Use of polyesters as lubricants

Patent metadata

Field	Value
Publication number	US-10119092-B2
Application number	US-201314443742-A
Country	US
Kind code	B2
Filing date	Nov 8, 2013
Priority date	Nov 19, 2012
Publication date	Nov 6, 2018
Grant date	Nov 6, 2018

Abstract

The presently claimed invention is directed to the novel use of polyester obtainable by reacting a mixture comprising adipic acid and an alcohol mixture comprising 1-nonanol, monomethyloctanols, dimethylheptanols and monoethylheptanols as lubricants and a lubricant composition comprising these polyesters.

First claim

The invention claimed is:

1. A lubricant composition comprising:
A) at least one lubricating base oil which is a poly-α-olefin (PAO) in an amount from 30 to 90% by weight,
B) at least one polyester in an amount from 3.5 to 45% by weight and obtainable by reacting adipic acid and an alcohol mixture comprising 1-nonanol, monomethyloctanols, dimethylheptanols and monoethylheptanols having a viscosity at 40° C. in the range of 8 to 12 mm 2 /s determined according to DIN 51562-1 and
C) one or more lubricating oil additives in an amount from 0.1 to 40% by weight wherein the lubricant composition has a cloud point of less than −80° C.

2. The lubricant composition according claim 1 , wherein the alcohol mixture contains a proportion of 25% by weight to 55% by weight monomethyloctanols, based on the overall weight of the alcohol mixture.

3. The lubricant composition according to claim 1 , wherein the alcohol mixture contains a proportion of 10% by weight to 30% by weight dimethylheptanols, based on the overall weight of the alcohol mixture.

4. The lubricant composition according to claim 1 , wherein the alcohol mixture contains a proportion of 6% by weight to 16% by weight 1-nonanol, 25% by weight to 55% by weight monomethyloctanols, 10% by weight to 30% by weight dimethylheptanols and 7% by weight to 15% by weight monoethylheptanols, based on the overall weight of the alcohol mixture.

5. The lubricant composition according to claim 1 , wherein the lubricating oil additives are selected from the group consisting of lubricity improvers, viscosity improvers, combustion improvers, corrosion and/or oxidation inhibiting agents, pour point depressing agents, extreme pressure agents, antiwear agents, antifoam agents, detergents, dispersants, antioxidants, and metal passivators.

6. The lubricant composition according claim 3 , wherein the alcohol mixture contains a proportion of 25% by weight to 55% by weight monomethyloctanols, based on the overall weight of the alcohol mixture.

7. The lubricant composition according claim 5 , wherein the alcohol mixture contains a proportion of 25% by weight to 55% by weight monomethyloctanols, based on the overall weight of the alcohol mixture.

8. The lubricant composition according to claim 5 , wherein the alcohol mixture contains a proportion of 6% by weight to 16% by weight 1-nonanol, 25% by weight to 55% by weight monomethyloctanols, 10% by weight to 30% by weight dimethylheptanols and 7% by weight to 15% by weight monoethylheptanols, based on the overall weight of the alcohol mixture.

9. The lubricant composition according to claim 1 , wherein the polyester has a viscosity index above 140.

10. The lubricant composition according to claim 1 , consisting essentially of components a, b and c wherein the lubricating oil additives are selected from the group consisting of lubricity improvers, viscosity improvers, combustion improvers, corrosion inhibiting agents, oxidation inhibiting agents, corrosion and oxidation inhibiting agents, styrene-based polymers, crosslinked alkyl phenols, alkyl naphthalenes, extreme pressure agents, antiwear agents, antifoam agents, detergents, dispersants, antioxidants and metal passivators.

11. The lubricant composition according to claim 1 , wherein the lubricant composition comprises 60% by weight to 90% by weight of component A), 10% by weight to 25% by weight of component B) and 2.0% by weight to 20% by weight of component C).

12. A lubricant composition comprising:
A) at least one lubricating base oil which is a poly-α-olefin (PAO),
B) at least one polyester obtainable by reacting adipic acid and an alcohol mixture comprising 1-nonanol, monomethyloctanols, dimethylheptanols and monoethylheptanols wherein the at least one polyester has a viscosity at 40° C. in the range of 8 to 12 mm 2 /s determined according to DIN 51562-1, a viscosity index above 140, a density at 20° C. according to DIN 51757 of from 0.90 to 0.94 g/cm 3 and a refractive index n D 20 according to DIN 51423 is from 1.440 to 1.460 and the alcohol mixture contains a proportion of 6% by weight to 16% by weight 1-nonanol, 25% by weight to 55% by weight monomethyloctanols, 10% by weight to 30% by weight dimethylheptanols and 7% by weight to 15% by weight monoethylheptanols, based on the overall weight of the alcohol mixture,
C) one or more lubricating oil additives are selected from the group consisting of lubricity improvers, viscosity improvers, combustion improvers, corrosion and/or oxidation inhibiting agents, pour point depressing agents, extreme pressure agents, antiwear agents, antifoam agents, detergents, dispersants, antioxidants and metal passivators, and
wherein the lubricant composition comprises 50% by weight to 90% by weight of component A), 3.5 to 45% by weight of component B) and 0.1% by weight to 40% by weight of component C) and wherein the lubricant composition has a cloud point of less than −80° C.

13. The lubricant composition according to claim 12 , wherein the lubricant composition comprises 60% by weight to 90% by weight of component A), 10% by weight to 25% by weight of component B) and 3.5% by weight to 20% by weight of component C).

14. The lubricant composition according to claim 13 , wherein the polyester is derived from a mixture which consists essentially of
11.0% 1-nonanol
20.8% 6-methyl-1-octanol
20.5% 4-methyl-1-octanol
5.3% 2-methyl-1-octanol
11.0% 2,5-dimethyl-1-heptanol
8.7% 3-ethyl-1-heptanol
6.2% 4,5-dimethyl-1-heptanol
2.9% 2-ethyl-1-heptanol
2.8% 2,3-dimethyl-1-heptanol
3.0% 2-ethyl-4-methyl-1-hexanol
2.7% 2-propyl-1-hexanol and
1.6% 3-ethyl-4-methyl-1-hexanol.

15. The lubricant composition according to claim 12 , wherein the viscosity of the lubricant composition at 40° C. is from 80 to 120 mm 2 /s determined according to DIN 51562-1.

Assignees

• Basf Se

Inventors

• Scherer Markus
• Breitscheidel Boris

Classifications

• C10N2030/36

  Seal compatibility, e.g. with rubber · CPC title

• C10N2020/02

  Viscosity; Viscosity index · CPC title

• C10N2030/02

  Pour-point; Viscosity index · CPC title

• C10M165/00 Primary

  Lubricating compositions characterised by the additive being a mixture of a macromolecular compound and a compound of unknown or incompletely defined constitution, each of these compounds being essential · CPC title

• C10M2207/282

  of (cyclo)aliphatic oolycarboxylic acids · CPC title