments comprising at least one hot shaping step and at least one cycle of cold rolling-annealing steps, the annealing of at least one of the cold rolling-annealing steps having been performed at a temperature comprised between 650° C. and the lowest of either 700° C. or (710−20×Nb%)° C., and wherein the annealings of the other cold rolling-annealing steps, if any, having been performed at a temperature not higher than 600° C., and in that its microstructure is deprived of β-Zr phase.

10. The zirconium alloy as recited in claim 9 wherein 1200 ppm ≤O≤1600 ppm.

11. A fuel cladding tube for a fuel assembly for a light water nuclear reactor, the fuel cladding made of the zirconium alloy as recited in claim 9 .

12. A guide thimble for a fuel assembly for a pressurized water nuclear reactor, the guide thimble made of the zirconium alloy as recited in claim 9 .

13. A fuel channel for a fuel assembly for a boiling water nuclear reactor, the fuel channel made of the zirconium alloy as recited in claim 9 .

14. A grid for a fuel assembly for a light water nuclear reactor, wherein the grid made of the zirconium alloy as recited in claim 9 .

15. A water channel for a fuel assembly for a boiling water nuclear reactor, wherein the water channel made of the zirconium alloy as recited in claim 9 .

16. The treatment process as recited in claim 1 wherein the partially recrystallized or completely recrystallized condition is formed by more than 10% of recrystallized grains.

Assignees

• Areva Np

Inventors

• Barberis Pierre
• Guerin Pascal
• Fremiot Pascaline

Classifications

• G21C3/30

  Assemblies of a number of fuel elements in the form of a rigid unit · CPC title

• C22F1/186

  of zirconium or alloys based thereon · CPC title

• Y02E30/40

  Cross-Sectional Technologies · mapped topic

• C22C16/00 Primary

  Alloys based on zirconium · CPC title

• G21C3/07

  characterised by their material, e.g. alloys · CPC title